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جستجوی مقالات مرتبط با کلیدواژه "wastewater" در نشریات گروه "محیط زیست"

تکرار جستجوی کلیدواژه «wastewater» در نشریات گروه «علوم پایه»
  • میترا غلامی مقدم، فریبا استوار *، محدثه توکلی

    هدف از این پژوهش، بررسی تصفیه پذیری پساب صنایع غذایی آماده با استفاده از فرآیند شیمیایی انعقاد و لخته سازی بود. در این فرآیند از منعقد کننده فریک کلراید (FeCl3) به همراه کمک منعقد کننده های پلی آکریل آمید و آهک استفاده شد.  به منظور بررسی اثر متقابل پارامترهای تاثیرگذار بر فرآیند تصفیه، نرم افزار طراحی آزمایش (DOE) به مدل مرکب مرکزی (CCD) مورد استفاده قرار گرفت. عوامل تاثیرگذار بر فرایند انعقاد و لخته سازی از قبیل غلظت منعقد کننده FeCl3 در محدوده ی غلظتی mg/L500-2000، pH اولیه در محدوده ی 10-5، کمک منعقدکننده ی آهک و پلی الکترولیت به ترتیب با غلظت های mg/L 25-100 و mg/L 5/2 -5/0 توسط دستگاه جارتست مورد ارزیابی قرار گرفتند. برای تعیین مقادیر بهینه، میزان اکسیژن خواهی شیمیایی (COD) به عنوان آزمون هدف انتخاب شد. مقایسه ی شرایط بهینه ی تک عامله و اثر متقابل داده ها با استفاده از نرم افزار طراحی آزمایش، مقدار بهینه ی pH برابر 5/7، غلظت منعقدکننده FeCl3 به مقدار mg/L 1250و کمک منعقد کننده های آهک و پلی الکترولیت به ترتیب با غلظت های mg/L 60 و 5/1، راندمان حذف COD برابر 15/94 % را نشان داد. بررسی های آماری نشان داد، مقدار F-value برابر 48/19، نشان دهنده ی مطابقت خوب این مدل با نتایج آزمایشگاهی است. همچنین، مقادیر P-value کمتر از 0500/0، بیانگر معنی دار بودن آزمایش است. با مقایسه نتایج آزمایشگاهی و نتایج پیش بینی شده نرم افزار، همبستگی خوبی بین نتایح مشاهده گردید. درنهایت، نتایج حاصل از پژوهش نشان داد که تصفیه ی پساب کارخانه ی صنایع غذایی با استفاده از منعقدکننده ی FeCl3 امکان پذیر بوده و پساب تصفیه شده، استانداردهای تخلیه به زمین های کشاورزی برای آبیاری مزارع را داراست.

    کلید واژگان: پساب, صنایع غذایی آماده, انعقاد و لخته سازی, جارتست, آهن (III) کلراید, COD
    Mitra Gholami Moghadam, Fariba Ostovar*, Mohadese Tavakoli

    This research aims to investigate the treatability of prepared food industry wastewater using the chemical process of coagulation and flocculation.  Ferric chloride (FeCl3) coagulant was used in this process along with polyacrylamide and lime flocculant aids. In order to investigate the mutual effect of the parameters affecting the treatment process, the design of experiments (DOE) software with the central composite model (CCD) was used. Effecting factors on the coagulation and flocculation process such as FeCl3 coagulant concentration in the concentration range of 500-2000 mg/L, initial pH in the range of 5-10, lime and polyelectrolyte with the concentration ranges of 25-100 mg/L and 0.5-2.5 mg/L respectively were evaluated by Jartest device. Chemical oxygen demand (COD) analysis was chosen as the target test to determine the optimal values. Comparison of optimal conditions of single agent and mutual effect of data using experiment design software, an optimal value of pH equal to 7.5, FeCl3 coagulant concentration of 1250 mg/L, and coagulants of lime and polyelectrolyte with concentrations of 60 and 1.5 mg/L respectively, showed COD removal efficiency of 94.15%. Statistical analysis showed that the F-value equal to 19.48 indicates the good agreement of this model with the laboratory results. Also, P-values less than 0.050 indicate the significance of the test. By comparing the laboratory and the predicted results, a good correlation between the results was observed. Finally, the results of this research showed that it is possible to treat the wastewater of the food industry using FeCl3 coagulant, and the treated wastewater meets the standards of discharge to agricultural lands for fields irrigation

    Keywords: Wastewater, Prepared Food Industry, Coagulation, Flocculation, Jar Test, Iron (III) Chloride, COD
  • A.A. Kiswandono *, N. Ningsih, A.V. Sindiani, Rinawati ., H.I. Qudus
    BACKGROUND AND OBJECTIVES
    The The swift advancement of the industrial sector raises concerns due to its detrimental impact on the environment, notably in the production of pollutants, such as organic substances like phenol. These compounds are corrosive and toxic to the environment. The study for transport of phenol using copoly eugenol-diallyl phthalate as a carrier based on membrane of polytetrafluoroethylene with supported liquid membrane method was conducted to handle phenol solution. This study seeks to mitigate phenol waste by employing an 8 percent copolymer of eugenol and diallyl phthalate through the supported liquid membrane method. Furthermore, it aims to assess the effectiveness of phenol transport and separation using this membrane technique. The objectives of this study was  contributed to the reduction of phenol solution with copoly eugenol diallyl phthalate 8 percent which was utilized from cross linked eugenol using supported liquid membrane method.
    METHODS
    This study was carried out with several variations, namely source phase power of hydrogen, receiving phase sodium hydroxide concentration, immersion time for supported liquid membrane, carrier concentration and time transport of phenol. This study for membrane evaluation was conducted to use the parameters such as concentration and type of salt, as well as lifetime. Fourier Transform Infrared Spectroscopy was employed to characterize the membrane, assessing its properties before and after the transport process in order to delineate the functional groups associated wit the membrane. Phenol concentration was determined using an ultraviolet-visible spectrophotometer with 4-aminoantipyrine reagent at a maximum wavelength of 455 nanometer.
    FINDINGS
    The phenol transport test showed that membrane containing copoly eugenol-diallyl phthalate 8 percent was successful in transporting phenol with the conditions such as power of hidrogen of 5.5 in the source phase, 0.25 molar sodium hydroxide concentration for receiving phase, immersion time membrane was 90 minutes, carrier concentration 0.005 molar for 24 hours. The results of the study revealed that portions of the membrane were damaged during the transport process. This conclusion was further validated by the outcomes of the supported liquid membrane technique and the characterization conducted through Fourier transform infrared spectroscopy.
    CONCLUSION
    The supported liquid membrane containing copoly eugenol diallyl phthalate 8 percent was able to transport phenol even though some membrane components were lost. The presence of 1 molar sodium nitrate salt enhances the durability of the supported liquid membrane, resulting in a lifespan of 15 days, whereas the membrane without the salt addition only lasts for 6 days. This study has significantly enhanced the recovery of phenol solutions, achieving a phenol recovery rate of 87.77 percent, while also successfully prolonging the lifespan of membrane.
    Keywords: Copoly Eugenol-Diallyl Phthalate, Phenol, Supported Liquid Membrane, Wastewater
  • زهره عبادتی*، رضا ارجمندی، علی محمدی
    زمینه و هدف

