Analytical Methods: Electrochemical azido-selenenylation of some olefins by cyclic voltammetry and controlled-potential coulometry

Electrochemical azido-phenylselenenylation of some olefins was studied with the oxidation of diphenyl diselenide in the presence of some olefins and sodium azide in dimethyl formamide containing tetra butyl ammonium perchlorate as supporting electrolyte in an H-type cell. The electrochemical oxidation of the mixture of (PhSe)2, olefins, and NaN3 was studied by cyclic voltammetry and controlled-potential coulometry. Anti product can be obtained with Markovnikov orientation. This product was characterized .by 1H, 13C NMR, and IR spectroscopy.