کیاندخت میراسدی

Smart materials can react to environmental changes like living organisms and adapt themselves to environmental conditions and changes such as changes in temperature, electric current, magnetic field, light, humidity, etc. Using 3D printing to process smart materials is a new approach known as 4D printing. In this research, processing, manufacturing and 3D printing of PETG-ABS in three weight percentages of 70/30, 50/50 and 30/70 were done. The results of SEM also confirmed the compatibility of these two polymers. In all PETG-ABS mixtures, a combination of sea-island and drop-matrix morphology was observed, and for the 30/70 and 30/70 blends, phase droplets dispersed in the matrix were clearly observed. The results of mechanical properties also showed that as the percentage of ABS in the mixture increases, the tensile strength increases and the elongation decreases. The results obtained from the shape memory test indicate the existence of the ability to program the shape memory property in 4D printing mixtures. As expected, the increase in the weight percentage of ABS was associated with the disorder in the recovery of the mixtures, so the mixture with 70% by weight of PETG and 30% by weight of ABS showed the most favorable shape memory properties.

In this research, processing and 3D printing of PETG-ABS- Fe 3 O 4  nanocomposites reinforced with iron oxide nanoparticles in three different weight percentages of iron oxide nanoparticles with PETG70-ABS30 polymer matrix was done. This research was carried out with the aim of strengthening the shape memory properties, thermal properties, mechanical properties and adding the ability to indirectly stimulate the background matrix through the addition of iron oxide nanoparticles. SEM images confirmed that the mixture of PETG-ABS is immiscible and adding nanoparticles does not change the compatibility and miscibility of the base polymer, and this result is consistent with the DMTA analysis was also checked and confirmed. With increasing amount of iron oxide, the tensile strength and elongation decrease, and this decrease in mechanical properties is more pronounced in the sample of 20% by weight of iron oxide compared to the sample of 10% by weight. Nevertheless, the final strength of the samples is around 25 to 32 MPa, which indicates a suitable and acceptable distribution of nanoparticles up to 15% by weight in the polymer field. By increasing the amount of iron oxide nanoparticles, the amount of shape recovery increases and the nanocomposites containing 10, 15 and 20% by weight show shape recovery of 63.77%, 88.48 and 93.33%, respectively.