جستجوی مقالات مرتبط با کلیدواژه « کمربند ماگمایی ارومیه - دختر » در نشریات گروه « زمین شناسی »

The study area is situated 21 km SW of Ardestan city and 80 km NE of Esfahan (Central Iran). and according to the sedimentary structural divisions (Fig. 1; Aghanabati, 1998) in the central part of Urumieh-Dokhtar Magmatic Belt (UDMB) The UDMB in the Alpine-Himalayan orogenic belt, the most productive metallic belt of Iran, composed of basic to acidic volcanic and plutonic rocks, tuff and agglomerate. The UDMB represents geochemical characteristics of subduction zones with features of calc-alkaline locally toward alkaline (Berberian and Berberian, 1981; Alavi, 1994; Shahabpour, 2007; Omrani et al., 2008; Ghorbani and Bezenjani, 2011; Yeganehfar, 2013; Rajabpour et al., 2017). The UDMB hosts several porphyry Cu±Mo±Au deposits including Sungun, Sarcheshmeh, Kahang, Darehzar, Nowchun and Meiduk (Atapour and Aftabi, 2007; Zarasvandi et al., 2015; Zamanian et al., 2016; Alirezaei et al., 2017; Jamali, 2017) and associated porphyry copper-gold, gold epithermal and manganese-iron deposits (Rajabpour et al., 2017; Ostadhosseini et al., 2018; Alaminia et al., 2020; Ostadhosseini et al., 2021). Different stages of Cenozoic magmatic activity in the middle segment of the UDMB around the study area consist of different successions of volcanic and intrusive rocks (Radfar, 1998). The Eocene to Miocene diorite- monzodiorite bodies were intruded the Eocene volcanic and subvolcanic rocks. In the middle of the area, these intrusive units are juxtaposed with a fault boundary (Marbin fault) adjacent to Eocene volcanic units. 
 
The Eocene volcanic stage is dominated by basalt, andesitic basalt, andesite, tuffs and ignimbrites rocks. Quaternary sediments are widespread in the northeastern and southern parts of the area. The oldest rock unit of this area is the Shotori dolomite formation trending NW-SW and belonging to Triassic age and located in the southwest of the study area. Cu mineralization occurs within the Eocene volcano-sedimentary sequence. The purpose of this study is to determine the type of Cu mineralization based on the mineralization characteristics, geometry, texture, structure and alteration studies, as well as the geochemistry and tectonic environment of the host volcanic rock.
For the purposes of this study, 60 thin sections of volcanic rocks and 30 polished thin sections of ore samples were studied by a standard petrographic microscope under reflected and transmitted lights. 10 surface and drill–holes samples from volcanic rocks were crushed and powdered in tungsten carbide swing mill for whole-rock analysis. The chemical analyses were performed for the major elements using X-ray fluorescence (XRF) and trace elements using Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). Electron microprobe analyses were performed, using a JXA-8100 electron microprobe. Operating conditions were 35 kV accelerating voltage, a beam current of 20 nA, and a beam diameter of 2-10 μm.
All the petrographic studies as well as chemical analyses including XRF, ICP-MS and EPMA were carried out at the Seoul National University Laboratories, Seoul, South Korean.
The dominant rocks of the area under study are basalt, basaltic andesite, andesite and a small volume of pyroclastic rocks which are metaluminous composition and calc-alkaline affinity. Geochemically, they are enriched in LREE relative to HREE, enrichment of LILE and negative anomalies of HFSE (i.e., Nb, Ti), pointing to characteristics of subduction-related magmatic possibly generated by partial melting of metasomatized lithospheric mantle source. As the discrimination diagrams of tectonic setting display, the volcanic rocks are also classified as a subduction-related magmatic arc. Alteration zones were developed in the rock types including silicic, propylitic, argillic, sericitic and zeolitic. The propylitic and silicic alterations were extended within the mineralized zones. The propylitic alteration is the dominant alteration consisting mainly epidote, chlorite, and calcite. The silicification zone consists of crystalline quartz-formation, which occurs as veins and veinlets including some copper minerals. The carbonate alteration is observed in basaltic andesite and andesite rocks. Copper mineralization is mainly strata-bound, and occurs partially as veins, veinlets and disseminated in the andesite, basaltic andesites, and basaltic rocks. Based on microscopic studies, three mineralization stages were recognized in the Rahimabad deposit including pre-mineralization, mineralization, and post-mineralization stages. In the pre-mineralization stage, pyrite is formed in decreasing conditions in the host rock. In the main mineralization stage, pyrite is replaced by primary Cu and Ag sulfide minerals such as chalcopyrite, bornite, chalcocite, digenite, jalpaite and acanthite. Finally, in the post mineralization stage, copper sulfide minerals are replaced by secondary copper sulfide minerals (chalcocite, covellite and digenite) and oxide minerals (malachite, azurite, goethite and hematite).
The Rahimabad Cu (Ag) deposit lies in the SW of the Ardestan city in the Urumieh-Dokhtar Magmatic Belts, Central Iran. In this area, Cu and Ag mineralization is observed in the volcano-sedimentary rocks. The copper (Ag) mineralization occurs in andesite, basaltic andesite and basaltic lavas. These rocks are meta-aluminous and have a calc-alkaline affinity and indicate a subduction-related magmatic arc. The main alterations zones are silicic, propylitic, argillic, sericitic and zeolitic. The geometry of mineralization is strata-bound and the texture and structure of mineralization is open space filling, disseminated, vein-veinlet and replacement. Based on microscopic as well as EPMA data, the most important Cu and Ag minerals include chalcopyrite, bornite, chalcocite- covellite group minerals, malachite, azurite, acanthite and jalpaite, which are accompanied by magnetite and hematite. Pyrite is mostly observed as a separate mineral in the host rock. The overall mineralization characteristics and tectonic setting, the type of host rock, geometry, texture and structure, mineralogy and the paragenetic of Cu minerals and finally the alteration zones with different types of copper deposits document that the Rahimabad copper deposit share many features with those of Manto type copper deposits.
Acknowledgment
The present study was financially supported by the Cu-Au company of Ardestan. The authors are grateful to Mr. Sharif for providing sampling facilities and let us access to drill cores and exploration data.

