جستجوی مقالات مرتبط با کلیدواژه "ethylene glycol" در نشریات گروه "مواد و متالورژی"
تکرار جستجوی کلیدواژه «ethylene glycol» در نشریات گروه «فنی و مهندسی»-
نانوسیال ترکیبی است که با افزودن ذرات در مقیاس نانو (100نانومتر) به یک سیال پایه با هدف بهبود انتقال حرارت حاصل می شود. در این پژوهش، تاثیر دما و غلظت نانوذرات متشکل از نانوذرات آلومینا و نانوصفحات گرافن بر هدایت حرارتی سیال پایه متشکل از آب و اتیلن گلیکول مورد مطالعه قرار گرفت. همچنین به میزان 2/0 درصد حجمی اولییک اسید (OA) و 2/0 درصد وزنی سدیم دودسیل سولفونات (SDS) به عنوان عامل فعال سطحی برای تثبیت و پراکندگی نانوذرات به سیال پایه اضافه شدند. کسرحجمی نانوذرات 05/0، 1/0، 5/0، 1، 5/1، 2 و 5/2 درصد حجمی و دماهای مورد آزمایش در بازه دمایی 305-260 کلوین انتخاب شد. ریخت شناسی و ریزساختار نانوذرات توسط میکروسکوپ الکترونی روبشی (SEM) و میکروسکوپ الکترونی عبوری (TEM) انجام شد. هدایت حرارتی نانوسیالات هیبریدی اندازه گیری و با سیال پایه مقایسه شد. نتایج نشان داد که هدایت حرارتی نانوسیال هیبریدی آب - اتیلن گلیکول / نانو گرافن - نانو آلومینا به غلظت نانوذرات و دما وابسته است. نتایج اندازه گیری هدایت حرارتی نانوسیال هیبریدی آب - اتیلن گلیکول / نانو گرافن - نانو آلومینا با مدل های پیش بینی هدایت حرارتی نانوسیالات مقایسه شد ولی تطابق قابل قبولی وجود نداشت. نتایج نشان داد که افزایش دما و غلظت حجمی نانوذرات موجب افزایش هدایت حرارتی نانوسیالات هیبریدی می شود. حداکثر افزایش هدایت حرارتی نانوسیال هیبریدی برابر با 02/44 درصد بود که در کسر حجمی جامد 5/2 درصد و در دمای 303 کلوین حاصل شد.
کلید واژگان: نانوسیال هیبریدی, اتیلن گلیکول, هدایت حرارتی, نانو ذرات آلومینا, نانوصفحات گرافنNanofluid is a suspension obtained by adding nanoscale particles (100 nm) to a base fluid to improve heat transfer. In this study, the effect of temperature and concentration of nanoparticles consisting of Alumina nanoparticles and Graphene nanosheets on the thermal conductivity of a base fluid consisting of water and ethylene glycol was studied. Also, 0.2% by volume of oleic acid (OA) and 0.2% by weight of sodium dodecyl sulfonate (SDS) were added to the base fluid as a surfactant to stabilize and disperse the nanoparticles. The volume fraction of nanoparticles of 0.05, 0.1, 0.5, 1, 1.5, 2 and 2.5% by volume and the tested temperatures were selected in the temperature range of 260-305 K. The morphology and microstructure of the nanoparticles were investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Thermal conductivity of hybrid nanofluids was measured and compared with the base fluid. Results showed that thermal conductivity of water-ethylene glycol / nano Graphene-nano Alumina hybrid nanofluid depends on nanoparticle concentration and temperature. The thermal conductivity measurements of water-ethylene glycol / nano Graphene-nano Alumina hybrid nanofluid were compared with the thermal conductivity prediction models of nanofluids but there was no acceptable agreement. The results showed that increasing the temperature and volumetric concentration of nanoparticles increases the thermal conductivity of hybrid nanofluids. The maximum increase in thermal conductivity of hybrid nanofluid was 44.02% which was obtained in solid volume fraction of 2.5% and at temperature of 303 K.
