جستجوی مقالات مرتبط با کلیدواژه "nmr" در نشریات گروه "مهندسی شیمی، نفت و پلیمر"
تکرار جستجوی کلیدواژه «nmr» در نشریات گروه «فنی و مهندسی»-
Determining and estimating reservoir properties such as capillary pressure and relative permeability are always challenging in reservoir studies. The current research has been done in the Sarvak Formation in the southwestern oilfields of Iran, focusing on applying Nuclear Magnetic Resonance (NMR) logging in synthesizing capillary pressure and relative permeability. In this study, the Sarvak Formation in the studied well was divided into three flow units using the Hydraulic Flow Unit method. Then, for each separate flow unit, the capillary pressure curves were calculated and illustrated from the NMR T2 distribution data. Next, the calculated capillary pressure curves were corrected concerning the laboratory capillary pressure data derived from SCAL. Then, the conversion factor to calibrate well log-derived Pc curves to SCAL Pcs was determined for each flow unit. Afterward, mathematical functions for capillary pressure curve estimation were written using MATLAB software. Next, the relative permeability for oil and water phases was calculated and plotted in MATLAB software based on the functions determined in the previous step. Finally, the representative capillary pressure curve and relative permeability curve of the oil and water phases were determined for each flow unit. The results showed an increasing trend in the reservoir quality from flow units 1 to 3. Flow unit 3 had the lowest capillary pressure with the highest relative permeability and, consequently, better reservoir quality. In contrast, flow unit 1 had the highest PC levels, the lowest relative permeability, and the lowest reservoir quality.Keywords: Nuclear Magnetic Resonance, NMR, Relative Permeability, Capillary Pressure, Sarvak Formation
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فرضیه:
یکی از پارامترهای مهمی که در سنتز پلیمرهای وینیلی، نقش بسزایی بر خواص فیزیکی-مکانیکی محصول نهایی دارد، نظم فضایی مونومرها درون زنجیر پلیمری است. پلی متیل متاکریلات یکی از پلیمرهای مهم صنعتی به شمار می رود که نحوه سنتز آن می تواند اثر عمده بر این پارامتر و در نهایت خواص نهایی داشته باشد. از عواملی که اثر شایان توجهی بر آرایش فضایی این پلیمر دارد، دمای واکنش است.
روش ها:
پلی متیل متاکریلات با پلیمرشدن رادیکالی آزاد توده ای-گرمایی در سه دمای مختلف 50، 150 و 250 سنتز شد. طیف نمایی رزونانس مغناطیسی هسته مهم ترین ابزاری است که برای بررسی نظم فضایی می توان به کار گرفت. آرایشمندی پلی متیل متاکریلات با در نظرگرفتن شکافت پروتون گروه آلفا-متیل و شکافت کربن گروه آلفا-متیل و کربونیل به کمک طیف نمایی پروتون (1HNMR) و کربن (13CNMR) در حلال های کلروفرم و تتراهیدروفوران دوتریم دار مطالعه شد. گمارش تمام توالی فضایی پیک های پروتون آلفا-متیل به شکل توالی سه تایی و پیک های کربن آلفا-متیل و کربن کربونیل به شکل پنج تایی به کمک طیف نمایی تشدید مغناطیسی هسته مایع انجام شد. مدل های آماری برنولی و مارکوف مرتبه اول برای نمونه های سنتز شده محاسبه و با نتایج تجربی مقایسه شد.
یافته ها:
نتایج نشان می دهد، احتمال افزایش توالی های مزو (Pm) با افزایش دمای پلیمرشدن، افزایش می یابد. مقادیر احتمال وجود توالی مزو برای پلی متیل متاکریلات سنتزشده در دماهای 50، 150 و 250 سلسیوس به ترتیب 0.203، 0.274 و 0.356 تعیین شد. در نهایت اثر آرایشمندی پلی متیل متاکریلات بر دمای گذار شیشه ای با گرماسنجی پویشی تفاضلی بررسی شد. نتایج نشان داد، پلی (متیل متاکریلات) سنتزی در دماهای 50، 150 و 250 به ترتیب دارای دمای گذار شیشه ای 126.0، 125.1و 102.9 درجه سلسیوس هستند.