The Sarkuh porphyry Cu deposit located in the Urumieh – Dokhtar Magmatic Belt (UDMB), is associated with the emplacement of Miocene intrusions mainly containing granite – granodiorite within Eocene units including tuff, andesite, basaltic andesite, and pyroclastic breccia. Potassic alteration of the deposit (dominated by magnetite, secondary and re-equilibrated biotites as well as anhydrite) is well extended. In this study EDX spectra of accessory minerals within potassic alteration was assessed to trace the occurrence of rare minerals. Additionally, EMPA results of magnetite paragenesis were linked to physicochemical attributes of rare minerals occurrences. Results indicate that unusual occurrence of Ce-La rich epidotes with REE-enriched monazites and Ce-bearing titanites are accompanied with apatite, anhydrite, hydrothermal biotite, quartz, and magnetite assemblages in the potassic alteration. Magnetite composition implies that early-stages high temperature magmatic – hydrothermal fluids (>500 °C) with low rates of fluid – rock interaction were contributed in the magnetite crystallization. Commonly, these magnetites are accompanied by hematite and anhydrite providing insights into the very high oxygen fugacity conditions (near magnetite - hematite buffers ~ ΔFMQ+4). Considering the chemistry of magnetite paragenesis, it seems that the occurrence of rare minerals are mainly associated pre-ore stages in the potassic alteration

Iju porphyry deposit is associated with the emplacement of Miocene tonalite-granodiorite intrusions (zircon U/Pb dating; 9.27±0.50) within Eocene volcanic and pyroclastic sequences including andesite, basaltic andesite, trachyandesite, andesitic breccias, tuffaceous breccias, and agglomerate. In this study, occurrence and chemistry of magnetites in the potassic alteration of Iju deposit were assessed using EMPA analysis. The findings imply for a limited occurrence of magnetite as fine-grained disseminated and/or product of biotite chloritization. Magnetites associated with potassic alteration of Iju deposit don’t show hematite intergrowth (as martitizied margin) and anhydrite paragenesis, indicating the lack of high oxygen fugacity (near magnetite-hematite buffers; ~ΔFMQ+4) during the magnetite crystallization in the potassic alteration. Studied magnetites are high temperature (>500 °C) and according to the Mg + Al + Si contents crystallized under low rate of fluid rock interaction. These evidences accompanied with the absence of reequilibration processes could imply for the lack of repeated stages of hydrothermal fluid exsolving during the evolution of potassic alteration in the in the Iju deposit. Additionally, results represent that there are considerable values of Ga (average; 0.015 wt. %) in the studied magnetites providing insights into the presence of unseen exploration potentials associated with porphyry Cu deposits of UDMB.

