جستجوی مقالات مرتبط با کلیدواژه "pvd" در نشریات گروه "فنی و مهندسی"
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In recent years, implants are used as prostheses to replace and protect bone. Titanium, as an implantable material, needs to improve corrosion and wear properties for better performance. Therefore, in the current study nitride coatings were applied with the aim of improving corrosion and wear properties. Cathodic arc evaporation physical vapor deposition (CAE-PVD) technique was used to deposit nanolayered CrN/CrAlN coatings on commercially pure titanium and Ti6Al4V substrates for biomaterial applications. X-ray diffraction (XRD) was used to characterize the crystal structure of the coating, and scanning electron microscopy (SEM) and field emission scanning electron microscopy (FESEM) were utilized to observe the surface morphology and cross-section of the coating. The coating adhesion was measured according to VDI 3198 standard using a Rockwell-C indenter. The corrosion behavior was evaluated by potentiodynamic polarization and spectroscope electrochemical impedance in Ringer's solution. The results showed that the nanolayered coating changed the corrosion potential from -0.368 V to -0.054 V for the titanium sample and from -0.405 V to -0.028 V for the Ti6Al4V specimen. Additionally, the corrosion current density was reduced to about one-eighth and a third for the titanium and Ti6Al4V coated samples, respectively. The capacitator circle diameters increased due to the deposition of CrN/CrAlN coating, demonstrating enhanced corrosion behavior of the coated samples compared to uncoated specimens, as the coating acted as a barrier against corrosive liquids accessing the substrate.Keywords: CrN, CrAlN coating, Titanium, Ti6Al4V, PVD, Ringer Solution, Corrosion behavior
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Journal of the Structural Engineering and Geotechnics, Volume:12 Issue: 2, Summer and Autumn 2022, PP 45 -52
In projects that involve surcharge and prefabricated vertical drains (PVDs) systems for the treatment of weak underlying layers, embankment failures, tension cracks, and differential settlements, surficial heaves, and foundation failures were addressed in various literature. Overestimation and unrealistic design assumptions made by geotechnical and structural engineers are the main reasons for most of the cases. In all these cases a simple collaboration between different parties in the project ranging from designers to field engineers could have decreased or prevented these undesirable outcomes. The problem of neglecting the infiltration of the embankment in the ground as a new distinct layer with all the necessary requirements, and also disturbance caused as a result of PVDs installation in four cases: preloading case, fill removal, main structure construction, and post- construction phase are discussed. A few design recommendations are given regarding the stated issues. Since after the completion of soil treatment operations, the soil engineering parameters and in some cases even soil stratification had changed, care should be taken to use the new treated parameters in the final design process, not the preliminary site report parameters. Neglecting this issue may lead to severe malfunctions and even unpredictable failures. BIM technology has the possibility of integrating all aspects, and complexities of geotechnical engineering in the structural-architectural platform as a whole, which would revolutionize the construction industry. Till now only the structural-architectural part is done and further research and investment are necessary for the geotechnical aspect.
Keywords: BIM, PVD, Embankment Failure, Soil Treatment, Optimization -
The rapid developments of infrastructures, especially in far less developed areas or in the coastal regions, necessitates new technologies to elevate the efficiency of the existing systems. One of the obstacles in such areas is the existence of weak soils that are not suitable at all for construction. Soil treatment process, especially in such areas, is very time consuming and expensive. The common method for land reclamation consists of application of prefabricated vertical drains (PVDs), surcharge with or without vacuum preloading. Even by applying vacuum preloading, the time needed for compilation of the project is still considered long. In this literature a new method is introduced as a new preloading agent to accelerate the soil treatment process and decrease the cost and time required for the compilation of the reclamation process. Blast preloading might be a substitution or a companion for existing methods. First, a case history was introduced and verified using finite element modeling (FEM) that includes surcharge and vacuum preloading. Then the blast was applied to verified models, and the efficiency of it was investigated for every possible situation. It was shown that blast preloading has the potential to be used in soil treatment systems, as the required time was halved in many cases and the settlement increased from 20 to 50 percent, in comparison to cases without blast preloading. Even in cases in the absence of surcharge or vacuum, the blast preloading acts the same as surcharge or vacuum. Although it should be noted that it is still a preliminary investigation, more extensive lab and field tests are required for adoption of blast preloading as a new technique in soil treatment systems.
