جستجوی مقالات مرتبط با کلیدواژه « double base solid propellants » در نشریات گروه « مواد و متالورژی »

In this work, a simple and selective method for the determination of nitroglycerine (NG) in double base solid (DB propellants) has been developed and validated. The proposed method is based on alkaline hydrolysis of NG and followed by colored reaction of released nitrite ion with p-nitroaniline in the presence of diphenylamine in acidic media, producing azo dye. The effect of important parameters on the solution absorbance was investigated and optimized. Under optimal conditions, at λmax= 534 nm, the linear range of determination of nitroglycerine was 0.2-5.0 µg mL-1 with detection limits of 0.1 µg mL-1. The proposed method was successfully applied to the determination of nitroglycerine in DB propellants with good recoveries ranged from 98-105 % and RSD less than 2.5 %. the results were statistically compared with those obtained by the by military standard 286 method using t- and F-tests. There was no significant difference between the mean values and the precisions of the two methods at the 95% confidence level. The results showed that the proposed method offers an accuracy and reliable approach for the determination of nitroglycerine in DB propellants, and can be suggested as a routine method in military quality control laboratories.

Double base solid propellant burning rate is highly dependent on the pressure, so that the combustion duration propellant rocket engines, combustion vibration leads to considerable changes in pressure. This could lead to an explosion in rocket engines. The best case is propellant combustion independent of pressure. Ballistic modifiers added to propellant formulation for reduce pressure sensitivity and reduce or increase of burning rate also. Lead and copper salts are materials that create plateau and mesa in double base propellant. In this article, effective ingredient in creation of plateau effect in double base propellant investigated. Some of these ingredients are particle size, concentration, dispersal, decomposition temperature and ability of ultraviolet ray of catalyst. In addition to, mechanism of create plateau and mesa in noncatalysed double base propellant and also empirical, radically and preckel mechanisms of create plateau and mesa for lead catalysts in double base propellant investigated.