    یکی از مهم ترین مشکلات ناشی از توسعه صنعتی و خدماتی در شهرستان ری تولید حجم بالایی از فاضلاب است که تخلیه غیر اصولی آن به محیط زیست می تواند، منجر به آلودگی منابع آب سطحی و منابع آب زیرزمینی شده و یا با استفاده از آن در مصارف کشاورزی باعث آلودگی خاک گردد. از این رو در این تحقیق مراکز صنعتی و خدماتی تولید کننده فاضلاب در شهرستان ری جهت ارائه راهکار برای بهبود وضعیت شناسایی و مورد بررسی قرار گرفت.

    روش بررسی

    در این پژوهش کانون های آلودگی فاضلاب در سطح شهرستان ری شناسایی و بررسی خصوصیات شیمیایی و بیولوژیکی فاضلاب این مراکز شامل پارامترهایpH، COD، BOD  و  Total Coliform  بر اساس میانگین دوره زمانی دو ساله (1395 - 1394) انجام و نقشه پراکنش مکانی غلظت آلاینده های فاضلاب خروجی مربوط به این مراکز  با استفاده از نرم افزار GIS و روش پهنه بندی IDW <!- [if !supportFootnotes]->[1]<!-[endif]-> تهیه شد.

    یافته ها

    در این بررسی 17 کانون اصلی تولیدکننده فاضلاب ازجمله 7 کشتار گاه دام و طیور، 1 مرکز دفع زباله و 1کارخانه روغن نباتی، در شهرستان ری شناسایی شد.

    بحث و نتیجه گیری

    نتایج نشان می دهد، موثرترین راه کارها برای بهبود وضعیت، تجهیز واحدهای آلاینده به سیستم تصفیه فاضلاب و بهبود سیستم تصفیه فاضلاب در واحدهایی که دارای سیستم تصفیه هستند. هم چنین کاهش آب مصرفی در فرآیند تولید که منجر به کاهش میزان فاضلاب تولیدی می شود و نظارت و پایش سازمان های مسئول در این زمینه می باشد.

    کلید واژگان: آلودگی آب, آلودگی خاک, فاضلاب, پهنه بندی, فاضلاب واحد های صنعتی و خدماتی, بهبود وضعیت.
    Zohreh Ebadati *, Reza Argmandi, Ali Mohammadi
    Background and Objective

    One of the most important problems caused by industrial and service development in Ray city is the production of a high volume of wastewater that its non-systematic discharge to the environment can lead to contamination of surface water and groundwater resources or by using it in agricultural uses Soil contamination. Therefore, in this research, the industrial and service centers of the waste water producer in Ray city were identified to provide a solution to improve the status.

    Material and Methodology

    To this end, wastewater contamination centers in the Ray city were identified and the chemical and biological properties of wastewater of these centers including pH, COD, BOD and Total Coliform were evaluated based on the average two-year period (1395-1394) and the spatial distribution map of concentration The wastewater pollutants associated with these centers in the Ray city were prepared using the GIS software and the IDW zoning method.

    Findings

    In this study, 17 main waste water   producers were identified, including seven livestock and a waste disposal center and a vegetable oil factory in Ray city.

    Discussion and conclusion

    The results show that the effective strategy   to improve the situation, equipping the pollutant units with the wastewater treatment system, and improving the wastewater treatment system in units that have a purification system, as well as reducing water consumption in the production process, which leads to a reduction in the amount of wastewater produced. And monitoring of responsible organizations in this field.

    Keywords: Water Pollution, Soil Pollution, Wastewater, Zoning, Industrial Wastewater, Water Quality Improvement
  • ملیحه امینی*، نرجس اکاتی، زهرا امینی خوئی، الناز عرفانی فر
    زمینه و هدف

    استفاده از ریزجلبک ها راهکاری موثر در فرآیند تصفیه پیشرفته فاضلاب به منظور حذف مواد مغذی می باشد. در این مطالعه ریزجلبک زنده Dunaliella salina پس از کشت برای انجام یک سری آزمایش های ناپیوسته و حذف نیترات و فسفات از فاضلاب استفاده شد.

    روش بررسی

    اثر تغییر غلظت نیترات و فسفات (13-5/2 میلی گرم بر لیتر) در محیط کشت بر میزان حذف این مواد مغذی در دوره رشد 12 روزه توسط جلبک D.salina در آزمایشگاه مرکز تحقیقات آب های دور چابهار در سال 1397 مورد بررسی قرارگرفت.

    یافته ها

    براساس نتایج بیشترین میزان حذف نیترات و فسفات توسط D. salina به ترتیب 5/51% و 4/93% به دست آمدند. بالاترین میزان حذف مواد مغذی پس از نمونه شاهد در 5/2 میلی گرم بر لیتر به دست آمد. میزان حذف فسفات در همه غلظت ها از نیترات بالاتر بود و این نشان می دهد که جلبک D. salina قابلیت رشد و سازگاری بالاتری در فاضلاب های آلوده به فسفات دارد. البته میزان حذف نیترات نیز قابل توجه و کاربردی در سیستم های تصفیه فاضلاب است. مدل های تعادلی Langmuir و Freundlich نیز در رابطه با نحوه جذب یون های مواد مغذی از محلول توسط ریزجلبک زنده بررسی شدند. فرآیند جذب با مدل تعادلی Langmuir با میزانR2 87/0 و 56/0 به ترتیب برای نیترات و فسفات مطابقت بیشتری داشت.

