hasti daraei
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The field of nanotechnology has demonstrated remarkable potential in effectively addressing environmental issues through remediation, particularly in extracting and removing pollutants from water, air, and human samples. The unique properties of nanomaterials, such as their high surface area (HSA) to volume ratio, size, and optical and magnetic behavior, make them well-suited for various applications in pollution control in different matrixes. Nanotechnology-based adsorbents are utilized in multiple fields such as water wastewater treatment, air purification filters, photocatalysis, environmental monitoring, electrochemical sensors, industrial, human sample analysis, and bioanalysis. Nanoadsorbents such as carbon nanotubes (CNTs), graphene (G), metal oxide nanoparticles, metal-organic frameworks (MOFs), nanocomposites, magnetic nanoparticles, and silica-based nanomaterials are materials at the nanoscale that can remove pollutants by solvent extraction, membrane separation, photocatalysis, sorption, filtration, adsorption, precipitation, ion exchange, bioremediation, phytoremediation, coagulation, flocculation, and chemical oxidation/reduction technique. These nanomaterials are designed to have high surface areas and unique properties that effectively absorb various contaminants. The choice of nano adsorbent depends on the specific pollutants targeted, the environmental conditions, the physicochemical characteristics of the pollutant, and the desired application. Ongoing research is exploring new nanomaterials and optimizing existing ones to improve efficiency and address potential environmental and safety concerns. In summary, nanotechnology holds great potential for extracting and removing pollutants in water, air, soil, and human samples, using innovative methods for environmental protection and public health.
Keywords: Removal, Pollutants, Nanotechnology, Adsorbents. Analytical Methods -
مقدمه و هدف
شیوع و انتشار غالب بیماری ها از جمله سالک علاوه بر مسائل اقتصادی، اجتماعی و فرهنگی تحت تاثیر عوامل اکولوژیکی است بنابراین مطالعه حاضر با بررسی تاثیر عوامل اقلیمی بر میزان ابتلا به لیشمانیوز جلدی شهری و روستایی در شهر کرمان و ارزوئیه طی سال های 99-95 انجام شد.
روش کارپژوهش حاضر یک مطالعه مقطعی از نوع توصیفی-تحلیلی است که بر روی کلیه بیماران با تشخیص قطعی لیشمانیازیس جلدی شهری ساکن در منطقه سرآسیاب از شهر کرمان، و نوع روستایی ساکن در شهر ارزوئیه که به مراکز درمان لیشمانیوز مراجعه نموده بودند؛ از نیمه دوم سال 95 تا پایان سال 99 با استفاده از روش سرشماری وارد مطالعه شدند.
یافته هابه طور کلی در مجموع 332 بیمار مبتلا به لیشمانیوز جلدی در مطالعه شرکت کردند. بین میانگین و انحراف معیار مبتلایان در هر فصل از سال در منطقه سرآسیاب از شهر تفاوت آماری معناداری مشاهده شد (0/05>p). همچنین در منطقه سرآسیاب شهر کرمان بین دما، بارش و سرعت باد بصورت ماهیانه با تاخیر 4 ماهه و میزان ابتلا به ازای یک میلیون نفر تفاوت آماری معناداری مشاهده گردید (0/05>p).
نتیجه گیرینتایج مطالعه حاضر نشان داد که تنها در نوع شهری لیشمانیوز ارتباط معناداری بین عوامل اقلیمی و ابتلا به بیماری وجود داشت. بنابراین توجه به فصول سال، بررسی کلیه عوامل اقلیمی بصورت همزمان و با تاخیر چند ماهه، توزیع پراکندگی جغرافیایی بیماری از جنبه های مختلف اپیدمیولوژیک و اکولوژیک می تواند در کاهش و کنترل این بیماری موثر باشد.
کلید واژگان: لیشمانیوز جلدی, عوامل اقلیمی, کرمان, ارزوئیهIntroductionThe prevalence and spread of the prevailing diseases, including the cutaneous leishmaniosis, is affected by ecological factors in addition to economic, social and cultural issues. Therefore, the present study was conducted to investigate the effect of climatic factors on the incidence of urban and rural cutaneous leishmaniosis in Kerman and Arzooieh in 2015-2019.
