جستجوی مقالات مرتبط با کلیدواژه « Blend » در نشریات گروه « شیمی »
تکرار جستجوی کلیدواژه «Blend» در نشریات گروه «علوم پایه»-
The work entails the viscometric study of a common plant gum found in Nigeria (Acacia Senegal) blended with polyacrylamide (PAM). The gum was purified after collected and mixed in specific ratios of 10:90, 30:70, 50:50, 70:30 and 90:10 with PAM, before they were subjected to rheological study. The intrinsic, relative and specific viscosity for the bends were determined and presented in the research work. The plots of the relative viscosity against concentration of the gums at different temperature vary significantly at higher concentration, while the viscosity for gum Arabic/PAM (90:10) showed the most distinct variation between different temperatures. The result was found to be agreement with some other similar research in the literature. PAM was found to be more viscose than gum Arabic at both temperatures, while the viscosity index such as intrinsic, specific and relative viscosity for the synergistic combination between the polymers were found to decrease as we increased the composition of gum Arabic within the blend.Keywords: PAM, Gum arabic, Polymer, Blend, Viscosity}
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Polypropylene / polystyrene blends containing montmorillonite (MMT) were prepared using a twin screw extruder followed by fiber spinning. The melt intercalation of PP and PS alloys was carried out in the presence of a compatibilizer such as maleic anhydride-g-polypropylene (MPP). The crystallization morphology, thermal behaviors and mechanical properties of polypropylene/polystyrene (PP/PS) nanoclay blends nanocomposite fibers were investigated in the present work. The improved adhesion between the phases and fine morphology of the dispersed phase contributed to the significant improvement in the properties and thermal stability of the final nanocomposite materials. On the basis of this result, we describe a general understanding of how the morphology is related to the final properties of OMMT- incorporated PP/PS blends.Keywords: polypropylene, Polystyrene, Blend, Organoclay, Nanocomposite, Morphology, properties}
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در این پژوهش، رفتار جذب آب آمیخته های زیست تخریب پذیر پلی اتیلن سبک - نشاسته گرمانرم بررسی شده است. نشاسته گرمانرم از اختلاط نشاسته خالص با 35% وزنی گلیسیرول با استفاده از مخلوط کن داخلی در دمای oC140، دور rpm 60 و به مدت 8 دقیقه به صورت مذاب به دست آمد. آمیخته های پلی اتیلن سبک - نشاسته گرمانرم دارای درصدهای گوناگون نشاسته (10 تا 40% وزنی) با (3% وزنی) و بدون PE-g-MA، با استفاده از اکسترودر تک مارپیچه تهیه شدند. آزمون جذب آب در دمای محیط و با استفاده از روش استاندارد مربوطه انجام گرفت. نتیجه ها نشان داد که با افزایش مقدار نشاسته گرمانرم و نیز افزایش زمان غوطه ور کردن نمونه ها، جذب آب آنها افزایش می یابد تا اینکه به مقدار ثابتی می رسد. پس از گذشت 21 روز از غوطه ور کردن نمونه ها، افزایش در جذب آب به میزان 5 /10% برای نمونه دارای 40% نشاسته و بدون سازگارکننده، و 3/16% برای نمونه سازگار شده دارای 40% نشاسته به دست آمد. نتیجه ها همچنین نشان داد که ویژگی های کششی از قبیل استحکام کششی نهایی و مدول یانگ پس از غوطه ور کردن نمونه ها کاهش پیدا می کند.
کلید واژگان: پلی اتیلن سبک, نشاسته, آمیخته, جذب آب, ضریب نفوذ, زیست تخریب پذیر}In this work, water absorption behaviour of biodegradable low density polyethylene-thermoplastic starch (LDPE-TPS) blends is investigated. Thermoplastic starch was prepared by melt mixing starch and glycerol (35 wt.%) using an internal mixer at 140 °C and rotor speed of 60rpm for 8 minutes. LDPE/TPS blends containing various amounts of starch (10-40 wt.%) were prepared with (3 wt.%) and without PE-g-MA using single screw extruder. Water absorption test was carried out at room temperature and using related standard methods. The results indicate that with increase in TPS content and also increasing the immersion time, water absorption increase unit the constant value is obtained. After 21 days of the immersion time, 10.5% and 16.3% increase in water absorption were obtained for uncompatibilized and compatibilized blends containing 40 wt.% TPS, respectively. The results also show that after immersion tests, the tensile properties such as ultimate tensile strength and Young's modulus decrease.Keywords: LDPE, Starch, Blend, water absorption, Diffusion coefficient, Biodegradable} -
Polycaprolactone (PCL) and poly(butylene terephthalate) (PBT) blend was prepared by melt processing. The PCL/PBT blend showed similar morphology with that of pure PCL.The crystallization temperature of PCL was increased by the incorporation of PBT. It was also observed that the peak height in the DSC thermograms decreased and then disappeared by adding 40 % or more PBT which might be due to the transestrification between –OH end groups of PCL and ester groups of PBT. The size of PCL spherulites was about 13 µm which decreased highly in the case of blends due to the nucleation effect. The thermal stability of the PCL/PBT blend was higher than pure PCL.Keywords: Polycaprolactone, Blend, morphology, Thermal properties}
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