    بحث و نتیجه گیری

    نتایج این تحقیق نشان داد که زیست توده D.salina ، بیوجاذبی مناسب برای حذف و جذب یون های نیترات و فسفات از محلول های آبی و فاضلاب ها ا ست.

    کلید واژگان: فاضلاب, فسفات, نیترات, میزان حذف, Dunaliella Salina
    Malihe Amini *, Narjes Okati, Zahra Amini Khoei, Elnaz Erfani Far
    Background and Objective

    The use of microalgae is an effective path in the process of advanced wastewater treatment in order to remove nutrients. In this study, living microalgae, Dunaliella salina was cultivated and then used in a series of batch experiments for the removal of nitrate and phosphate from wastewater.

    Material and Methodology

    The effect of changes in NO3- and PO43- concentrations (2.5-13 mg/l) on the removal efficiency using D. salina was evaluated during the 12-day growth period in the laboratory of Offshore Fisheries Research Center, Chabahar, 2017.

    Findings

    Results indicated that the maximum nitrate and phosphate removal efficiency using D. salina were 51.5% and 93.4%, respectively. The range of initial nitrate and phosphate concentrations were 0, 2.5, 5, 7.5, 10 and 12 mg/l and among them, the highest efficiency of nutrients removal after the control sample was obtained in 2.5 mg / l concentration of nitrate and phosphate. Phosphate removal efficiency was higher than nitrate at all concentrations and this shows that living microalgae D. salina has a good compatibility for growth in phosphate-contaminated wastewater. However, nitrate removal percentage is also significant and applicable to wastewater treatment systems. The Langmuir and Freundlich equilibrium models were also investigated in absorption process from solutions by living microalgae and the results of experiments were more consistent with Langmuir equilibrium model with R2 levels of 0.87 and 0.56 for nitrate and phosphate, respectively.

    Discussion and Conclusion

    The results of this investigation suggested that D. salina is suitable as a biosorbent material for recovery and biosorption of nitrate and phosphate ions from aqueous solutions and wastewaters.

    Keywords: Wastewater, Phosphate, Nitrate, Removal Percentage, Dunaliella Salina
  • Belhadj Khouloud *, Mimeche Leila, Lynda Hecini, Rahmani Bahi Eddine, Belhadj Amina
    Constructed wetlands (CWs) have been widely recognised for efficiently removing many pollutants from wastewater, making them vital for environmental bioremediation. The substrates used in constructed wetlands are crucial in determining their overall performance, notably their ability to improve nitrogen and phosphorus removal from wastewater. This study aims to investigate the possibility of removing pollutants from wastewater using a pilot scale vertical flow constructed wetland (VFCW) planted with Phragmites australis applied to various substrates, such as gravel and sand in an arid climate in Southeast Algeria.The study involved using four basins, filled with sand and gravel. Two were planted with Phragmites australis and the others were left as a control without vegetation. The efficiency of the filtration systems was evaluated based on various physicochemical and organic parameters. Results showed that the highest hydraulic retention time is in the 7 days. The removal efficiency values are 84.38% for biological oxygen demand (DBO5), 77.45% for chemical oxygen demand (COD), and 83.30% for total solid matter (TSS) in the planted gravel filter. The planted sand filter had even higher removal efficiency values, with 89.59%, 85.80%, and 86.63% for DBO5, COD, and TSS, respectively. Nitrate concentration increased in all filters due to the complete transformation of ammonium into nitrate. NO2-, NH4+, and PO43- removal efficiencies were also higher in the planted sand filter 74.45%, 95.43%, and 77.64%, respectively.
    Keywords: Substrate, Phragmites Australis, HRT, Wastewater, Arid
  • محدثه توکلی *، محمدجواد چایچی

    تالابها، یکی از بارزترین زیست بوم های دنیا هستند. این زیستگاه های حیاتی و متنوع، ازجمله نظام های حیات بخش فاقد جایگزین به حساب می آیند. لیکن، هیچ یک از زیست بوم های جهان به اندازه ی تالاب ها صدمات و خسارات انسان محور را تجربه نکرده اند. از عوامل اصلی تهدید تالاب های گیلان، عوامل انسانی مانند فاضلاب های شهری و خانگی، صنعتی، صید بی رویه و تبدیل زمین های حاشیه ی برای بررسی پارامتر کیفی آب ،RGB تالاب به زمین های کشاورزی هستند. در این مطالعه، از تصاویر تالاب انزلی (ایستگاه جزیره ی بهشتی)، استفاده شد و داده های مربوط به آن، با مقادیر حاصل از در تصاویر (R) مقایسه شد. براساس داده های به دست آمده، شدت رنگ قرمز TSS سنجش ماکروسکوپی (با چشم غیرمسلح) از تالاب، می تواند یک شاخص محیط زیستی، به منظور اندازه گیری نیز، برای رنگ قرمز با ضریب همبستگی RGB باشد. بررسی نتایج حاصل از آنالیز TSS غلظت با ضریب همبستگی (B) 0 و برای رنگ آبی / با ضریب همبستگی 382 (G) 0/3118 ، برای رنگ سبز و RGB بین کاهش مقادیر) R2=0/ 0/668 ، به دست آمد. در نهایت، یک ضریب همبستگی (3081 و آزمون عمق سکی، در این مطالعه pH حاصل شد. پارامترهای دیگری، مانند ،TSS افزایش غلظت مورد سنجش قرار گرفتند.

    کلید واژگان: تالاب, فاضلاب, آلاینده, RGB, TSS
    Mohadese Tavakoli *, Mohammadjavad Chaeichi

    Wetlands are one of the most prominent ecosystems in the world. These vital and diverse habitats are among life-giving systems that have no alternative. However, none of the world's ecosystems have experienced human-centered injuries and damages as much as wetlands. One of the main threats to Gilan wetlands are human factors such as urban, domestic and industrial wastewater, overfishing and converting wetland marginal lands into agricultural lands. In this study, RGB images were used to assess the water quality parameters of Anzali wetland (Beheshti Island Station) and the related data were compared to the values obtained from the TSS measurement. Based on the obtained data, the intensity of red color (R) in the macroscopic images (with the naked eye) from the wetland can be an environmental indicator to measure TSS concentration. The results of RGB analysis for red color with a correlation coefficient of 0.8513, for green color (G) with a correlation coefficient of 0.832 and for blue color (B) with a correlation coefficient of 0.663 were obtained. Finally, a correlation coefficient (R2=0/8035) between the decrease of RGB values and the increase of TSS concentration was obtained. Other parameters such as pH and Secchi Depth test were also measured in this study.