Taft area is located in the central part of Urmia-Dokhtar Magmatic Arc (UDMA), adjacent to Western block of Dehshir Major Fault, in the south of Yazd city. The UDMA is one of the favorable regions for occurrence of porphyry and Skarn copper deposits with more than identified 100 copper occurrences. It seemed that these Cu occurrences are related to structures, especially major and main faults. Therefore, the Taft area is selected for investigation on relationship between Cu mineralization and Tectonics (and structures). The Aliabad and Darre Zereshk are two important Cu indices in this area. In this research, the main structures are extracted and analyzed by using Remote sensing techniques, GIS environment and Field investigations. The results shown that a Structural Rhombohedral shape was created by two order faults with N150-170 and N110-120 strikes activation. In follow, the third-stage of faulting with N60-70 trend cut and offset the all of other formed structures and known as youngest order of faulting in this area. This stage of faulting was taken placed during initiation of collision between Arabian plate and Iranian Micro plates in Oligocene-Miocene episode. Because, this fault zone was formed perpendicular to collision zone, it has tension component and prepared a suitable environment for Granitoid body’s injection in this time. This phenomenon has main role in forming of Porphyry- Skarn Cu mineralization in length of this fault zone.

The Chahfiruzeh porphyry copper deposit is located at 35 Km northwest of Shar-e-Babak in Dehaj–Sarduieh part of the Urumieh- Dokhtar magmatic arc (UDMA). The world class porphyry Cu deposits, such as Sarcheshmeh, Meiduk, Sungun and several other Cu-porphyry in the UDMA have been numerously studied, for example: Boomeri, et al., (2009, 2010), and Asadi et al., (2014). The Chahfiruzeh Cu porphyry is divided into two parts of the southern and northern deposits. The southern deposit was studied by Hezarkhani (2006), and Sheikhzadeh et al., (2011). This paper studies the northern part to distinguish mineralized rock units, alteration types, mineralization style, ore mineralogy and geochemical characteristics. Geology of the northern part of the Chahfiruzeh area consists of upper Cretaceous-Eocene andesitic lava, pyroclastic and volcanoclastic rocks that have been intruded by Oligo-Miocene intermediate stocks and dikes (Dimitrijevic, 1973). Neogene rocks in the area are mainly alkali basalt to dacitic domes and Quaternary alluvium deposits. During the field studies more than 100 samples were taken from the boreholes and outcrops. Among them 25 thin sections and 39 polished sections were studied by microscopic methods, 6 samples from the alteration zones, 8 samples from the less altered rocks and 25 samples from the mineralized rocks were examined and analyzed by XRD, XRF and ICP-OES, respectively. The analyses and XRD data are presented in Tables 1, 2 and 4. The igneous rocks in the northern part occur as extrusive and intrusive. The extrusive rocks are dacite and andesite and intrusive rocks are diorite, granodiorite and quartzdiorite. They are porphyry in texture and high-K calc-alkaline in magmatic series. The main mineral in all rocks is plagioclase that has variable size, shape and texture. K-feldespar, amphibole, biotite and quartz are other primary minerals in the study rocks. Biotite, quartz, and K-feldspar occur also as secondary minerals that are associated with chlorite, sericite, clays minerals and sulfide and oxide minerals. Mineralization can be usually divided into the two hypogene and supergen types. The hypogene mineralization occurs mainly as silicic veinlets and disseminated in the intrusive porphyries and volcanic rocks. The silicic veins are in eleven types as follows: 1) quartz + chlorite + pyrite, 2) quartz + chlorite , 3) quartz + pyrite , 4) quartz , 5) chlorite , 6) pyrite + chalcopyrite + quartz , 7) quartz + magnetite , 8) pyrite , 9), chalcopyrite , 10) quartz + chalcopyrite + bornite, 11) molybdenite. The hypogene sulfides are pyrite, chalcopyrite, bornite and molybdenite that are associated with magnetite, hematite and ilmenite. The pyrites and chalcopyrites occur in all parts of the mineralized area from the surface to the depth while molybdenites and bornites occur only in the deep depths. The supergene mineralization occurs as small outcrops of iron oxide and hydroxide, copper carbonate and clay minerals. The alteration zones in the mineralized area are potassic, propylitic, phyllic and argillic. The main alteration is potassic that is characterized by biotite, sericite and chlorite and numerous sulfide-bearing silicic veinlets with or without orthoclase and magnetite. The orthoclase is probably present as anhedral in some parts and around the plagioclase. The hydrothermal biotites are fine and thin in shape and occur in groundmass. Magmatic biotites are also present as euhedral to subhedral grains. The propylitic alteration observes only in the surface as an outer zone and characterized mainly by chlorite and epidote. Calcite and clay minerals are other minerals of this zone while sulfides are rare. The phyllic alteration zone is characterized by a higher proportion of sericite, quartz veins and pyrite than the potassic alteration in the marginal parts of the mineralized area. The argillic alteration zone occurs locally in shallow depths. Based on XRD analyses, each one of the clay minerals such as kaolinite, montmorillonite, illite and dickite, are dominant in some samples.
The alteration map of the northern part is presented in Fig.15 for two depths of 10 and 400 meters. The potassic alteration is the main alteration type in both levels. In level 10, the inner potassic alteration is surrounded by phyllic and outer propylitic alteration, while in level 400, the inner potassic alteration is only associated with the local phyllic alteration. Distribution of copper and molybdenum in different boreholes indicate that mineralization has occurred mainly in the potassic and phyllic alteration zones (Fig. 16). The copper shows similar contents from shallow to deeper depths while Mo contents are higher in the depths of more than 500 meters (Fig. 16).
The following features show that the northern part of Chahfiruzeh ore deposit is a porphyry Cu-type ore deposit: style, grade, size and shape of the mineralization, alteration types, associated calc-alkaline intrusive porphyries and the tectonic setting.

