امیر رضا آزادمهر

The flotation circuit in Sungun copper plant consists of two column flotation cells as cleaner, having fixed-spargers system. To achieve the expected aims in flotation step, there are serious operational challenges such as: fast choking of the static mixers, boiling problem, burping phenomena and pulp overflow to concentrate lander, maintenance and control problems. An attempt was exerted by implementing new helical static mixer in one of cleaner cells instead of old elliptical type to overcome the challenges. The changes resulted in proper performance of the column whereas burping phenomena due to choking was eliminated, finer bubbles were produced, and the boiling and overflow problems were solved. Also, the static mixers life time increased to 7 months in helical column cells from one month in elliptical column cells. In addition to 40% air consumption reduction and 20% solid percent increase in final product, the grade of Cu and Mo increased by helical static mixer replacement up to about 18.7% from 16.8% (11%) and to 511.1 ppm from 263 ppm (94%) in the cleaner step, respectively. Recovery of Cu and Mo were increased about 1.5% and 0.2%, respectively. Finally, the results proved the effectiveness of finer bubble generation on grade improvement is depend on minerals hydrophobicity as Mo grade increased more than Cu.

In this work, two clay-based composites are prepared for the adsorptive removal of the chloride ions from aqueous solutions. These composites are characterized through Fourier transform-infrared spectroscopy, scanning electron microscopy, X-ray fluorescence spectroscopy, and X-ray diffraction analysis. The effects of different parameters such as the contact time, amount of adsorbent, chloride concentration, temperature, and pH are studied by batch experiments. Also the isotherm, kinetic, and thermodynamic of the adsorptive removal of the chloride ions from these two composites are investigated. According to the results obtained, the adsorptive removal of chloride ions is initially rapid, and the equilibrium time is reached after 30 min. The optimal pH value is 7.0 for a better adsorption, and the maximum capacity can be achieved, which is 60.2 mg/g with 1000 mg/L of the initial chloride concentration. The Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich adsorption models are applied to describe the equilibrium isotherms at different chloride concentrations. According to the equilibrium isotherms and the correlation coefficients (R2CDC: 0.9424, R2LDC: 0.996), the process can be described by the Langmuir model, and exhibits the highest removal rate of 97.24% (24.31 mg/g) with 250 mg/L of the initial chloride concentration. The pseudo-first-order and pseudo-second-order, intra-particle diffusion, and mass transfer kinetics models are used to identify the mechanism of the adsorptive removal of the chloride ions. The pseudo-second order model due the correlation coefficients (R2CDC: 0.9217-0.9852, R2LDC: 0.9227-0.9926) can be fitted to the kinetic calculations, and it is applicable for the adsorptive removal of chloride ions by the adsorbents. The thermodynamic calculations show that in a low chloride concentration, the sorption is spontaneous, associative, and endothermic; and in a high concentration, it is unspontaneous, dissociative, and endothermic. The calculated value of free energy (E) for adsorption onto the adsorbents suggests that the reaction rate controls the adsorptive removal of the chloride process rather than diffusion. It can be concluded that these two composites can be used as effective and applicable adsorbents for the adsorptive removal of chloride ions.

Copper oxide ores are usually leached in sulphuric acid solution. However, it has severe adverse impact on the environment. In this study, bioleaching and leaching by citric acid, as environmentally friendly methods, are investigated. The experiments were carried out on a copper oxide ore sample containing copper content of 3.4%. This sample does not contain any energy source to grow the conventional bioleaching microorganisms (like Thiobacillusferrooxidans and Thiobacillusthiooxidans). This sample was leached by a heterotrophic bacterium, Pseudomonas aeruginosa. This bacterium produces organic acids in selected culture medium that operate as leaching agents. Leaching is investigated by citric acid, as an organic acid produced by this microorganism. The optimum bioleaching conditions were found as: glucose percentage of 6, bioleaching time 8 days and solid/liquid ratio of 1:80 and of optimum leaching conditions as: particle size range105-150µm, acid concentration of 0.2 M, 30 min dissolution time, solid/liquid ratio of 1:20 g/mL and temperature of 40°C. Under optimum bioleaching conditions 53 percent of copper was extracted and copper extraction under optimum leaching conditions was 92 percent.