Keywords: Hybrid nanofluid, ethylene glycol, thermal conductivity, alumina nanoparticles, graphene nanosheets -
In this study, Pd-Co alloying nanoparticles supported on reduced graphene oxide (rGO) were synthesized and characterized by various techniques such as field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray (EDX), X-ray diffraction (XRD), and Raman spectra. The prepared Pd-Co/rGO nanoparticle was used as the electro-catalyst for the ethylene glycol (EG) oxidation reaction in the alkaline medium. The activity of Pd-Co/rGO was evaluated in the half-cell by cyclic voltammetry (CV) technique. Results demonstrate that Pd-Co/rGO electro-catalyst has higher performance compared to simple alloyed-based Pd electro-catalysts for EG electro-oxidation in alkaline media. Pd-Co/rGO catalyst showed well-defined peaks for the EG oxidation reaction after 150 CV cycle. This result indicated that Pd-Co/rGO electro-catalyst is still active in EG oxidation reaction even after 150 CV cycles, suggesting high poisoning toleration of Pd-Co/rGO electro-catalyst in the EG oxidation reaction. The results of electrochemical experiments indicated that Pd-Co/rGO could be practically used as the high-efficiency anode electro-catalyst for the EG oxidation reaction in alkaline media.Keywords: Catalyst Activity, Electro-oxidation Reaction, Ethylene glycol, Graphene oxide, Pd-Co, rGO Electro-catalyst
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Magnesium has been used in aviation industries, automobile manufacturing, electronics and medical engineering due to its unique properties thus far. The main problem in its utilization is the high reactivity of magnesium with oxygen and humidity, which both changes its properties. The surface charge and different density results in difficulties in dispersion stability of the powder in an organic medium. Therefore, numerous methods have been applied to improve the chemical resistance and surface modification of the powder particles. The ball milling process as well as immersion in Ethylene Glycol (EG) was used in this study to increase chemical resistance and micro-sized powder dispersion stability in an organic medium. The x-ray powder diffraction analysis was applied to analyze the phase constitutions formed on the powder surface. Scanning electron microscope (SEM) was also utilized to obtain the morphology and the particle size. Moreover, the simultaneous thermal analysis was executed for determining thermal resistance and reactions, which both were measured dispersion stability before and after ball milling process. Results showed a decrease in average particle size from 100 to 7 μm. The chemical resistances and the stabilization increased in organic solvents.Keywords: magnesium powder, ball milling, ethylene glycol, chemical resistance
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The electrochemical behavior of 6063 aluminum alloy in ethylene glycol-water mixture was investigated by polarization curves and AC impedance measurements (EIS). The results obtained from polarization curves showed that corrosion rate decreased with increasing ethylene glycol concentration. EIS data showed the decrease in the interface capacitance which caused by adsorption of ethylene glycol at the surface of aluminum alloy. The cathodic current increased with the increase in rotating speeds of solution and the anodic current decreased. The effect of temperature was studied and the corrosion rate was increased with increasing the temperature. In addition, thermodynamic parameters were calculated in different ethylene glycol concentrations.Keywords: Corrosion, Aluminum 6063, Ethylene glycol, Hydrodynamic, Temperature
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خوردگی و بازدارندگی خوردگی فولاد ساده کربنی CK10 در محلول %3 کلرید سدیم اشباع از گاز CO2 توسط عصاره انیسون (AE) محلول در اتیلن گلایکل (EG) بوسیله نمودارهای پلاریزاسیون، طیف سنجی امپدانس الکتروشیمیایی (EIS) و روش آنالیز سطحی AFM مورد بررسی قرار گرفت. بازده بازدارندگی با افزایش غلظت عصاره انیسون و دما افزایش یافت. نتایج نشان می دهد که عصاره ی انیسون به عنوان یک بازدارنده از طریق مکانیزم مختلط عمل می نماید و فرآیند بازدارندگی به تشکیل یک فیلم جذب شونده شیمیایی از AE و EG بر روی سطح فلز از طریق موقعیت های جذب چند مرکزی نسبت داده می شود. پارامترهای ترمودینامیکی جذب بازدارنده با استفاده از ایزوترم جذب لانگمیر محاسبه شد. مطالعات مورفولوژیکی از سطح الکترود فولاد ساده کربنی توسط میکروسکوپ نیروی اتمی(AFM) انجام شد.
کلید واژگان: فولاد ساده کربنی, خوردگی CO2, بازدارنده, عصاره انیسون, اتیلن گلایکلThe corrosion and corrosion inhibition of CK10 carbon steel in CO2-saturated 3% NaCl solution by anise extract (AE) dissolved in ethylene glycol (EG) was studied using polarization curves، electrochemical impedance spectroscopy (EIS) and surface analysis (AFM) methods. Inhibition efficiency increased with increase in AE concentration and temperature. The data suggest that AE functioned as inhibitor via a mixed-inhibitor mechanism and the inhibition process is attributed to the formation of a chemically adsorbed film of AE and EG on the surface of the metal via its polycentric adsorption sites. Thermodynamic adsorption parameters of studied inhibitor were calculated using the Langmuir adsorption Isotherm. Morphological studies of the carbon steel electrode surface were undertaken by atomic force microscopy (AFM).
Keywords: CK10 carbon steel, CO2 corrosion, Inhibitor, Anise extract, Ethylene glycol -
In this paper, the natural convection heat transfer of Al2O3-EG-water nanofluid in a rectangular cavity which is heated from the bottom and is cooled from the top has been investigated numerically. The governing equations for a Newtonian fluid have been solved numerically with a finite volume approach using the SIMPLER algorithm. The main focus of the current study is on the effects of variable thermophysical properties of nanofluid on the heat transfer in natural convection. The influence of pertinent parameters such as Rayleigh number (Ra=105-107) and volume fractions of nanoparticles (0≤Φ≤0.05) on the heat transfer characteristics of natural convection have been studied. The results have shown that the average Nusselt number is reduced by increasing the volume fraction of nanoparticles. To study the significance of temperature effect on thermophysical properties of nanofluid, the results obtained by using variable properties of nanofluid are compared with those of constant properties.Keywords: Nanofluid, Variable properties, Rayleigh–Benard convection, Ethylene Glycol, Enclosure
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In this study, the effect off adding SiO2 nanoparticles on the viscosity of base fluid is investigated experimentally. Base fluids are chosen among common heat transfer fluids such as ethylene glycol, transformer oil and water. In addition different volume percentages of ethylene glycol in water are used as ethylene glycol-water solution. In every base fluid different volume fractions of SiO2 nanoparticles is added. It is shown that the viscosity of solution enhance by adding nanoparticles. The effect of cooling and heating process on the viscosity of nanofluid is also discussed. The presented data show that as the temperature increases the viscosity of base fluid and nanofluid decrease. It is also revealed that there are very little differences between the viscosity of nanofluid in a specific temperature at cooling and heating cycles. According to the experimental results new correlations for predicting the viscosity of nanofluids is presented. These correlations relate the viscosity of nanofluid to the particle volume fraction and temperature.Keywords: Ethylene glycol, water solution, Transformer oil, Viscosity, Nanofluid, Heating, cooling cycles
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