کلید واژگان: پلی متیل متاکریلات, ریز ساختار, نظم فضایی, طیف سنجی رزونانس مغناطیسی هسته, پلیمرشدن رادیکالی آزادHypothesis:
In the synthesis of vinyl polymers, one of the important parameters that play a significant role in the physical-mechanical properties is the tacticity of monomers within the polymer chain. Polymethyl methacrylate is considered one of the important industrial polymers. The method of its synthesis can have a major effect on this parameter and finally on the final properties. One of the parameters that has a significant effect on the stereoregularity of this polymer is the reaction temperature.
MethodsThe poly methyl methacrylate was synthesized at three different temperatures of 50, 150, and 250 °C via bulk thermal polymerization method. The most important instrument that can be used to study tacticity order is nuclear magnetic resonance spectroscopy. The tacticity of the polymethyl methacrylate (PMMA) was investigated and studied through alpha-methyl protons splitting and alpha-methyl and carbonyl carbons splitting, respectively, by proton (1HNMR) and carbon (13CNMR) nuclear magnetic resonance spectroscopy in deuterated chloroform (CDCl3) and deuterated tetrahydrofuran (THF-d8). The assignment of all stereosequences at triad level for alpha-methyl proton and pentad level for alpha - methyl carbon and carbonyl carbon were carried out by liquid nuclear magnetic resonance spectroscopy in deuterated chloroform. Bernoullian and first-order Markov statistics models were calculated for the synthesized sample and compared with the experimental results.
FindingsThe results indicated that probability of meso (Pm) was increased by increasing the methyl methacrylate polymerization temperature. The corresponding probability of meso values determined for synthesized polymethyl methacrylate at 50, 150, and 250°C were 0.203, 0.274, and 0.356, respectively. Finally, the effect of tacticity on glass transition temperature using differential scanning calorimetry (DSC) is discussed. The temperature glassy (Tg) values by DSC results were shown that the synthesized polymethyl methacrylate at 50, 150, and 250°C had 126.0, 125.1 and 102.9 oC, respectively.
Keywords: polymethyl methacrylate, microstructure, tacticity, NMR, Thermal Bulk Polymerization -
A detailed description of the carbonate reservoir is an important step in preparing a field development plan. An accurate determination of petrophysical parameters and rock characteristics are key parameters in the carbonate reservoir description. The rock properties are traditionally obtained from different techniques such as lab measurement, well logging, well test, etc. In this manuscript, data from core measurements and NMR measurements are analyzed to study the petrophysical properties of Cretaceous carbonate rock from Asmari Formation. First, the pore size, pore system, porosity and permeability are determined from the core measurements and NMR Analysis. Second, the results of core and NMR evaluations are compared, and the reasons for differences are distinguished. Comparison between the porosity values demonstrates that porosity from NMR and helium injection experiments are very similar in which the average porosity is 21.4 % and NMR porosity is 20.68%. Afterwards, pore sizes received from the NMR model show reliable results and match the pore size distribution determined from the MICP experiment. The permeability value is modeled with NMR permeability predicting models, namely Standard Kenyon and Timur-Coates. Adjusted NMR Permeability results are 17.7 (mD) and 18 (mD) for (SDR) and (TC) methods, respectively, and they are consistent with laboratory core permeability results (Kg=22, Kl=19.2, Kw=18.4). The pore throat distributions are also similar for two NMR and core measurement methods. This study shows how NMR analysis could be useful in determining petrophysical parameters. Ultimately, the results for reservoir characteristics of carbonate rock obtained by core and NMR experiments are compared quantitatively and qualitatively.Keywords: NMR, core measurement, Permeability, Porosity, Pore Size Distribution, SDR, Timur-Coates models, Thin Section
