جستجوی مقالات مرتبط با کلیدواژه "hydrotalcite-derived catalysts" در نشریات گروه "مهندسی شیمی، نفت و پلیمر"

Several mesoporous nickel-based catalysts with MgO-Al2O3 as the catalyst support were prepared using a co-precipitation method at a constant pH. The supports were prepared from the decomposition of an Mg-Al hydrotalcite-like structure which had already been prepared with Mg/Al=1. Prior to impregnating 10 wt.% nickel on the supports, the precursor was decomposed at several temperatures of 500, 600, 700, and 800 °C in order to elucidate the effect of calcination temperature on the physical and chemical characteristics of Mg-Al mixed oxides and the ultimate catalytic performance of the synthesized catalysts in the combined steam and dry reforming (CSDRM). The catalyst the precursor of which was calcined at 700 °C shows an excellent nickel dispersion and the highest activity among the other samples. It also exhibits the most stable performance during the long-term 36-hour run with high resistance against coke formation in the harsh condition of CSDRM.