    Keywords: Wetland, Wastewater, Pollutants, RGB, TSS
  • Reza Cheraghi, Maryam Abrishamkar *, Hossein Jalali Jahromi, Farzaneh Hoseini
    The applicability of Polyetheretherketone/polyvinylalcohol nanocomposite modified with zinc oxide nanoparticles synthesis for the removal of benzyl butyl phthalate from wastewater. Identical techniques, including BET, FT-IR, XRD, and SEM, have to characterize this unknown material. The investigation shows the applicability of adsorbent PEEK/PVA/ZnONPs, as an available, suitable, and low-cost adsorbent for adequately removing the benzyl butyl phthalate from wastewater. The impacts of variables, including benzyl butyl phthalate concentration, adsorbent, pH, and time (15 mgL-1, 0.3 g, 5.0, and 60 min). Based on the received data, the adsorption of benzyl butyl phthalate on the PEEK/PVA/ZnONPs adsorbent agrees well with the Langmuir adsorption model isotherm (qm = 34.24 mgg-1). The results of the thermodynamic parameter showed a negative enthalpy (-77.0 KJ/mol), a negative Gibbs free energy (-11.7 KJ/mol), and negative entropy (-274.0 J/K.mol). This led to the conclusion that the adsorption process is energetically possible, and exothermic was also spontaneous. This work indicates that the PEEK/PVA/ZnONPs, used as an ecologically adapted, adsorbent holds promise for eliminating benzyl butyl phthalate from wastewater.
    Keywords: Benzyl butyl phthalate, Adsorption, Composite membrane, Zinc oxide Nanoparticles, Wastewater
  • Noushin Osouleddini *, AmirHesam Mahlooji, Mohammad Abdollahzadeh

    Preserving the health of food resources, including drinking water, is considered one of the most important issues in human usability. Therefore, all efforts and research are based on finding and utilizing the best methods to safeguard the hygiene of water and municipal wastewater, aiming to protect human health and improve the quality of treated sanitary sewage. Hence, the objective of this study is to investigate water contaminated with Escherichia coli bacteria (E.coli) and the removal of this microorganism as an indicator of drinking water contamination and the degree of treatment of sanitary wastewater using a Pulsed Electric Field (PEF). In this research, the PEF device was utilized within the range of 1 to 13 kV/cm with a frequency of 500 Hz for some time of 3 to 60 min. The investigation was conducted using the Most Probable Number (MPN/100 mL) test in a 9-tube format. The results of this assessment at a temperature of 20 ºC showed that the minimum removal efficiency of total coliform bacteria was achieved at 1 kV voltage with a contact time of 1 min, yielding a 0% efficiency, while the highest removal efficiency was obtained at 13 kV voltage with a contact time of 30 min, resulting in a 99.8% efficiency.

    Keywords: Pulsed Electric Field (PEF), Escherichia coli (E. coli), Wastewater, Microbial pollution, Microorganismremoval
  • اخترالسادات موسوی*، احمد اکبری، سید کاظم موسوی
    زمینه و هدف

    محدودیت های محیطزیستی و اقتصادی که به طور چشم گیری بر صنعت نساجی و رنگ رزی اعمال شده منجر به توسعه فرآیندهای دوست دار محیطزیست برای اصلاح خواص الیاف و بهبود فرآیندهای سنتی موجود شده است. تلاش های بسیاری برای کاهش هزینه ها و همچنین مواد آلوده کننده دفع شده همراه پساب انجام شده که از آن جمله می توان به استفاده از پلیمرهای طبیعی اشاره کرد. هدف از این تحقیق استفاده از پلیمر طبیعی بتاسیکلودکسترین به عنوان جایگزینی مناسب با اثرات محیطزیستی مطلوب برای دیگر افزودنی های شیمیایی در رنگرزی می باشد.

    روش بررسی

    در این مطالعه الیاف پشم با پلیمر زیست سازگار بتاسیکلودکسترین، اصلاح شد و ویژگی های رنگ رزی آن نظیر اثر مقدار ترکیب بتاسیکلودکسترین (5/0-20%)،pH رنگ رزی (7-3) و غلظت ماده رنگ زا (75-5%) بر روی قابلیت رنگ رزی پشم با رنگ زای طبیعی روناس مورد ارزیابی و مقایسه رنگ قرار گرفت. و در نهایت تغییرات فیزیکی الیاف خام و اصلاح شده بعد از رنگ-رزی با استفاده از تست SEM انجام شد.

    یافته ها

    نتایج نشان داد که با افزایش مقدار ماده بتاسیکلودکسترین، قدرت رنگی نمونه ها به مقدار قابل قبولی بهبود می یابد و قابلیت رنگ رزی (K/S) الیاف رنگرزی شده با پشم اصلاح شده نسبت به پشم دندانه شده با آلومینیوم و پشم خام بیش تر می باشد. همچنین رمق کشی پشم اصلاح شده در pH خنثی نسبت به شرایط اسیدی به میزان قابل توجهی بهبود یافت، در حالی که تغییر محسوسی در قابلیت رنگ رزی پشم خام با تغییر در pH مشاهده نشد.

    بحث و نتیجه گیری

    به طورکلی با توجه به شرایط اصلاح پشم با پلیمر زیست سازگار بتاسیکلودکسترین و تغییرات در شرایط رنگ رزی، نه تنها امکان حذف مواد شیمیایی از پساب صنایع نساجی و رنگ رزی قابل انجام است، بلکه می توان مقدار رنگ زای مصرفی و رنگ زای جذب نشده و باقی مانده در پساب را کاهش داد که از نظر محیط زیستی بسیار حایز اهمیت می باشد.

    کلید واژگان: بتاسیکلودکسترین, محیط زیست, رنگ رزی, آلودگی, پساب
    akhtar mousavi*, ahmad akbari, seyed kazem mousavi
    Background and Objective

    environmental and economic limitations that are imposed dramatically on textile and dyeing industry leads to the development of environmentally friendly processes for modifying the properties of fibers and improving the existing traditional processes. Many efforts have been done for decreasing costs and disposed contaminants which one of them is using natural polymers. The purpose of this study is applying beta-cyclodextrin natural polymer as an appropriate alternative with favorable environmental effects for other chemical additives in dyeing.