Materials and MethodsThe present study is a cross-sectional descriptive-analytical study which was performed on all patients with the definitive diagnosis of urban cutaneous leishmaniosis living in Sarasiab area of Kerman, and the rural type living in Arzooieh who referred to leishmaniosis treatment centers; From the second half of 2015 to the end of 2019. They were included in the study using the census method.
ResultsA total of 332 patients with cutaneous leishmaniosis participated in the study. There was a statistically significant difference between the mean and deviation from the standard of patients in each season of the year in Sarasiab area of the city (p<0.05). Moreover, in the head mill area of Kerman province a statistically significant difference was observed between temperature, precipitation and wind speed, monthly with a delay of 4 months and the rate of infection per million people (p<0.05).
ConclusionThe results of the present study showed that only in the urban type of leishmaniosis, there was a significant relationship between climatic factors and disease. Therefore, considering the seasons, studying all climatic factors simultaneously and with a delay of several months, the geographical distribution of the disease from different epidemiological and ecological aspects can be effective in reducing and controlling the disease.
Keywords: Cutaneous Leishmaniosis, Climatic Factors, Kerman, Arzooieh -
Iranian Journal of Chemistry and Chemical Engineering, Volume:36 Issue: 3, May-Jun 2017, PP 137 -146The purpose of this study was the investigation of the removal of phenol with nanoparticles zero valent iron and iron powder. The effect of various parameters such as initial concentration, pH, contact time, and dosage of NZVI and Fe powder was examined, and a Central Composite Design (CCD) was then applied to appraisal the effect of these variables. The chemical and physical characteristics of NZVI were studied with Scanning Electron Microscope (SEM) and X-Ray Diffraction (XRD) analysis. The results displayed that the adequate initial concentration for phenol sorption, pH, contact time, and sorbent dosage were 5 mg/L, pH 2, 54.75 min and 1.40 g in the case of NZVI and 5 mg/L, pH 2, 55.84 min and 2.5 g in the case of Fe powder. The Central Composite Design (CCD) showed that the fundamental parameters were pH and initial phenol concentration had the main effect on phenol removal.Keywords: Zero valent iron, Phenol, Central composite design, Sorption, Nanoparticles, Dosage
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Phenol is one of the serious pollutants from the chemical and petrochemical industries. This pollutant due to its convoluted structure is resistant to biodegradation. One of the methods that are useful to remove this pollutant is advanced oxidation (AOP).A laboratory scale study was done on a synthetic wastewater containing phenol. All experiments were done in batch conditions and effect of variables pH, amount of hydrogen peroxide, iron dosage, contact time and an initial concentration on the phenol removal were tested. The remaining phenol concentration was evaluated using the DR-5000 device. In order to effect of these parameters, the experiment was performance at pH 2 to 6, 5 to 45 ml/ml of peroxide, and time of 5 to 60 minutes with 2 to 15 g/ml iron (Fe˚).The optimum pH, the ratio of hydrogen, Fe˚and time were 3, 15 ml, 8g and 5 minutes respectively. Chemical oxygen demand (COD) index was chosen as the parameter for evaluation in this study. Result showed that mineralization of phenol was not complete. The COD removal efficiency was obtained 71%.According to the results of this study, Fenton-like process can be used for conversion organic resistant compounds to other compounds with lower toxicity.Keywords: Fenton, like, Advance Oxidation, Phenol, Iron Powder
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زمینه و هدففنل از جمله آلاینده های سمی در فاضلاب های صنعتی می باشد که می تواند برروی تصفیه بیولوژیکی فاضلاب تاثیر نامطلوب بگذارد. روش های معمول برای حذف این فلز از فاضلاب اغلب گران قیمت هستند، بنابراین نیاز به یک روش ارزان قیمت و در دسترس برای تصفیه پساب وجود دارد. هدف از تحقیق حاضر توسعه یک متد اقتصادی، سریع و در دسترس برای حذف آلاینده های آلی سمی از فاضلاب با استفاده از غشاء پوست تخم مرغ است.روش کاردر این مطالعه تاثیر پارامترهای گوناگون همچون pH، زمان تماس، دما، مقدار غشاء و غلظت اولیه فنل بررسی شد. سپس مدل مرکب مرکزی (CCD) جهت ارزیابی تاثیر این متغیرها به کار گرفته شد. همچنین مشخصات شیمیایی و فیزیکی غشاء با استفاده از آنالیز SEM و XRF بررسی گردید.یافته هانتایج نشان داد که مقادیر بهینه برای pH، مقدار غشاء، زمان تماس، دما و غلظت اولیه فنل به ترتیب 63/3، 78/3 گرم، 5/115 دقیقه، 20 درجه سانتیگراد و 5 میلی گرم در لیتر به دست آمد. همچنین نتایج آنالیز CCD نشان داد که pH و غلظت فنل پارامترهای اساسی موثر در راندمان هستند.نتیجه گیرینتایج نشان داد که پوست تخم مرغ بعنوان یک ماده زائد به دست آمده از صنایع غذایی، می تواند به عنوان یک جاذب موثر برای حذف فنل و دیگر آلاینده های آلی استفاده شود.
