فصلنامه سلامت و محیط زیست
سال یازدهم شماره 3 (پیاپی 41، پاییز 1397)

Treatment of hospital wastewaters has an important role in reducing the discharge of organics and pharmaceutical compounds into aquatic environments. Nowadays, advanced oxidation processes were extensively used for the removal of organic compounds from treated effluents. The study aimed to examine organic compounds removal from real treated effluent of a hospital treatment plant using a lab scale UV/H2O2/TiO2 process by optimizing the process. The effluent characteristics including COD, TOC and DOC were measured and recorded. A hybrid advanced oxidation process (UV/H2O2/TiO2) was used for the removal of organic compounds. The experiments were designed using surface response methodology (RSM). The effects of the independent factors including pH, duration of UV irradiation, H2O2 and TiO2 concentrations on COD, TOC, DOC and the approximate cost of treatment were assessed by analysis of variance (ANOVA). The optimal condition was 7.2 for pH, 50 mg/L for H2O2, 100 mg/L for TiO2 and 19.65 min for irradiation time. This condition provided the maximum removal percentage for organic compounds with a minimum cost. The removal efficiency for TOC, DOC and COD were 63.9, 52.9, and 64.7%, respectively. The treatment cost was approximated to be $ 0.71 per one liter of the effluent. Irradiation and H2O2 concentration had the greatest impact on the cost of the treatment. UV/H2O2/TiO2 process seems to be an expensive process for tertiary treatment of wastewater. However, further investigations are required to evaluate the cost effectiveness of the process for a full scale operation.

A scientific questionnaire for assessing the knowledge, attitude and judgment of people on waste management by municipalities has not been developed so far. Therefore, the purpose of this study was to design and validation of an instrument to assess the knowledge, attitude and judgment of people on waste management by municipalities. This analytical study was conducted in District 21 of Tehran in 2017. The initial items of the questionnaire were designed based on previous studies and opinions of the team of specialists and people. Then, the face validity and the content validity of the designed questionnaire was examined. The face validity and the content validity was examined qualitatively and quantitatively, respectively. Finally, the reliability of the attitude and knowledge and evaluation of municipal performance items were measured by Cronbach's alpha and a test-retest method, respectively. The initial questionnaire had 43 items. In the face validity, 8 items were removed and 8 items were edited. In quantitative content validity, 7 items were excluded, with the content validity index of less than 0.79 and the content validity ratio less than 0.49. Pearson correlation coefficient obtained for knowledge component equal to (r=0.77, p<0.0001) and for component performance (r=0.93, p<0.0001), respectively. Cronbach's alpha coefficient was equal to 0.89 for items attitudes, which were in an acceptable level. The questionnaire can be used as a valid research instrument to collect information on knowledge, attitude and judgment of people on waste management by municipalities.

Antibiotics are a group of emerging contaminants in the aquatic environment. Antibiotic residues threaten the human health and ecosystem in the low concentrations found in the environment. Hence, the present work has been conducted to investigate the occurrence and removal efficiency of most prescribed antibiotics including amoxicillin, penicillin, cefixime, cephalexin, ciprofloxacin, erythromycin and azithromycin detected in two urban wastewater treatment plants (WWTPs) in Tehran. The present work is an applied research based on USEPA method no. 1694, to investigate pharmaceuticals residues in water by HPLC/MS/MS in year 2016. The differences between target antibiotics residues were investigated statistically. After the calculation of the removal efficiencies, the normality of the data was assessed. Then, parametric and non-parametric tests were used to compare the removal efficiencies in both WWTPs. There was not a significant difference between the influent and effluent concentrations of cefixime and azithromycin (in Ekbatan WWTP) and cefixime (in southern Tehran WWTP). There is a significant difference between the removal efficiencies of cephalexin (p=0.005) and erythromycin (p=0.002) in two WWTPs. The Highest median removal efficiencies were observed for cephalexin 94.41 and 99.47 in Ekbatan WWTP and southern Tehran WWTP, respectively. In addition to the type of treatment processes, it is physicochemical properties of the selected compound has a significant influence on removal efficiencies.

The sewer system is one of the important and suitable areas for the growth and reproduction of American Cockroach Periplaneta americana (L.) in Bushehr. This project was implemented for considering the high cost of spraying and environmental pollution. In this study some commonly insecticides were tested in different doses to evaluate the effectiveness on cockroaches in sewer system. Three treatments including the combination of the insecticide with class B diatomaceous earth, solid silica gel and boric acid were evaluated in manholes of sewer system. In this regard, the Bushehr city was divided into ten clusters based on its sewer system and then, ten manholes were selected randomly from each area to survey and conduct field experiments. A random-cluster sampling method was used to generalize the results of the whole system. The mortality rate was corrected on control mortality with the Henderson-Tilton formula. Experimental insecticides spraying controlled up to 100 percent of cockroaches in the laboratory. However, using insecticide alone reduced the mortality rate in manholes over time. The results of statistical tests showed that the most effective method in destroying cockroach was the usage of the compounds of insecticide, mineral and non-chemical substances which caused mortality rate more than 90% up to 12 months. As little as 50 g/manhole of a dust consisting of 5% silica gel, 35% boric acid, 60% diatomaceous earth with a commercial insecticide such as Deltamethrin sprayer provided more than 98% control for 12 months.