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In particular, quantitative laboratory measurements are challenging to perform due to their costs and time consumption. So, the need to explore other available data interconnectivity to permeability is of great importance. One of these data is NMR (Nuclear Magnetic Resonance) log data which have been used frequently in recent studies. It is considered to segregate different groups, which can be obtained through cluster analysis. Using reliable parameters in the cluster analysis helps to segregate different rock units which can be used in the permeability models. To select reliable parameters, cross plots of the permeability versus extracted features from the NMR T2 distribution curve were plotted. Results indicate that TCMR, peak reading amplitudes, and T2Lm are the best permeability indicators, respectively. Cluster analysis was performed on T2LM, TCMR and Peak reading amplitudes, which showed the highest consistency with core derived data compared with other parameters. The crucial step is to determine the best estimate of the number of clusters. It is usually taken as a prior in most clustering algorithms. In this research, Davies-Bouldin criterion values versus the number of clusters were used to obtain the optimal number of clusters. The knee method, which finds the “knee” in many clusters vs. clustering evaluation graph, was used. A clustering model with the number of clusters from 2-100 was created. It showed the five is an optimal number of clusters. Subsequently, the Schlumberger-Doll-Research (SDR) coefficients for each cluster were modified using a curve fitting tool in the Matlab software. Results indicated that calculated permeability using cluster analysis showed a higher correlation by core derived permeability than the original SDR permeability model. Since this is the core part of the group attempt to use extracted T2 distribution features in permeability estimation in carbonate reservoirs, more investigation is required to attempt satisfactory results to standardize the value of the coefficient of the permeability models in carbonate rocks with different petrophysical properties.
Keywords: NMR, Peak Analysis, Clustering, Timur-Coates, SDR -
Permeability is arguably the most critical property for evaluating flow in the reservoir. It is also one of the challenging parameters which must be measured in the field. Nuclear Magnetic Resonance (NMR) logging across the borehole is among the popular techniques, which it is utilized to determine permeability across the reservoir. However, available correlations in literature for estimating permeability from NMR data do not usually provide acceptable accuracy in the carbonate rocks. Therefore, a new model is proposed to estimate permeability by establishing a relationship between core derived permeability and extracted features from the T2 distribution curve of NMR data with the ensemble LSBoost algorithm. The feature extraction process is performed using peak analysis on T2 distribution curves which it leads to 5 relevant parameters, including T2lm, TCMR, prominence, peak amplitude and width. The proposed model is validated by comparing the proposed method’s correlation coefficient against Timur-Coates and SDR equation estimation accuracy. The results show that our model generally provides better prediction accuracies in comparison with the empirical equation-based derived permeabilities.Keywords: NMR, T2 distribution, LSBoost, Timur-Coates, Permeability
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Since the development bloom in unconventional reservoirs in North America, total organic carbon (TOC) has become a more essential parameter, as the indicator of the efficiency of these reservoirs. In this paper, by using conventional well logs and NMR log data, the TOC content of an unconventional reservoir in West Africa is estimated. Passy’s, Issler’s, and Schmoker’s methods were used as indirect wireline methods to estimate TOC content, along the well paths. Afterward, NMR log data, as a direct method, was used to provide more precise calculations of TOC. Both methods showed almost similar trends, with the NMR method indicating lower values for the TOC. Then, an adjusted Schmoker equation was proposed, which showed the best fit between NMR and conventional well logs results. By using the equation, the TOC content was calculated in three other wells, where NMR data were unavailable. The results were then used to prepare a 3D model of the TOC distribution, within the reservoir.Keywords: NMR, TOC, unconventional reservoirs, Well Logs, West African