Keywords: Blast, Vacuum, Surcharge, PVD, Clay -
One of the important parameters that should be considered in designation of weak clay and peats treatment systems is the influence zone wherever there are infrastructures or sensitive buildings in the vicinity of the treatment area. Since large vertical and horizontal displacements occur in these treatment systems, the soil around the project undergoes large strains that should be accounted for in project planning prior to finalization of the treatment system. The treatment systems for weak clays and peats are often a combination of prefabricated vertical drains plus vacuum and/or surcharge preloading. For investigation of the impact of preloading agents, and FEM simulation of two case histories were performed. One the project incorporates the combination of surcharge and vacuum preloading while the other one consisted of only vacuum preloading without surcharge embankment. Based on the verified models, different scenarios were introduced for comparison of impact of the vacuum and preloading agents on the magnitude of the influence zone. Regarding the impact of surcharge embankment, it was shown that reducing the height of surcharge can drastically reduce the influence zone in both numerical simulations. The application of vacuum preloading as the only preloading agent has decreased the influence zone drastically and for urban areas or places that sensitive infrastructures exist might be an ideal option for similar cases. Regarding the impact of magnitude of vacuum pressure on the influence zone it was shown that application of a stable high vacuum pressure can significantly reduce the diameter of the influence zone.
Keywords: Vacuum preloading, Influence zon, e Surcharge preloading, PVD, clay -
Three trial embankments as TS1, TS2, and TS3 that were built for the investigation of a soil treatment project in Bangkok were modeled and verified based on the reported data. To clarify the importance of integration of the hydraulic modifier function vs stress, in the verified models, the modifier functions were omitted and the FEM models were run in the absence of the function. It was shown that after the omission of the hydraulic modifier, the results were overestimated especially for the TS1 and TS2, which had smaller PVDs (prefabricated vertical drains) distance. For the TS1 embankment, the settlement increased from 0.78 m to 0.87 m in 210 days. In 365 days, the settlement increased from 1.27 m to 1.44 m. For the TS2 embankment, the settlement increased from 0.93 m to 1.67 m in 230 days. In 410 days, the settlement increased from 1.36 m to 2.27 m. For the TS3 embankment, the settlement increased from 1.15 m to 1.79 m in 230 days. In 410 days, the settlement increased from 1.52 m to 2.24 m. The inclusion of the hydraulic function that calibrates the model for every step of loading is essential in the modelling such problems. For the design phase, this function should be calculated from lab tests, preferably undisturbed samples that were bored from the site, and the resultant function be used as an inseparable part of modeling and calculations.
Keywords: PVD, Consolidation, Soil Treatment, Hydraulic Modifier, Surcharge -
In Finite element modelling (FEM) of the soil treatment systems that includes prefabricated vertical drains (PVDs), either for preliminary designation, or in the evaluation period, one the main challenges of geotechnical engineers are the correct estimation of the parameters used in the model. The main objective of these kind of soil treatment is the acceleration of the consolidation process to reinforce the weak soft clay stratum underneath. In the consolidation process the initial soil parameters changes, such as void ratio, hydraulic conductivity, swelling and compression index and so on and that is why the modelling of such reclamation process is so challenging. In previous published literature, there was no paper, especially concentrate on the sensitivity analysis. In this literature first, a case history is presented and verified, and then base on the verified model, the following parameters as: void ratio, vacuum pressure, phi and over consolidation ratio, rate of loading of the surcharge embankment, mesh size, Lambada (𝝀) and Kappa (𝜿), Hydraulic conductivity ratio and Mesh type were parametrically investigated. It was shown that, even a minute change in the quantity of some parameters can adversely affect the precision of the prediction of the model. The results of this study can be used by both field and design engineers, involved in the construction of embankments on soft ground for soil treatment systems in weak and rate-sensitive clays.
Keywords: Sensitivity Analysis, Clay, PVD, Surcharge, Vacuum Preloading, FEM -
One of the new technology that is widely used in all the world is the vacuum preloading that accelerate the process of dewatering and consolidation process along with prefabricated vertical drains (PVD)s with or without surcharge preloading. In the finite element modelling (FEM) modelling process, the reduction in conductivity due to the consolidation and increase in stress of underneath layers, plays a dramatic role in prediction of the settlement. Appling a modifier function is a good means to account for reduction in the hydraulic conductivity in FEM modelling. To illustrate the importance, the importance of applying this function in the modelling, TV2 trial embankment in Bangkok airport was appointed as a case history. After the verification of the model, the model was run in the absence of hydraulic modifier. It was observed that the predicted final settlement after 160 days is increased from 0.94 m to 1.19. Also the curve pass is unreal base on the verified model, and the quantity of the calculated settlements are 10 to 25 percent overestimated. Since the clogging of PVDs pore, is one the obstacles in modeling procedure of the vacuum preloading, the clogging effect can be applied as a modification in the resultant hydraulic modifier function derived from lab tests. By applying the proper modifier function, more realistic results can be obtained in FEM modelling in such models including PVDs and vacuum and/or surcharge preloading.