Javinan skarn is located at 115 km north west of Isfahan (40 km south of Kashan and east of Ghohrud), is included in Central Iran structural zone and spread in contact with Ghohrud granitoid (Middle Miocene age) with shale, sandstone and limestone succession of the Jurassic age known as Shemshak Formation. Skarnification is made up of endo- and exoskarn subzones. Wide mineralization in these skarns hasn’t observed. Endoskarn subzone has limited occurence (from a few millimeters to a few centimeters) and exoskarn has the greatest development (from 1 meter to more than 10 meters). Endoskarn with the formation of the skarn minerals garnet, pyroxene, plagioclase, epidote and sphene, is formed in the intrusive host rock and is in the vicinity of the carbonate part. In its immediate neighborhood, exoskarn subzone starts with the formation of minerals garnet, pyroxene, idocrase, epidote, phlogopite, chlorite, quartz and calcite in the carbonate section. Mineralogical studies and textural relationship of minerals have shown that the metamorphic facies اhas reached to pyroxene hornfels in skarn rocks of this area.

Dehaj-Meiduk area is located at North of Shahre-babak. There are nine porphyry intrusive bodies in this region, which include Meiduk, Parkam, Iejoo, Segino, Chah Firouzeh, Narkoh, Ayoub Ansar, Sara and Keder. Meiduk, Chah Firouzeh, Parkam, Iejoo and Segino are productive among them and Narkoh, Keder, Ayoub Ansar and Sara are barren. These intrusive bodies are mostly composed of porphyry diorite, quartzdiorite and granodiorite. Geochemical studies indicate that the magma of these rocks has the peraluminous to metaluminous nature and magma series are calc-alkaline with high potassium and shoshsonitic nature. The geochemical variation diagrams of major oxides and minor elements, illustrate the continuous spectrum of rock compositions for the studied samples, which indicates high crystallization differentiation during magmatic processes. Field observations, petrographic and geochemical studies suggest that the rocks in the Dehaj-Meiduk area are I type. All available data demonstrate that these rocks are result of subduction of Neotethyan oceanic crust beneath the central Iran continental crust. Flat subduction happened in some parts of the study area and because of that, partial melting rate has been low and as a result adakitic rocks are produced. The adakitic rocks have formed intrusive bodies in Pliocene. Since magma is depleted in metallic elements by forming earlier stage productive plutons, the later rocks do not contain metallic elements and are barren.