    Material and Methodology

    In this study, wool fiber amended/treated by β-Cyclodextrin biocompatible polymer and its dyeing features such as the effect of β-Cyclodextrin composition (%20-0/5), dyeing pH (3-7) and density of the dye (%5-75) on the dyeing capabilities of wool with madder dye color was evaluated and compared. And finally, physical changes of crude fiber and amended fiber after dyeing was amended/treated using SEM analysis.

    Findings

    According to the results, as the β-Cyclodextrin amount increased, the color strength of the samples are considerably enhanced and dye ability (K/S) is better in the case of modified wool rather than aluminium-mordanted wool and pristine wool. Besides, exhaustion of modified wool in neutral pH rather than acidic pH has been increased dramatically while no appreciable changes was observed in pristine wool dye ability with pH changes. Color strength (K/S) data were in the following order of the β-Cyclodextrin modified wool>.

    Discussion and Conclusions

    In general, according to the conditions of modifying wool with β-Cyclodextrin biocompatible polymer and changes in dyeing conditions, not only removing chemical compounds from the wastewater of textile industrial can beapplied, but also the amount of consumed dye and unabsorbed dye remaining in wastewater can be reduced which is environmentally very important.

    Keywords: β-Cyclodextrin, Environment, Dyeing, pollution, Wastewater
  • Smily Vishwakarma *, Dharmendra Dharmendra
    Constructed wetlands (CWs) are man-made systems designed to treat a range of residential, commercial, and industrial wastewaters. The objective of the study was to evaluate the efficiency of wastewater treatment systems using constructed wetlands. The effectiveness of removing chemical and physical pollutants was also evaluated. The setup consisted of a hybrid flow system composed of upflow constructed wetland and a horizontal flow constructed wetland connected in series that is used for primary treatment of the influent of domestic wastewater. Two systems were analyzed: one cultivated with the ornamental species Canna Indica, and one cultivated with the cattail Cymbopogon flexuosus. It consisted of two treatment sections consisting of two plant species Cymbopogon citratus (lemon grass – first CW) and Canna xalapensis Horan (Canna Indica – second CW). The water quality parameters i.e., BOD, COD, TSS were analyzed according to APHA (American Public Health Association) by daily sampling. The CW was monitored for the quality of wastewater inflows and outflows and nutrient accumulation in plants. Results showed that the maximum COD removal for Lemon Grass and Canna Indica beds were 75% and 70% respectively at 200mg/L COD loading in the CW setup over a six-month period respectively. The maximum BOD removal found in Lemon Grass and Canna Indica beds were 73% and 64% respectively at a feed concentration of 200mg/L COD. Both the CWs together as one unit showed similar rates of TSS removal irrespective of the type of wetland plant species and were more efficient in treating wastewater.
    Keywords: Wastewater, Lemon grass, Canna indica, Recycle, Reuse
  • Amir Nabi Bidhendi *, Nasser Mehrdadi, Abdolreza Karbassi
    In this work, it was attempted to evaluate and demonstrate disinfection effectiveness of an electrochemical process to entirely remove coliform from wastewater effluent following secondary treatment. For the tests, an experimental bench-scale batch electrochemical cell was constructed, and aluminum electrodes were employed in the electro-disinfection reactor. In the electric disinfection phase, wastewater samples were put in the reactor/disinfector and a direct current (DC) was applied to it. According to findings, a significant decrease occurred in the total number of coliforms in the treated wastewater, and a high improvement occurred in the effluent properties. At a contact time of 15 min and a current density of 5.5 mA/cm2, led to a bacterial killing effectiveness of 97.7% or above. As the current density and contact time increased, a general increase occurred in the bacterial killing efficiency, and the effect of the two above-mentioned factors was much greater than the effect of salinity. Moreover, according to the experimental data, the removal efficiency of chemical oxygen demand (COD) and total suspended solids (TSS) by the aluminum electrodes were 78.50% and 99.93%, respectively. The findings indicate the applicability of the proposed electrochemical treatment to wastewater effluent. Nevertheless, to be able to apply this system at an industrial scale in the future, it is necessary to conduct more research into the optimum operation conditions and make an in-depth comparison of energy consumptions between the electrochemical treatment and the conventional approaches.
    Keywords: Electrochemical disinfection, E. coli, Wastewater, aluminum
  • Olufunmilayo Olayinka, Morenikeji Egbeyemi, Adedayo Oyebanji *
    Phenols have attracted global interest in the sphere of environmental management due to their potential toxicity on human health. This study determined concentrations of three priority phenolic compounds in effluent and water of a local textile industry in Abeokuta, Nigeria.  During tie-dye production, triplicates of effluent, well water, stream and control water were collected three times from five points to give a total of forty-five samples. Physicochemical parameters of samples including temperature, pH, electrical conductivity (EC), total suspended solids (TSS) and total dissolved solids (TDS) were determined according to standard methods while the concentrations of the priority phenolic compounds (4-nitrophenol, 4-chloro-3-methylphenol and 2, 4-dinitrophenol) were determined using High Performance Liquid Chromatography equipped with Ultra-Violet detector (HPLC/UV). Data obtained were subjected to descriptive (mean and standard deviation) and inferential (ANOVA) statistics. pH, EC and TSS of effluent and water samples were higher than the permissible limits of World Health Organization (WHO) and Federal Environmental Protection Agency (FEPA) while temperature of the effluent samples and TDS of the well water samples were within standard values. Higher concentrations of the priority phenolic compounds occurred in effluent than water samples but 4-nitrophenol was below detection limit (DL) in water samples. Concentrations of 4-nitrophenol, 4-chloro-3-methylphenol and 2,4-dinitrophenol in effluent exceeded stipulated standard of WHO (0.01 mg/L) and water samples. High concentrations of phenols in water bodies at the local textile industry suggest uncontrolled discharge of effluent from the industry which could eventually reach surface and ground water with potential significant health implications to the populace.
    Keywords: Phenols, Wastewater, Physicochemical properties, Dye
  • Smily Vishwakarma *, Dharmendra Dharmendra, Rohit Singh, Bharti Bharti, Ankita Ankita
    Substrates play a major role to filter, adsorb, sediment, flocculate, precipitate, and exchange ions. In CW (Constructed wetland), selecting substrate or bed materials is not difficult, as locally accessible, cost-effective, and environment-friendly materials can be used based on size, hydraulic conductivity, texture, porosity, etc. CW substrates undergo a multitude of purification processes, including physical filtration and sedimentation, sorption, ion exchange and microbial degradation, precipitation, and bio-immobilization in the substrate, in addition to uptake and metabolism by macrophytes. With constructed wetlands, treatment facilities with well-defined substrates, vegetation species, and flow patterns can be built with greater control than with natural systems. This report details investigations of some of the locally available substrates that all fit the requirements. Based on analysis of parameters which are pH, water absorption capacity, hydraulic conductivity, porosity, surface area, bulk density, particle size distribution, D10 particle diameter, D60 uniformity coefficient, permeability and specific gravity, a comparison of four materials is presented in this paper. The study found that the construction waste materials evaluated showed satisfactory physical properties for use as filler media in constructed wetlands for wastewater treatment.
    Keywords: Wastewater, Pollution, Recycle, Reuse, sustainability
  • امیر بهرامی*، فاطمه احدی، مهدی بهرامی، فاطمه سادات آقامیرمحمدعلی
    سابقه و هدف