Keywords: Vacuum preloading, Consolidation, Hydraulic modifier, PVD, Clay -
This paper describes the behavior of soft soil foundation under Surcharge and with and Without prefabricated vertical drains (PVDs) or Vacuum Preloading base on a trial embankment which was built in Bangkok International Airport, Thailand. An analytical solution considering the variation of soil permeability and compressibility was adopted. Three scenarios were modeled and analyzed for Bangkok airport as: Model A: Application of surcharge load alone (i.e., no vacuum and PVD installation), Model B: Application of surcharge load combined with PVD (i.e., no vacuum application), Model C: Application of surcharge load combined with PVD and 60 kpa constant vacuum preloading and Model D: Application of surcharge load combined with PVD and field vacuum that was applied on site. The associated settlements at the embankment centerline are predicted and compared with the available field measurement. The field data show that the efficiency of this soil treatment technique depends on the magnitude and distribution of vacuum pressure. The height of surcharge and consolidation time can be significantly reduced in comparison with the conventional method of surcharge alone or surcharge and pvd alone. The findings of this study are expected to be useful to design engineers involved in the construction of embankments on weak grounds.
Keywords: surcharge, Soil treatment, vacuum consolidation, PVD -
Molybdenum disulfide (MoS2) is one of the most widely used solid lubricants. In this work, composite MoSx/Ti coatings were deposited by direct-current magnetron sputter ion plating onto plain carbon steel substrates. The MoSx/Ti ratio in the coatings was controlled by sputtering the composite targets. The composition, microstructure, and mechanical properties of the coatings were explored using an energy dispersive analysis of X-ray (EDX), Xray diffraction (XRD), and nano indentation and scratch techniques. The tribological behavior of the coatings was investigated using the pin-on-disc test at room temperature. With the increase of doped titanium content, the crystallization degree of the MoSx/Ti composite coatings decreased. The MoSx/Ti coatings showed a maximum hardness of 13 GPa at a dopant content of 5 at% Ti and the MoSx/Ti composite films outperformed the MoSx films. Moreover, the films exhibited a steady state friction coefficient from 0.13 to 0.19 and the main wear mechanisms of the MoSx/Ti coating in air were abrasive, adhesive, and oxidation wear.Keywords: MoSX, Ti coating, tribological properties, low friction, PVD
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In this investigation, MoSx/Cr coatings were deposited by direct-current magnetron sputter onto Ck45 (AISI 1045) plain carbon steel substrates. The MoSx/Cr ratio in the coatings was controlled by sputtering the composite targets. The chemical characterization was performed using EDX (energy dispersive X-ray analysis); the structural characterization was accomplished by X-ray diffraction (XRD) studies. The mechanical properties of coatings were analyzed by nanoindentation experiments. The tribological behavior of the coatings was investigated using the pin on disc test at room temperature. MoSx/Cr coatings with Cr atomic percentage of 13% was found to possess the optimum wear resistance and durability. The MoSx/Cr coatings showed a maximum hardness of 12.5 GPa at a dopant content of 13 at.% Cr. Moreover, the films exhibited a steady state friction coefficient from 0.15 to 0.19 and the main wear mechanisms of the MoSx/Cr coating in air were abrasive, adhesive, and oxidation.Keywords: MoSX-Cr coating, PVD, Tribological properties, Low Friction, Solid Lubricant