کلید واژگان: غشاء, فنل, جذب, پوست تخم مرغBackground and ObjectivesPhenol is a major toxicant present in industrial effluent that can adversely affect the biological treatment of wastewater. Conventional methods for removal of this chemical compound from wastewater are often expensive، hence; cheap and available methods for wastewater treatment are required. The aim of present research is to develop economic، fast، and versatile method for the removal of toxic organic pollutants from wastewater using membrane eggshell.MethodsIn this research the effect of various parameters such as pH، contact time، temperature، dosage of shell membrane، and initial concentration of phenol were investigated. Central composite design (CCD) was applied to evaluate the effect of these variables. The chemical and physical characteristics of eggshell membranes were studied through SEM and XRF analysis.ResultsThe results indicated that the optimum values for pH، dosage of shell membrane، contact time، temperature، and initial concentration for phenol sorption were 3. 63، 3. 78 g، 115. 50 min، 20 ºC and 5 mg/L، respectively. The results of the CCD analysis showed that pH and phenol concentrations are fundamental parameters affecting the efficiency.ConclusionResults showed that eggshell، as a solid waste of the food industries، can be used as an effective sorbent for removal of phenol and other organic pollutants from aqueous solutions.Keywords: Membrane, Phenol, Sorption, Eggshell -
BackgroundSmall intestinal (SI) volvulus is defined as a rotation of greater than 180 degrees about its mesentery of a segment of jejunum or ileum. Horses of all ages have been affected. There is typically an acute onset of signs of mild to severe pain..ObjectivesThe objective of this study was to evaluate the microbial pathogens of the duodenum, ileum, cecum, colon and rectum (feces) in associated with volvulus horse, and to determine whether rectal (fecal) samples are representative of proximal segments of the gastrointestinal tract..Materials And MethodsA brown 26 years old mare, BCS (body condition score) 4 was found dead in stall in the morning. It was moved to a suitable area to conduct a post-mortem exam. The mare was examined in hanging position and then left lateral-recumbent. Advanced abdominal tympany was present. Clinical signs, laboratory data, surgical or necropsy findings, clinic-histopathological findings and outcome for horse with SI volvulus was obtained from medical records, and identified by manual review. Horsefeces and colon were collected in autopsy. Fecal material was scooped from the center of a freshly defecated bolus into sterile sample cups, which were placed into plastic anaerobe jars with PackAnaero sachets (Mitsubishi Gas Co. via Remel, Lenexa, KS) and transported to the laboratory. Alternatively, colon contents were collected from horse at the autopsy by direct incision into the colon immediately after the horse was autopsied. The samples were transported anaerobically to the laboratory..ResultsOn opening the abdominal cavity; a large quantity of sanguineous, foul-smelling fluid with pus exited the perforated bowel wall (hemoperitoneum). Additionally, signs of an acute diffuse peritonitis were visible. The blood vessels of the stomach and intestines were distended. Small intestinal volvulus was observed in several segments (360 degree rotation involving the mesentery). This information may aid diagnosis and prognosis and guide