    امروزه پساب ها به طور گسترده در خاک های کشاورزی نزدیک به مناطق شهری کشورهای در حال توسعه برای رفع کمبود آب استفاده می شود. از طرف دیگر به دلیل افزایش آلودگی های ایجاد شده، منابع محدود موجود مورد تهدید قرار می گیرد. استفاده از آب های نامتعارف در صورت دارا بودن استاندارد لازم در بسیاری از کشورهای دنیا برای تولید محصولات کشاورزی کاربرد دارد و تصفیه خانه های فاضلاب شهری به دلیل قابلیت تحویل آب پایدار در تمام فصول سال منبع بسیار قابل اعتمادی می باشند. در سال های اخیر پژوهش های متعددی در زمینه بررسی کیفیت پساب خروجی تصفیه خانه های فاضلاب شهری و امکان استفاده از آنها در مصارف مختلف از جمله کشاورزی، در شهرهای مختلف ایران انجام شده است. با توجه به بحران آبی به وجود آمده به ویژه در نواحی خشک و نیمه خشک کشور، ضروری است امکان استفاده بیشتر از این منبع آبی نامتعارف مورد بررسی و تحلیل قرار گیرد. هرچند بازچرخانی فاضلاب می تواند پیامدهای بهداشتی و زیست محیطی مختلفی را به دنبال داشته باشد.

    مواد و روش ها

    در این پژوهش با استفاده از داده های روزانه تصفیه خانه فاضلاب شهری شیراز طی سال های 1397 تا 1398 به بررسی کیفیت پساب خروجی برای مصارف مختلف مانند آبیاری محصولات کشاورزی، آبیاری فضای سبز، شرب دام و طیور، پرورش ماهی، تخلیه به آب های سطحی و تغذیه آب های زیرزمینی بر اساس استانداردهای ملی و بین المللی پرداخته شد. در این راستا، ابتدا مقادیر پارامترهای مختلف فیزیکی و شیمیایی از جمله اسیدیته، قابلیت هدایت الکتریکی، کل جامدات محلول، کل مواد جامد معلق، کل جامدات فرار، کل جامدات، اکسیژن خواهی شیمیایی، اکسیژن خواهی بیوشیمیایی، کدورت، اکسیژن محلول، شوینده ها، فسفات، فسفر کل، نیترات، نیتریت، آمونیاک، نیتروژن کل کجلدال، کلر آزاد و چربی- روغن- گریس در فاضلاب خام و پساب خروجی تعیین گردید. سپس ضمن مقایسه مقادیر این متغیرها با استاندارد سازمان حفاظت محیط زیست ایران، راندمان های حذف این پارامترها محاسبه گردید و در نهایت کیفیت پساب خروجی برای به کارگیری در بخش های مختلف بررسی شد.

    نتایج و بحث: 

    نتایج نشان داد که راندمان حذف BOD5، COD، TSS، NH3، شوینده ها و چربی- روغن- گریس در این تصفیه خانه به ترتیب 85، 85، 67، 64، 94 و 5/68 درصد است. کیفیت پساب خروجی فقط بر اساس استاندارد سازمان محیط زیست ایران برای اهداف کشاورزی مناسب است و از نظر سایر استانداردها قابلیت چنین استفاده ای را ندارد. این پساب را می توان برای آبیاری درختان میوه زینتی، محصولات علوفه ای، درختان و فضای سبز کنار جاده های خارج از شهر، محصولات زراعی، صنعتی و جنگلی و نیز شرب دام و طیور به کار برد. اما برای آبیاری فضای سبز شهری، پرورش ماهی، تخلیه به آب های سطحی (مانند دریاچه مهارلو در مجاورت تصفیه خانه) و نیز تغذیه آب زیرزمینی محدودیت هایی دارد، هر چند برخی از این محدودیت ها را می توان با ارتقاء کارکرد تصفیه خانه رفع نموده و پساب را برای این اهداف نیز استفاده کرد. با آبیاری گیاهان غیرمثمر و پارک های جنگلی اطراف شیراز و حتی قسمتی از فضای سبز شهری می توان فشار بر منابع آب را تا حد زیادی کاهش داد. از طرف دیگر، استمرار آبیاری با این پساب که حاوی مواد آلی و مغذی به نسبت زیادی است، افزایش نیترات خاک را سبب شده و امکان شستشو و انتقال آن به منابع آب سطحی و زیرزمینی وجود خواهد داشت.

    نتیجه گیری

    مقدار پارامترهای کیفی پساب خروجی تصفیه خانه در محدوده استاندارد حفاظت محیط زیست ایران قرار دارد و می توان از آن به عنوان منبع آبی پایدار در بخش هایی استفاده نمود که ارتباط مستقیم با انسان ندارد. در استفاده از این منبع در مصارف مجاز باید کلیه موارد بهداشتی برای کارگران این بخش رعایت شود و پساب به طور مستمر گندزدایی گردد.