The main objective of this study was to evaluate the surface and deep distribution of Pb, Ni and Cu in the wastewater-irrigated area of south of Tehran using GIS and Hydrus. It was expected to find a comprehensive information of heavy metals distribution and their accumulation in the soil. This study was carried out in wastewater-irrigated area of south of Tehran. Soil sampling from the top surface layer (0-15 cm) and wastewater channels was done. After sample analysis, ordinary Kriging method using different variogram in GIS was applied to explore the surface distribution of Ni, Pb and Cu heavy metals. Moreover, the deep percolation of heavy metals in the soil profile was simulated by Hydrus-1D in a duration of 210 days and the heavy metals concentrations in the soil were estimated. Exploration of the distribution of Pb using spherical model showed that the variation of this element was in the range of 20-70 mg/kg. This amount varied to 50-60 mg/kg for Cu and about 30 mg/kg for Ni. Moreover, the simulation of heavy metals deep percolation using Hydrus revealed that the most accumulation of heavy metals happened in the 0-15 cm soil surface layer and for deeper layer, this trend was descending. Comparing the concentration of Pb, Cu and Ni with the maximum allowable amounts of WHO standards demonstrated that Pb concentration was more than the threshold limit. Finally, the applied models could simulate soil’s heavy metals content for both surface and deep distribution in the studied area.

Concentration prediction with Gaussian dispersion models is highly sensitive to meteorological data. The lack of sounding data station in developing countries may lead to large error and uncertainty in air pollution modeling results. In this paper, the effects of estimated upper air data on the model output concentration values were investigated. AERMOD model was executed once with real upper air data and also with estimated upper air data separately. T-Student and LEVENE tests were used to evaluate the significant differences between concentrations in two modes of using actual and estimated upper air data. The results showed that large differences in concentration between the two methods. In long term modeling, there was up to 33% differences between real and estimated upper meteorological data and up to 63% differences for short term modeling. A large difference was also observed between boundary layer parameterization values in each case. The statistical analysis showed a meaningful difference (p=0.00) between the cases. The differences between ZICNV, DT/DZ, W* were 7.1%, 48%, and 19%, respectively. The use of estimated upper meteorological data in comparison with measured data may lead to a large error. The AERMOD modeling results with estimated meteorological data must be expressed with appropriate uncertainties and confidence interval.

Noise pollution causes many physiological, psychological, economic and social effects on human life. This issue is more important in the environment of industrial workplaces. This research aimed to adopt the functions of GIS for evaluating and spatial analysis of noises in industrial environments. At the initial step, the spatial data for industrial halls were collected and stored as map layers into GIS database. Then, the noise pollution data sampled. The data, including the locations and values of sound pressure levels, were used for the relevant spatial analyses. The analyses included: the estimation of sound pressure levels in different areas of halls and at the given distance from machines, determination of noisy areas, development of sound noise risk map, interpolation of sound pressure level data, prioritization of the sound sources (i.e., machines) for a given point, prediction of sound pressure levels by moving machines, and optimal site selection and distribution of machines. The mean of noise pressure level was 95 dB for knitting hall, 93 dB for spinning hall 1 and 88 dB for spinning hall 2. GIS plays a key role in the assessment of noise pollution in industrial workplaces. It is an appropriate tool to store, analyze, manage, and present all types of sound pressure spatial data. Specifically, the use of such system provides spatial intelligence and could help monitor, detect, control, and solve real word sound noise pollution issues.

Street dust is an important factor in urban pollution which consists of soil, particulate matters and heavy metals. At present, over half of the world’s population lives in urban areas. Therefore, this study aimed to investigate health risks of heavy metals in street dusts in Zahedan. The samples of street dust were collected in Zahedan. After preparation, the samples, were injected to ICP-MS for determination the amount of Hg and Cu. According to the measured concentrations, Hazard quotient (HQ) and hazard index (HI) were calculated to evaluate the health risk assessment. Results showed that Hazard quotient for both Hg and Cu was less than 1 for children and adult. HQ for Hg and Cu was in order of HQingestion >HQdermal >HQinhalation> HQvapour for adults and HQvapour > HQingestion > HQdermal > HQinhalation for children. HI was also less than 1. The value of HQ showed that inhalation of mercury vapor and ingestion were the main routes of exposure to Hg for children and adults. The non-carcinogenic risk was within the safe value (HI <1) in this study.