to decision making for horses with this condition..ConclusionsThe present study results can be used to make a scientific assessment of prognosis in the pre-operative, operative, and post-operative management of horses with small intestinal volvulus. Bacterial infectivity results from a disturbance in the balance between bacterial virulence and host resistance. The “objective” of bacteria is to multiply rather than to cause disease; it is in the best interest of the bacteria to kill the host. Rectal samples were not entirely representative of intestinal compartments in the small or large intestine. This should be taken into account when designing studies using fecal sampling to assess other intestinal compartments, suggesting that parts of the intestinal microbiota were unique to each animal in this study..Keywords: Intestinal Compartments, Fecal Bacteria, Small Intestinal
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Background And AimsPhenol and chlorophenol are among the serious pollutants in industrial effluents. These pollutants in drinking water have a medicinal taste and are quite pronounced and objectionable. The aim of this research was investigation the feasibility potential of nano particle zero valent iron for phenol and chlorophenol removal from aqueous solutions.Materials And MethodsnZVI was synthesized by reduction of ferric chloride by sodium borohydrid. Finally, the chemical and physical characterization of sorbents carried out with SEM analysis. The Batch experiment was conducted to evaluate the effect of pH, chlorophenol and phenol concentration, sorbent dosage, contact time and temperature. Then for experiments the central composite design (CCD) was applied to appraisal the effect of these variables.ResultsResults showed that the adequate initial concentration for phenol removal, pH, contact time, and dosage of nZVI were at 5 mg/L, 2, 54.75 min, and 1.40 g, respectively. Also results showed that the adequate initial concentration for chlorophenol removal, pH, contact time, and dosage of nZVI were at 5 mg/L, 4, 70 min and, 1.33g, respectively.ConclusionAccording to the results of this study and high resistance in degradation by biological processes, iron nano particles can be used for phenol removal and its compound. Also, the results of the CCD showed that the fundamental parameters resulted from pH and phenol concentration having an intense effect on the efficiency.Keywords: nano particle, effluent, phenol, chlorophenol
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زمینه و هدففنل از جمله آلاینده های آلی موجود در پساب صنایع بوده که به شدت برای انسان و محیط زیست سمی می باشد. هدف از این مطالعه کاربرد پر شترمرغ به عنوان منبع طبیعی از اسید آمینه های فعال برای حذف فنل از محلول های آبی است.روش بررسیدر این مطالعه از پر شترمرغ به عنوان یک جاذب جدید برای حذف فنل در وزن های 2/0، 3/0، 5/0، 7/0، 1 و 5/1 گرم در 100میلی لیتر استفاده شد و تغییرات اثر زمان، pH، مقدارجاذب و دما در حین فرایند حذف و همچنین تبعیت فرایند جذب از معادلات فروندلیش و لانگمیرمورد بررسی قرار گرفت و از نرم افزار Excel برای تجزیه و تحلیل داده ها استفاده شد.
یافته هانتایج به دست آمده معلوم کرد که با افزایش مقدار ماده جاذب از g 2/0 تا g 7/0 میزان جذب افزایش می یابد. جذب فنل با افزایش مقدار pH محلول کاهش می یابد. همچنین این نتیجه به دست آمد که افزایش زمان تماس تاثیر ویژه ای (70درصد) در میزان جذب از محلول دارد.نتیجه گیریبه طور کلی، این جاذب به صورت موفق آمیزی برای تصفیه نمونه های آبی صنعتی و محلول های آبی می تواند به کار رود.