    کلید واژگان: تصفیه خانه, کیفیت آب کشاورزی, فاضلاب, شیراز
    Amir Bahrami *, Fatemeh Ahadi, Mehdi Bahrami, Fateme Aghamir
    Introduction

    Today, treated wastewater is widely used on agricultural soils adjacent to urban areas of developing countries to meet water shortages. On the other hand, due to the pollution increase, the limited available resources are threatened. For the production of crops, unconventional water is used in many countries of the world if it has the necessary standard, and municipal wastewater treatment plants are a very reliable source due to their ability to deliver sustainable water in all seasons. In recent years, several studies have been conducted in the field of the effluent quality of municipal wastewater treatment plants and the possibility of using them in various applications, including agriculture, in different regions of Iran. Due to the water crisis that has arisen, especially in arid and semi-arid regions of the country, it is necessary to study and analyze the possibility of further use of this unconventional water resource. However, wastewater recycling can have various health and environmental effects.

    Material and methods

    In this study, the effluent quality of the Shiraz municipal wastewater treatment plant was investigated using the daily data during 2018 and 2019 for use in various purposes such as irrigation of crops, irrigation of green spaces, drinking of livestock and poultry, fish farming, discharge into streams, artificial recharge of groundwater based on national and international standards. In this regard, at first, the values of various physical and chemical parameters such as acidity, electrical conductivity, total dissolved solids, total suspended solids, total volatile solids, total solids, chemical oxygen demand, biochemical oxygen demand, turbidity, dissolved oxygen, detergents, phosphate, total phosphorus, nitrate, nitrite, ammonia, Kjeldahl total nitrogen, free chlorine, and fat-oil-grease were determined in raw and treated wastewater. Then, while comparing the values of these parameters with the standard of the Environmental Protection Organization of Iran, the removal efficiencies of these parameters were calculated and finally, the quality of the effluent was investigated for use in various sectors.

    Results and discussion

    The results showed that the removal efficiency of BOD5, COD, TSS, NH3, detergents, and fat-oil-grease in this treatment plant is 85, 85, 67, 64, 94, and 68.5%, respectively. The quality of the effluent is only suitable for agricultural purposes based on the standard of the Environmental Organization of Iran, and according to other standards, it is not capable of such use. This effluent can be used to irrigate ornamental fruit trees, fodder crops, plenteous trees and green spaces side of the roads outside the city, field crops, industrial crops, and forestry, as well as drinking livestock and poultry. However, there are limitations for urban green space irrigation, fish farming, discharge to surface waters (such as Maharloo lake in the vicinity of the wastewater plant), and groundwater recharge, although some of these limitations can be improved by upgrading the function of the treatment plant. By irrigating unfruitful plants and forest parks around Shiraz and even part of urban green space, the pressure on water resources can be reduced to a great extent. On the other hand, the continuation of irrigation with this effluent, which contains organic and nutritious substances in a large proportion, has caused an increase in soil nitrate, and it will be possible to leach and transfer it to surface and underground water sources.

    Conclusion

    The amount of quality parameters of the treatment plant effluent is within the standard of Iranian Environmental Protection and can be used as a sustainable water source in areas that are not directly related to humans. In using this sustainable water source for permitted uses, all health issues for the workers of each sector must be observed, and the effluent must be continuously disinfected.

    Keywords: Treatment Plant, Agricultural Water Quality, Wastewater, Shiraz
  • ایمان همایون نژاد*، سعید شجاعی، پرییا امیریان
    زمینه و هدف

      امروزه کمبود ذخایر آبی در زمین بویژه اقلیمهای خشک از جمله کشور ما باعث شده تا استفاده مجدد و هدفمند از پساب جهت تامین منابع آبی جدید بعنوان یک راه حل مناسب مطرح گردد. در حال حاضر کشورهایی که با مشکل کمبود منابع آبی روبرو هستند  امکان سنجی استفاده از فاضلاب تحت عنوان آبهای نامتعارف را بررسی میکنند. اما متاسفانه در این خصوص تحقیق بسیار کمی صورت گرفته است.

    روش بررسی

    بمنظور بررسی میزان تغییرات برخی عناصر و مشخصات خاکی که بوسیله پساب در مدت زمان 3 سال آبیاری شده است، آزمایشی بصورت طرح بلوک کامل تصادفی با سه بارتکرار انجام گرفت. نمونه برداری از دو عمق 0-30 و 30-60 سانتی متری خاک صورت گرفت و پارامترهای سدیم، مجموع کلسیم و منیزیم، هدایت الکتریکی و pH خاک در سه منطقه متفاوت مطالعاتی (بدون آبیاری، آبیاری با پساب تصفیه شده، آبیاری با آب رودخانه) اندازه گیری و مورد بررسی قرار گرفت.

    یافته ها

    پساب خروجی از تصفیه خانه زاهدان سبب افزایش قابل قبول میزان سدیم، مجموع کلسیم و منیزیم و اسیدیته خاک نسبت به منطقه شاهد گردیده است. اما درمورد هدایت الکتریکی، آبیاری با پساب سبب کاهش این مقدار گردید.

    بحث و نتیجه گیری

    پساب(تصفیه شده) سبب افزایش موثر و قابل قبول برخی عناصر خاک می گردد. بنابراین می تواند در امر احیاء خاک کمک موثری باشد و بعنوان یکی از منابع آب بخصوص در مناطق خشک که با کمبود آب مواجه هستند، مورد استفاده قرار گیرد.

    کلید واژگان: آب نامتعارف, پساب, خاک, زاهدان
    Iman Homayoonnezhad *, Saeed Shojaee, Paria Amirian
    Background and Objective

    Today, the lack of water reserves on the ground, especially in dry climates including our country, has caused the purposeful reuse of wastewater to provide new water sources as a new solution. Currently, countries that are facing the problem of lack of water resources are investigating the feasibility of using wastewater under the title of unconventional waters. But unfortunately, very little research has been done in this regard.

    Materials and Methodology

    In order to investigate the amount of changes in some elements and characteristics of the soil under irrigation with wastewater, for 3 years, an experiment was conducted as a randomized complete block design with three repetitions. Sampling was done from two depths of soil 0-30 and 30-60 cm, and the parameters of sodium, total calcium and magnesium, acidity and electrical conductivity of the soil in three study locations (without irrigation, irrigation with treated wastewater, and irrigation with water of river) was measured and analyzed.

    Findings

    The effluent from Zahedan treatment plant has caused an acceptable increase in the amount of sodium, total calcium and magnesium, and soil acidity compared to the control area. But regarding the electrical conductivity, irrigation with sewage decreased this amount.

    Discussion and Conclusion

    Effluent causes an effective and acceptable increase of some soil elements, which can be an effective help in soil regeneration and to be used as one of the water sources especially in dry areas that are facing a shortage of water resources.