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مخازن هیدروکربنی (به خصوص انواع کربناته) به دلیل اثر دیاژنز از نظر نوع منافذ و شعاع منفذی بسیار متنوع می باشند. از آنجایی که توزیع منافذ و فشار مویینه در سنگ مخزن از کنترل کننده های اصلی حرکت سیال در فضای متخلخل است، به همین دلیل تعیین نوع و اندازه منافذ و همچنین فشار مویینه نقش اساسی در خواص پتروفیزیکی، بهینه سازی تعداد چاه ها در یک میدان و پیش بینی هیدروکربن قابل بازیافت دارد. در این مقاله انواع منافذ در سازند مختلط کربناته-آواری آسماری با استفاده از نگار انحراف سرعت در 3 رده (انحراف مثبت، انحراف صفر و انحراف منفی) و 8 زیررده طبقه بندی شدند. 6 زیررده مربوط به بخش کربناته (درون ذره ای یا درون فسیلی، قالبی یا حفره ای، ریزتخلخل، بین ذره ای، بین بلوری و شکستگی) و 2 زیررده دیگر مربوط به بخش آواری (بین دانه ای و ریزتخلخل شیل) می باشند. پس از شناسایی انواع منافذ با استفاده از نگار انحراف سرعت، مقدار تخلخل، تراوایی، شعاع منفذی و فشار شبه مویینه در هر زیررده بطور پیوسته در امتداد چاه و سازند مورد مطالعه با استفاده از نگار تشدید مغناطیس هسته ایی تعیین شدند. به منظور اعتبارسنجی اندازه شعاع منافذ و فشار شبه مویینه از منحنی های فشار تزریق جیوه نیز استفاده شده است. نتایج این مطالعه نشان می دهد، که تولید از مخزن آسماری تحت کنترل منافذ نوع بین دانه ای در بخش آواری و منافذ نوع شکستگی، بین ذره ای و بین بلوری در بخش کربناته می باشد. توزیع هریک از این 4 نوع منفذ بطور پیوسته با استفاده از نگارها در امتداد چاه مشخص شده است.
کلید واژگان: نوع منافذ, نگار انحراف سرعت, نگار تشدید مغناطیس هسته ای, سازند آسماری, فروافتادگی دزفولIn hydrocarbon reservoirs (especially in carbonate rocks)، the variation of pore type and size is influenced by diagenesis effects. Hence pore type distribution and capillary pressure in the reservoir rock is the main factor controlling fluid flow in porous media. In other words، the determination of pore type/size and capillary pressure has an important role in understanding petrophysical features، optimizing the number of wells in the field، and forecasting the recoverable hydrocarbon. In this paper، pore types in the mixed carbonate-siliciclastic Asmari formation is divided by velocity deviation log into three classes (positive، zero، and negative deviation) and eight subclasses. Six subclasses are related to carbonate part (interaparticle or interafossil، moldic or vuggy، microporosity، interparticle، intercrystalline، and fracture) and two subclasses are related to clastic part (intergranular and shale microporosity). After identifying pore types، pore size and pseudo capillary pressure are continuously determined in each subclasses throughout the well bore by using NMR log. Pore size and pseudo capillary pressure are compared by mercury injection capillary pressure curves. The results of this study show that intergranular porosity is the main factor for production in calstic intervals; however، fracture، interparticle، and intercrystalline porosities play an important role in carbonate intervals. The distributions of each four pore types are continuously determined along the well bore.Keywords: Pore Type, Velocity Deviation Log, NMR, Asmari Formation, Dezful Embayment -
Microstructural investigation of low molecular weight 1,4-polybutadiene (1,4-PBD) was studied by 1H and 13C nuclear magnetic resonance spectroscopy (NMR). The isomer contents of 1,4-cis, 1,4-trans and 1,2- vinyl in polybutadiene microstructure were determined. The number average molecular weight for low molecular weight polybutadiene was measured by NMR techniques and comparison was made with gel permeation chromatography (GPC) results. Due to the presence of methyl end group and considering the repeating units in 1,4-PBD microstructure, the number average molecular weight was calculated by NMR techniques. This study was accomplished by obtaining cis-trans isomerization in non-pyrolytic anaerobic conditions at 200 to 250oC. The results showed that increase in heat treatment time increased the trans isomer and decreased the cis isomer contents respectively. The presence of 1,2-vinyl isomers increased the average molecular weights by heat treatment time at 250oC and did not lead to any chain scission in 1,4-PBD.Keywords: polybutadiene, NMR, microstructure, thermal rearrangement, GPC
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