IntroductionThe formation of porphyry copper deposits is attributed to the shallow emplacement, and subsequent cooling of the hydrothermal system of porphyritic intrusive rocks (Titley and Bean, 1981). These deposits have usually been developed along the chain of subduction-related volcanic and calc-alkalin batholiths (Sillitoe, 2010). Nevertheless, it is now confirmed that porphyry copper systems can also form in collisional and post collisional settings (Zarasvandi et al., 2015b). Detailed studies on the geochemical features of ore-hosting porphyry Cu-Mo-Au intrusions indicate that they are generally adakitic, water and sulfur- riched, and oxidized (Wang et al., 2014). For example, high oxygen fugacity of magma has decisive role in transmission of copper and gold to the porphyry systems as revealed in (Wang et al., 2014). In this regard, the present work deals with the mineral chemistry of amphibole and plagioclase in the Dalli porphyry Cu-Au deposit. The data is used to achieve the physical and chemical conditions of magma and its impact on mineralization. Moreover, the results of previous studies on the hydrothermal system of the Dalli deposit such as Raman laser spectroscopy and fluid inclusion studies are included for determination of the evolution from magmatic to hydrothermal conditions.
Materials and methodsIn order to correctly characterize the physical and chemical conditions affecting the trend of mineralization, 20 least altered and fractured samples of diorite and quartz-diorite intrusions were chosen from boreholes. Subsequently, 20 thin-polished sections were prepared in the Shahid Chamran University of Ahvaz. Finally, mineral chemistry of amphibole and plagioclase were determined using electron micro probe analyses (EMPA) in the central lab of the Leoben University.
ResultsAmphibole that is one of the the main rock-forming minerals can form in a wide variety of igneous and metamorphic rocks. Accordingly, amphibole chemistry can be used as an indicator for characterizing the conditions involved during the evaluation of magma crystallization i.e., pressure, temperature, liquid water content and oxygen fugacity. Most recent studies on the porphyry copper intrusions in the Urumieh- Dokhtar magmatic arc by (Zarasvandi et al., 2015a), indicate that all of the mineralized porphyry systems (Dalli porphyry is included) consistently show high levels of La/Sm and Sm/Yb, with concave upward patterns in the rare earth elements’ spider diagrams. Importantly, such features indicate high crustal assimilation in a relatively thickened crust and provide insight into the contribution of hornblende during the development of mineralized porphyry systems in the Urumieh- Dokhtar belt. The results of this study indicate that amphiboles of Dalli intrusions belong to the calsic group and range in composition from magnesio- hornblende, to edenite, magnesiohastingsite, and tschermakite. (Ridolfi et al., 2010), indicating that the alumina content of amphibole could be used for geobarometry. The calculations of geobarometry for quartz diorite intrusions of Dalli indicate that they formed in the pressure range of 136 to 287 (MPa). Also, calculation of magmatic water content using amphibole geochemistry indicates that the water content of quartz diorite intrusions in the Dalli were between 4.6- 5.7 (wt. %). The results of plagioclase chemistry indicate that there is a little zoning in this mineral. Also, the plagioclase composition varies from Or0.01 to Ab 0.48, An 0.50, Or 0.018, Ab 0.62 and An 0.35. They mostly have Andesine and Labradorite compositions.
DiscussionAmphibole minerals of the Dalli intrusions are calcic type and exhibit geochemical signatures of subduction zones. Also, characterizing the source of ore-hosting intrusions with amphibole chemistry indicate that parental magma of Dalli intrusion were generated from mixing of mantle melts with crustal materials. It seems that in an ongoing process of closure of Neo-Tethys, during compression and crustal shortening favourable conditions were provided for mixing of mantle melts with crustal materials. The geothermobaromerty calculations using amphibole and plagioclase minerals indicate conditions of 777 - 850 oC and 1-4 Kbar, representing magmatic stage of Dalli intrusions. Also, amphibole minerals are characterized by Fetot/Fetot Mg > 0.3 and AlIV > 0.7 which reveal the presence of primary oxidative magma in the Dalli porphyry Cu-Au deposit. Oxidative conditions seem to have prevailed during the onset of the hydrothermal stage of the Dalli porphyry deposit. This is because it has been confirmed by laser Raman spectroscopy analyses that the most primitive quartz veins in the potassic alteration of the Dalli deposit are characterized by the presence of anhydrite and hematite minerals (see Zarasvandi et al., 2015b). Also, microthermometry results on the most primitive barren quartz veins in potassic alteration represent temperatures as high as 620oC which indicate the beginning temperature of hydrothermal conditions.