Coagulation, which is carried out by mixing coagulants such as alum, ferric chloride and poly aluminum chloride PAC with raw water, is one of the main processes in conventional water treatment plants. Sludge from this process contains high amounts of coagulants with high economic value. Therefore, if these coagulants are recovered, in addition to reducing the risks relate to sludge disposal, the expenses related to the supply of fresh coagulant in water or wastewater treatment plant may decrease. To access related documentation, ScienceDirect, Google scholar and other databases were searched using keywords such as “coagulant recovery”, “water residuals management”, etc. More than one hundred fifty documents were investigated based on the content validity and thematic relation. Gathered contents were classified and summarized under the titles of “recovery methods”, “repeated recoveries”, “recovery regarding economic aspect” and “advantages and disadvantages of methods”. Use of new methods such as combination of membrane and chemical processes or ion exchange membrane processes leads to the recovery of coagulants with a similar quality to the commercial ones. In case of using conventional and less costly methods such as acid digestion, quality of recovered coagulants is not comparable with those of commercial ones, which are used in water treatment. Different coagulants recovery methods were investigated to determine the reuse strategies. It is likely that using of recovered coagulants through conventional methods is in accordance with the related regulations of the wastewater treatment plants. Industrial use of novel processes for recovery of coagulants with higher quality needs precise technical and economical investigations.

Heavy metals contaminations are readily bioaccumulated in aquatic systems and lead to increased concentrations in food chains, posing a serious threat to human health, water-related organisms and aquatic ecosystems. The purpose of the present study was to determine the concentration of heavy metals in surface sediments of CheshmehKile River, to evaluate environmental and ecological risk and to determine the degree of contamination of the elements studied. In this study, 25 samples of surface sediment were collected from the CheshmehKile River. The heavy metals content of the samples was measured by inductively coupled plasma-optical emission spectrometry. According to the content of heavy metals in sediment samples, environmental and ecological risk indices were calculated. Also, river contamination was evaluated by comparing the elements studied values with the sediment quality guidelines values. The mean concentration of chromium, manganese, iron, cobalt, nickel, zinc and arsenic were 41.27, 356.35, 16756.32, 9.17, 11.87, 41.24 and 24.60 µg/g, respectively. Based on the values of the CF and Igeo indices, all of the elements, with the exception of arsenic, showed a low degree of contamination. The indices of Eir and RI also showed the lowest ecological risk at all stations. The results of this study showed that the surface sediments of CheshmeKile River in Mazandaran province were somewhat contaminated with arsenic. However, fortunately, the river sediments were of good quality from the point of view of the content of chromium, manganese, iron, cobalt, nickel and zinc.

Marine sediments are the most important component of monitoring the health of aquatic ecosystems. The present study uses sediment quality indices to determine the contamination status in Qeshm ecosystems and to evaluate the toxicity of the elements studied for its organisms. Sampling of surface sediments of seven stations was carried out on Qeshm coastal areas. The samples were digested by a combination of nitric acid and perchloric acid, and the concentration of metals was measured by atomic absorption spectrometry. The results of modified Hazard Quotient indicated a high pollution rate for copper and nickel metals in most stations, which was consistent with the results of the Potential Contamination Index in relation to nickel metal. Additionally, the results of the Potential Contamination Index and Contamination Factor agreed with the amount of lead element. According to the results, the pollution index of Hamoon Lake and Zakeri pier was highly contaminated and Modified Pollution Index demonstrated a contamination in Romacha, Hamoon Lake, Zakeri pier and Nazes areas. The enrichment factor associated with contamination regarding most of the heavy metals confirmed the indices used to evaluate the comtamination in the study area. Due to the higher concentrations of the heavy metals in the sediments than that of the quality guidelines, the high toxicity of sediments for the aquatic ecosystems was confirmed. The Romachah, Hamoon, Zakeri stations showed higher pollution levels and sever toxicity for aquatic life. Copper, nickel and in some cases lead, were the main heavy metals that contaminated the sediments in the region.

The establishment of pelletizing and steel industries in Ardakan suburbs has increased the pollutants such as heavy metals into the environment. The purpose of this study was to investigate the contamination of the area soil by heavy elements around these industries using the pollution index (PI), comprehensive pollution index (NIPI), accumulation index (Igeo) and enrichment index (EF). 57 soil samples were prepared by systematic-random sampling from 0 to 5 cm depth and levels of As, Cd, Cr, Mo, Ni, Pb, V and Zn were analyzed by ICP-OES. The highest and lowest mean of Igeo (0.49 and 0.36) and PI (2.16 and 1.17), were related to nickel, and the highest EF was calculated for Zn at about 25.1 and the lowest were detected for molybdenum approximately that was 17.1. The EF index of lead, vanadium and zinc, which was 15.8%, 5.3% and 1.8%, respectively, classified the study area in a medium enrichment class. Hot spots of lead, vanadium, nickel and zinc was at the nearest distance to these industries and downstream of wind direction. Indicators of Igeo and EF showed a low level of soil pollution. The PI and NIPI indices in most stations were classified in medium pollution class, and the highest of these indicators was related to the surface soil of station 30, which was located near the steel industry. Therefore, it can be concluded that the activities of these industries had affected the soil contamination of the study area.