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Sputtered MoS2 coatings have been mostly used as a solid lubricant. In this investigation, MoSx/Ni composite coatings with Ni contents varying from 0 to 22 % were deposited onto steel substrate using a DC magnetron sputter process. The MoS2/Ni ratio in the coatings was controlled by sputtering the composite targets. The composition, microstructure, and mechanical properties of the coatings were explored using an energy dispersive analysis of X-ray (EDX), Xray diffraction (XRD), nano indentation, and scratch techniques. The tribological behavior of the coatings was investigated using the pin-on-disc test at room temperature. The nickel doping in MoS2–Nix% coatings improves their mechanical properties, cohesive strength and tribological properties. The films exhibited a steady state friction coefficient from 0.13 to 0.19 and the main wear mechanisms of the MoSx/Ni coating in air were abrasive, adhesive, and oxidation wear.Keywords: MoSX, Ni coating, Tribological properties, PVD, Low friction, Solid lubricant
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در این پژوهش پوشش نانوساختار DLC (کربن شبه الماسی) با استفاده از روش PACVD (رسوب گذاری شیمیایی از فاز بخار به کمک پلاسما) و روش Arc-PVD (رسوب گذاری فیزیکی از فاز بخار به کمک قوس کاتدی)، روی فولاد St37 پوشش داده شد. سپس در روش Arc-PVD یک لایه میانی قبل از پوشش DLC رسوب گذاری گردید. مشخصه یابی و ارزیابی پوشش ها به وسیله روش های میکروسکوپ الکترونی روبشی، پراش سنجی پرتو ایکس، طیف سنجی رامان، طیف سنجی با تفکیک انرژی، آزمون های چسبندگی و تریبولوژیکی انجام شد. نتایج نشان داد که پوشش DLC PVD به دلیل حضور لایه میانی TiCrAlN، اندازه ذرات 30 تا 40 نانومتر، سختی گرادیانی و همچنین حضور کاربیدهای تیتانیم و کروم درون پوشش، دارای خواص مکانیکی، چسبندگی و سایش عالی است. اندازه دانه های پوشش DLC PACVD تقریبا در محدوده ی 70 تا 110 نانومتر اندازه گیری شد. از طرفی ضخامت پوشش در روش Arc-PVD کم تر از پوشش حاصل از روش PACVD شد که تنش داخلی کم تر پوشش منتهی به چسبندگی مناسب این پوشش شد. بنابراین پوشش حاصل از روش PACVD علی رغم خواص مناسب، نسبت به پوشش DLC PVDسختی و چسبندگی کمتری از خود نشان داد.کلید واژگان: رسوب فیزیکی بخار, رسوب شیمیایی بخار به کمک پلاسما, کربن شبه الماس, پوشش نانوسختار و فولاد St37In this Study, PACVD (plasma assistant chemical vapor deposition) and Arc-PVD (cathodic arc physical vapor deposition) methods were used to deposit of DLC (diamond like carbon) on St37 steel. Then, an interlayer was performed before applying the main DLC coating using arc-PVD. Field emission scanning electron microscopy, x-ray diffraction, Raman spectroscopy, energy dispersive spectroscopy, adhesion and tribological tests were performed to characterize and evaluate of coatings. Many factors are responsible for the excellent wear and mechanical behaviors of the DLC PVD coating including the presence of TiCrAlN interlayer, the fine grains (30-40 nm), hardness gradient as well as Ti and Cr carbides. These factors, also led to reach the high adhesion for this coating. The grain size of DLC PACVD coating was measured approximately 70-110 nm. In addition the thickness of arc-PVD coating was less than that of the PACVD coating which caused lower internal stress and subsequently appropriate adhesion to the substrate. The results revealed that this coating had lower hardness and adhesion to the substrate than that of the DLC PVD.Keywords: PACVD, Arc, PVD, diamond like carbon, Nanostructured coating, St37 steel
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International Journal of iron and steel society of Iran, Volume:12 Issue: 2, Summer and Autumn 2015, PP 7 -16In the present study, the effects of growth defects and chromium content loss on the degradation of corrosion and passivation of cathodic arc evaporation (CAE-PVD) of stainless steel coating were investigated in 2 M sulphuric acid solution. EDS analysis indicated that the micro-particles were obtained during the coating growth. In addition, it was detected that the growth defects had poor adhesion to the coating matrix and in the open circuit potential (OCP), they were detached from the coating, providing appropriate conditions for the penetration of the solution. In addition, loss of chromium during evaporation was found to be detrimental to the passivation of the stainless steel coating and the formation of a porous oxide layer. The average percent of the main elements of the coating, according to EDS area analysis, was Fe-13Cr-6Ni. Moreover, the lower semicircle diameter of the coating in electrochemical impedance spectroscopy (EIS) measurements revealed the lower polarization resistance of it, in comparison to that of the bulk 304 stainless steel.Keywords: Stainless steel coating, CAE, PVD, Growth defects, Corrosion, Passivation