کلید واژگان: اسید آمینه, پرشترمرغ, جاذب, فنلBackgrounds andObjectivesPhenol is one of the organic pollutants that is found in industrial effluents and is very toxic for human and environment. This study proposes the use of ostrich feathers as a natural source of active amino acids to remove phenol from aqueous solution.Materials And MethodsFor this study، ostrich feather has been used as a synthetic adsorbent in removal of phenol in different doses 0. 2، 0. 3، 0. 5، 0. 7، 1، 1. 5 g/100 ml. Besides، the effects of changing contact time، pH، adsorbent dose and temperature has been determined. Description of adsorption Freundlich isotherm has also been accomplished and Excel software for analyzing the data was used.ResultsThe result obtained revealed that by increasing the dosage of the sorbent from 0. 2 g to 0. 7 g the adsorption increases. The adsorption of phenol decreases by the increase of the pH value of the solution. In addition، it is observed that the contact time significantly affect the rate of phenol adsorption (70%) from solution.ConclusionGenerally، the adsorbent was applied successfully for treating industrial water samples and aqueous solution. ►Please cite this paper as: Manshouri M، Yazdanbakhsh AR، Daraei H. Determine the Optimum Parameters of Phenol Removal from Industrial Effluents by Using Ostrich Feathers.Keywords: amino acids, ostrich feather, adsorbent, phenol -
زمینهفنل و ترکیبات آن از آلاینده های رایج محیطی هستند که به دلیل پتانسیل زیانشان برای سلامت انسان به عنوان آلاینده های اولویت دار شناخته شده اند. در این تحقیق، پتانسیل پر شترمرغ برای حذف فنل از محلول های آبی مورد بررسی قرار گرفت.روش هاحذف فنل از محلول های آبی با پر شترمرغ در سیستم بسته در شرایط گوناگونی از جمله اثر میزان ماده جاذب (در مقادیر 1/0، 2/0، 3/0، 5/0، 7/0، 1 و 5/1 گرم)، غلظت فنل اولیه (در مقادیر 50-1 میلی گرم در لیتر)، زمان تماس (در محدوده 30 دقیقه تا 30 ساعت) و pH (در محدوده 9-2) مورد بررسی قرار گرفت. همچنین تبعیت فرایند جذب از معادلات فروندلیش و لانگمیر بررسی شد. از نرم افزار Excel برای تجزیه و تحلیل داده ها استفاده شد.یافته هادر پروسه جذب سطحی ناپیوسته، زمان تعادل در 24 ساعت تماس حاصل گردید و میزان حداکثر حذف فنل، در میزان pH 2، برای غلظت 1 میلی گرم در لیتر فنل و مقدار ماده جاذب 7/0 گرم به دست آمد.نتیجه گیریپر شترمرغ توانایی مناسبی برای جذب فنل در غلظت های پایین دارد. با این حال توانایی این ماده و در نتیجه امکان استفاده از آن برای تصفیه فاضلاب های آلوده به فنل در غلظت های بالا محدود است.
BackgroundPhenol and its compounds are common environmental contaminants، which because of their potential harm to human health، are considered as priority pollutants. In this study، the potential of ostrich feather for phenol removing from aqueous solution was studied.MethodsRemoving the phenol from the aqueous solution was studied via considering the effect of absorbent (0. 1، 0. 2، 0. 3، 0. 5، 0. 7، 1 and 1. 5)، initial phenol concentration (1 to 50 mg/L)، contact time (30 min to 30 hr) and pH (2 to 9) in batch phase. The Description of adsorption Freundlich isotherm has also been accomplished and Excel Software was employed for analyzing the data.ResultsIn the Batch ion-exchange process، it reached equilibrium after about 24 hour of contact and the maximum removal of phenol received in the pH range 2 for an initial concentration of 1 mg/L and 0. 7 g adsorbent dose.ConclusionOstrich feather has higher adsorption capacity for phenol in low densities. However، the experimental results indicated that the capability of feather to absorb phenol and consequently its possible utilization in the treatment of phenol-contaminated solution and its adsorptive capacity is limited in high densities. -
حضور فنل در آب و فاضلاب به دلیل سمیت و تهدیدی که برای زندگی انسان و محیط دارد یک نگرانی عمده محسوب می گردد. در این مطالعه از پرشترمرغ به عنوان یک جاذب جدید برای حذف فنل در وزن های 2/0، 3/0، 5/0، 7/0، 1 و 5/1 گرم استفاده شد و تغییرات اثر زمان،pH، مقدارجاذب و دما در حین فرایند حذف و همچنین تبعیت فرایند جذب از معادلات فروندلیچ و لانگمیر مورد بررسی قرار گرفت. برای تجزیه و تحلیل داده ها از نرم افزار Excel استفاده شد. نتایج حاکی از آن است که با افزایش مقدار جاذب از 2/0 تا 7/0 گرم میزان جذب افزایش می یابد. همچنین مشاهده شد که جذب فنل با افزایش pH محلول کاهش می یابد و افزایش زمان تماس، تاثیر ویژه ای (70درصد) در میزان جذب دارد. همچنین موازنه جذب به خوبی توسط ایزوترم های جذب فروندلیچ و لانگمیر نمایش داده شدند. نتایج نشان می دهند که پر شترمرغ به عنوان یک ماده زائد در کشتارگاه ها، می تواند یک جاذب زیستی موثر برای حذف فنل به شمار رود.