    Keywords: Unusual water, Wastewater, soil, Zahedan
  • Tatiana Del Castillo De Loayza, Ingrid Maldonado, Franz Zirena Vilca *
    The Huatanay River in Cusco-Peru, is affected by wastewater discharges along its course. In order to evaluate this impact, we evaluate antibiotic residues and their impact on the increase of bacterial resistance in the city of Cusco treatment plant. For this purpose, water samples from the influent and effluent of the treatment plant were analyzed by chromatographic methods; additionally, sensitivity tests were performed with three bacterial strains (Escherichia coli, Salmonella sp., and Klebsiella sp.), which were isolated from the same place. Six antibiotic residues were identified (ceftriaxone, amoxicillin, trimethoprim, sulfamethoxazole, dicloxacillin, and lincomycin). Those found in the highest concentration were: amoxicillin (91495 and 0 µg/L) and lincomycin (33970 and 10800 µg/L) in the influent and effluent, respectively. There is more resistance in the effluent than the influent in the case of E. coli shows resistance in the effluent to cephalexin (30 µg) and azithromycin (15 µg). Salmonella sp. is resistant to amoxicillin (15 µg), dicloxacillin (1 µg), lincomycin (2 µg), ceftriaxone (30 µg), cephalexin (30 µg), and ciprofloxacin (5 µg). Finally, Klebsiella sp. is sensitive to ceftriaxone (30 µg), amoxicillin (15 µg), and cephalexin (30 µg). This confirms that the antibiotic residues contained in the wastewater of Cusco generate resistance in the isolated bacteria.
    Keywords: Bacteria resistance, chromatography, Emerging pollutants, Environmental Health, Pollution, Solid phase xtraction, Wastewater
  • Rim Bougassa *, Latifa Tahri, Ilham Nassri, Mohammed Fekhaoui
    Olive mill wastewater is the main by-product derived from olive mills using the three-phase extraction process,displaying a serious environmental risk due to its notable content in organics and phenolics Olive oil production, an agro-industrial of vital economic particularly in Mediterranean countries, is unfortunately associated with the generation of large quantities of OMW (Olive Mill Wastewater) and solid wastes. The OMW is considered a major environmental problem, it is a powerful pollutant rejected in nature without any prior treatment. This research work aims to study the treatment of OMW by a new ecological and economic system, which consists of the use of the following components: gravel, sawdust, soil, activated carbon, bamboo, and the valorization of the solid residues. HPLC analysis showed that hydroxytyrosol is the most abundant biophenol. Many other biophenols were identified (Tyrosol, gallic acid, and eleonic acid). The comparison between before and after filtration by the new system showed an essential degradation of phenolic compounds after treatment and found a new compound resulting from their degradation.
    Keywords: New system, Phenolic-compounds, Wastewater, filtration, Olive mills
  • N. Masne *, S. Suryawanshi
    In this study, natural coarse aggregates were replaced with coarse recycled concrete aggregate (RCA) in 0 %, 50 %, and 100 % extracted from construction and demolition wastes. Their recycling could lead to a greener resolution for preserving the environment and paving the way for sustainability through solid waste management. The compressive strength of 0 %, 50 % and 100 % RCA at 365 days was reduced by 3.97 %, 4.88 %, 6.81 %, respectively, compared to the compressive strength at 28 days. Tensile strength at 365 days was reduced by 4.31 %, 6.50 % and 9.83 % compared to tensile strength at 28 days. There was no discernible effect of water type on the strength properties of concrete. Compared to other combinations, 100 % RCA concrete experiences a greater percentage of weight loss owing to evaporation of free water. When temperature was elevated, the concrete matrix expands and deep cracks were observed on the concrete surface. The overall performance of recycled aggregate concrete was not much influenced by the use of such aggregates, so these findings will add a new achievement to a sustainable construction through solid waste management.
    Keywords: Concrete, Curing, Demolished waste, Recycled aggregate, Solid waste, Wastewater
  • Sofiane Labidi *, Boukoffa Mechati
    Natural quartz mineral was examined as a new sorbent for Hg(II) removal from synthetic wastewater systems. Batch adsorption experiments of Hg(II)  onto quartz mineral were conducted under various conditions such as solution pH, sorbent dosage, contact time, initial Hg(II)  concentration. Adsorption experiments results of Hg(II) by quartz mineral showed good achievement after 180 min with 1.0 g/L sorbent mass at pH of 2.0, agitation speed of 200 rpm and a temperature of 25°C. Moreover, the Hg(II) concentration was directly related to increases the adsorption capacity, the maximum Hg(II) uptake by quartz  sample was 16.52 mg/g for 80 mg/L (C0 (Hg(II)].  Langmuir isotherm and pseudo-second-order kinetics (R2 > 0.99) were found to be the most appropriate models to describe the adsorption of Hg(II) by quartz mineral. The intra-particle diffusion model and the calculated Dubinin–Radushkevich adsorption energy (Eads = 0.78 kJmol-1), confirms a physisorption adsorption reaction occurring in three stages.
    Keywords: SiO2, Hg(II), Wastewater, kinetic, physisorption
  • Salam K. Al- Dawery, Sreedhar Reddy *, Khaloud Al-Mashrafiya, Buthina Al-Fraji, Muataz Salam Al-Daweri
    The goal of this research was to investigate the efficacy photocatalysis with natural solar radiation and artificial UV radiation for disinfecting total coliforms in biologically treated wastewater.   The effect of TiO2 dosage and irradiation time on total coliform inactivation as measured by log reduction values (LRV), removal of BOD, COD, turbidity, and effluent properties as measured by pH and conductivity was investigated. Two sets of experimental equipment were constructed, one for using solar UV light and the other for using artificial UV light. After four hours of irradiation with 60 mg/L TiO2, photocatalysis achieved LRVs of 1.4 and 1, respectively, under UV and solar radiation. COD and BOD were reduced by 67% and 50% respectively under UV and solar radiation after two hours of irradiation with 60 mg/L TiO2. Turbidity was reduced by 71%. Both conductivity and acidity of the effluent were reduced as TiO2 concentration was increased. Photocatalysis with natural solar radiation produced disinfection results that were comparable to that of efficient UV light exposure. Artificial UV light and natural solar radiation can be combined in photocatalysis process to form a hybrid process.
    Keywords: Log reduction values Titanium dioxide, Photo-oxidation, Wastewater, COD, BOD
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