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هدف از پژوهش حاضر ارزیابی و مقایسه مشخصه های ساختار سطحی آلیاژ Ti 6Al 4V پس از انجام دو فرآیند مهندسی سطح شامل فرآیند نیتروژن دهی پلاسمایی و فرآیند دوتایی نیتروژن دهی پلاسمایی و لایه نشانی نیترید تیتانیم به وسیله رسوب فیزیکی از فاز بخار است. عملیات نیتروژن دهی پلاسمایی در دماهای 700، 750، 800 و °C850 به مدت 10 ساعت با ترکیب گاز نیتروژن و هیدروژن با نسبت 4 به 1 انجام شد. جهت انجام فرآیند دوتایی، لایه TiN به روش رسوب فیزیکی بخار به کمک پلاسمای قوس کاتدی، روی سطح نمونه های نیتروژن دهی پلاسمایی شده، نشانده شد. مشخصه یابی ساختار سطح و مقطع نمونه ها توسط میکروسکوپ نیروی اتمی (AFM)، میکروسکوپ الکترونی روبشی (SEM)، طیف سنج تفکیک کننده انرژی (EDS)، پراش سنج پرتو ایکس (XRD) و سختی سنج ویکرز انجام شد. در حالی که لایه نشانی نیترید تیتانیم به تنهایی منجر به تشکیل فاز TiN-δ شده، نیتروژن دهی پلاسمایی آلیاژ Ti 6Al 4V، باعث ایجاد لایه ترکیبی، شامل فازهای -TiNδ و -Ti2Nε، ناحیه غنی از آلومینیم و ناحیه نفوذی حاصل از نفوذ نیتروژن و تشکیل محلول جامد بین-نشین، شده است. الگوهای پراش پرتو ایکس مربوط به فرآیند دوتایی نشان دهنده حضور هم زمان پیک های متعلق به فازهای تشکیل شده در اثر هر دو فرآیند است. هرچند ساختارهای حاصل از هرکدام از دو فرآیند به تنهایی سختی سطح را افزایش داده است، سختی سطح خارجی در شرایط پوشش دوتایی در مقایسه با نمونه های نیتروژن دهی پلاسمایی شده به طور قابل توجهی افزایش یافته است. فصل مشترک ممزوج شده لایه TiN (حاصل از فرآیند PVD) با لایه ترکیبی (حاصل از نیتروژن دهی پلاسمایی) نقش مهمی در کارایی پوشش دوتایی داشته است. با افزایش دمای نیتروژن دهی پلاسمایی نه تنها نرخ تشکیل لایه TiN ایجاد شده با روش رسوب فیزیکی بخار افزایش یافته، بلکه پیوستگی لایه TiN به لایه ترکیبی نیز بهبود یافته است.
کلید واژگان: فرآیند دوتایی, نیتروژن دهی پلاسمایی, رسوب فیزیکی بخار, آلیاژ Ti 6Al 4VThe purpose of the present paper was evaluation and comparison of Ti 6Al 4V alloy structural surface characteristics after both surface engineering processes comprised of plasma nitriding (PN) and a PN process followed by TiN PVD deposition, duplex process. PN treatment performed under gas mixture of N2/H2=4; at temperatures of 700, 750, 800 and 850°C for 10 h. To perform duplex process, a TiN layer deposited by catholic were plasma PVD on the surface of pre plasma nitrided samples. Structural characterization of surface and cross section performed by scanning electron microscopy (SEM), atomic force microscopy (AFM), Energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and microhardness testing methods. While TiN deposition was led to formation of only δ-TiN phase, three distinguished structure including of compound layer (constituted of δ-TiN and ε-Ti2N), aluminum-rich region and a diffusion zone, interstitial solid solution of nitrogen in titanium, were detected at the surface of plasma nitrided Ti 6Al 4V alloy. XRD patterns of duplex treated samples were indicated the simultaneous present of phases which formed during both processes. Although the structures obtained from each one of the processes alone were increased surface hardness, the hardness of outer surface produced by duplex process was significantly higher than plasma nitrided samples. Interdiffused interface of TiN layer (resulted of PVD process) with compound layer (caused by PN process) has been a significant role on the duplex coating performance. Increasing of plasma nitriding temperature, not only increased growth rate of TiN deposition by PVD process, but also improved homogeneity and continuity of TiN with compound layer.Keywords: öööDuplex Process, Plasma Nitridin, PVD, Ti 6Al 4V Alloy
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