کلید واژگان: پر شترمرغ, جاذب زیستی, بهینه, ایزوترمThe presence of phenol and its derivatives in water and wastewater are of major concern because of their toxicity and threat to human life and environment. In this study, ostrich feather has been used as a new adsorbent in removal of phenol in different doses of 0.2, 0.3, 0.5, 0.7, 1 and 1.5 g and the effects of changing contact time, pH, adsorbent dose and temperature has been determined. Then, the adsorption data were described with Langmuir and Freundlich adsorption isotherms and Excel software for analyzing the data was used. The results obtained revealed that by increasing the dosage of the sorbent from 0.2 to 0.7 g the adsorption increases. The adsorption of phenol decreases by the increase of the pH value of the solution. Also, it is observed that the contact time significantly affect the rate of phenol adsorption (70%) from solution. The adsorption equilibrium was well represented by the Freundlich and Langmuir adsorption isotherms. The results showed that the ostrich feathers, a solid waste produced in poultry processing plant, can be used as an effective biosorbent for removal phenol in aaqueous solution.Keywords: Ostrich Feather, Biosorbent, Optimal, Isotherm -
سابقه و هدففنل یکی از آلاینده های آلی موجود در پساب صنایع بوده و به شدت برای انسان و محیط زیست سمی می باشد. هدف از این مطالعه کاربرد خاکستر پر شترمرغ بعنوان جاذب طبیعی برای حذف فنل از محلول های آبی بود.مواد و روش هادر این مطالعه از خاکستر پر شترمرغ بعنوان یک جاذب جدید برای حذف فنل در مقادیر گوناگون (2/0، 3/0، 5/0، 7/0، 1، 5/1، 2 و 3 گرم) استفاده شد. تغییرات اثر زمان، pH، مقدارجاذب، دما و غلظت اولیه فنل بررسی گردید. سپس داده های جذب توسط ایزوترم های جذب فروندلیش و لانگمیر شرح داده شدند و از نرم افزار Ëxcel برای تجزیه و تحلیل داده ها استفاده شد.یافته هانتایج نشان می دهد که با افزایش مقدار ماده جاذب از g 2/0 تا g 2 میزان جذب افزایش می یابد. جذب فنل با افزایش مقدار pH محلول کاهش می یابد. همچنین مشاهده شد که افزایش زمان تماس تاثیر ویژه ای (77 درصد) در میزان جذب از محلول دارد.استنتاجبطور کلی، این جاذب مورد مطالعه بصورت موفق آمیزی برای تصفیه نمونه های آبی صنعتی و محلول های آبی می تواند بکار رود.
کلید واژگان: خاکستر پرشترمرغ, فنل, پساب صنعتیBackground andPurposePhenol is an organic pollutant that is found in industrial effluents and is very toxic to human and the environment. The purpose of this study was to use the ostrich feathers ash as a natural absorbent to remove phenol from aqueous solution.Materials And MethodsFor this study, ostrich feather ash was used as a new adsorbent in removal of phenol at different doses (0.2, 0.3, 0.5, 0.7, 1, 1.5, 2 and 3 g). Çhanges following the effect of contact time, pH, adsorbent dose, temperature and initial phenol concentration have been recorded. Then, the adsorption data were described with Langmuir and Freundlich adsorption isotherms and Ëxcel software was used for data analysis.ResultsThere is a dose-dependent relationship between phend adsorption by absorbent at doses ranging from 0.2-2 g. The adsorption of phenol decreases following an increase in the pH of the solution. Âlso, it is observed that the contact time significantly affects the rate of phenol adsorption (77%) from solution.Çonclusion: Generally, the studied adsorbent was applied successfully for treating industrial water samples and aqueous solution.
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