به جمع مشترکان مگیران بپیوندید!

تنها با پرداخت 70 هزارتومان حق اشتراک سالانه به متن مقالات دسترسی داشته باشید و 100 مقاله را بدون هزینه دیگری دریافت کنید.

برای پرداخت حق اشتراک اگر عضو هستید وارد شوید در غیر این صورت حساب کاربری جدید ایجاد کنید

عضویت

جستجوی مقالات مرتبط با کلیدواژه « Wastewater » در نشریات گروه « مهندسی شیمی، نفت و پلیمر »

تکرار جستجوی کلیدواژه «Wastewater» در نشریات گروه «فنی و مهندسی»
  • Saeid Jabbarzare *
    SnO2 nanoparticles were first synthesized using a grape extract media, then characterized by XRD, FE-SEM, TEM, BET, and DLS techniques, and finally used as an efficient adsorbent for the removal of Pb2+ and Cd2+ ions from wastewater. The prepared sample had a tetragonal phase with an average crystallite size of 41 nm (XRD analysis), a specific surface area of 47.08 m2.g-1 (BET method)/46.25 m2.g-1 (BJH method), and a pore diameter of 6.49 nm (BJH method). The best conditions for adsorbing were a 30 ppm concentration of metal ions, ambient temperature, pH of 6, and 0.025 g of an adsorbent. The maximum adsorption for Pb and Cd ions was 97 and 93%, respectively. The Elovich model was matched as the most suitable kinetic model, indicating that the adsorption mechanism is chemical adsorption. The negative values of ΔG (Pb: -6.38 kJ.mol-1; Cd: -4.16 kJ.mol-1) represent the spontaneousness of the adsorption process. The negative values of the parameters ΔH (Pb: -63.0 kJ.mol-1; Cd: -42.95  kJ.mol-1) and ΔS (Pb: -188.8 J.mol-1; Cd: -128.4 J.mol-1) represent the exothermic nature of the adsorption.
    Keywords: Removal of heavy metals, Kinetic, thermodynamic, grape extract, Wastewater, SnO2}
  • Pegah Bahman, Tayebe Bagheri Lotfabad *, Amir Heydarinasab, Soheila Yaghmaei
    Industries extensively use synthetic dyes, and it is crucial to eliminate them from effluents to prevent their accumulation in nature. The elimination of synthetic dyes is effectively achieved through the well-established method of adsorption; previous researchers have developed a range of materials dedicated to the adsorption of such dyes. In this regard, natural materials have received much attention as environmentally friendly. This study examined the ability of SiO2-based stone samples, including silica, zeolite, pumice, and scoria, to adsorb carmoisine and malachite green dyes from water. The ball-milling method was utilized to prepare the nanosized adsorbents. Physicochemical properties were evaluated by analytical methods, including dynamic light scattering (DLS), X-ray diffraction (XRD), X-ray fluorescence (XRF), Brunauer-Emmett-Teller (BET), and Fourier transform infrared spectroscopy (FTIR). The removal of dyes was experimentally undertaken utilizing both granular and nanosized adsorbents with conditions of 30°C temperature, pH 7, and initial dye concentrations set at 45 mg/l.  Adsorption isotherm models and kinetic models were evaluated for dye adsorption. The highest levels of adsorption capacities for carmoisine and malachite green were 54.42 and 19.01 mg/g, respectively. The findings of this research demonstrated that nanosized scoria and silica have the potential to be used as efficient adsorbents in cationic and anionic dye removal, respectively.
    Keywords: Synthetic Dyes, Adsorption, Wastewater, Silica, Natural Porous Materials}
  • Arvind Swarnkar *, Samir Bajpai, Ishtiyaq Ahmad

    The quality of groundwater (GW) depends on its surrounding environment, such as population, drains, ponds, and industries. This study evaluated the improvement of wastewater (WW) quality due to the wetland and ponds in the Amanaka, Raipur region of Chhattisgarh, India, and their impact on GW. Water samples were taken at four different locations to measure physicochemical parameters: pH, electrical conductivity (EC), total dissolved solids (TDS), hardness, dissolved oxygen (DO), biochemical oxygen demand (BOD5), chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN), nitrate nitrogen (NN), and total phosphorus (TP). The removal efficiency (RE) obtained through the wetland was 50.0% for BOD5, 87.9% for COD, 71.4% for TKN, 87.2% for NN, and 56.5% for TP from the influent. The obtained RE from the wetland to the pond was 72.6% for BOD5, 40.0% for COD, and 89.6% for TP during the pre-monsoon. According to the findings, GW quality was good, even though ponds, wetlands, and some small-scale industries surround it. The government should also monitor landfills, home garbage, and agricultural activities for sustained GW quality. All borewell water is drinkable.

    Keywords: Wetland, Wastewater, pond, Borewell, Groundwater, Water Quality}
  • محمد پوربابا، منصوره سلیمانی*

    تاکنون روش های مختلف شیمیایی (اکسایش و تخریب الکتروشیمیایی)، بیولوژیکی (حذف با زیست توده میکروبی و سامانه های بی هوازی) و فیزیکی (مانند جذب سطحی و مبادله یونی) برای حذف رنگ ها به عنوان یکی از مهم ترین آلاینده های آب پیشنهاد شده که در این مطالعه روش کاویتاسیون هیدرودینامیک (ایجاد حباب در یک مایع) به عنوان روشی نوین انتخاب شده است. از ویژگی های بارز این روش می توان به بی نیازی از استفاده مواد شیمیایی، مصرف انرژی کم و قابلیت ترکیب آسان با سایر روش های حذف رنگ اشاره کرد. بررسی پیشینه مطالعات پژوهشی درزمینه حذف رنگ با استفاده از ترکیب فرایند کاویتاسیون هیدرودینامیک با سایر فرایندهای اکسایش پیشرفته نشان داد که اغلب از اوریفیس و ونتوری برای تولید حباب در سامانه استفاده و در مدت زمان کمتر از حباب ساز، فشار ورودی، دمای عملیاتی، pH و خواص مایع مانند فشار بخار، گران روی و  2h و در شرایط بهینه عملیاتی بیش از 80% از رنگ حذف شده است. عواملی مانند شکل هندسی کشش سطحی بر فرایند تصفیه موثر هستند. نتایج کارهای پیشین بیانگر بازدهی بسیار مناسب این روش در ترکیب با سایر فرایندها و روش ها مانند فنتون، فتوکاتالیستی، ازن دهی، هوادهی و حضور انواع یون های فلزی و غیرفلزی در محیط واکنش است. هم چنین انعطاف پذیری در طراحی و ترکیب با سایر فرایندهای اکسایش پیشرفته بسته به هدف و نیاز محل کاربرد از دیگر برتری های اصلی و مهم برای جای گزینی این روش با روش های مرسوم امروزی در آینده نزدیک است.

    کلید واژگان: صفیه, حذف رنگ, آب, پساب, کاویتاسیون هیدرودینامیک}
    M. Poorbaba, M. Soleimani *

    Until now, various chemical treatments (oxidation and electrochemical destruction), biological treatments (microbial cultures and anaerobic bioremediation systems) and physical treatments (such as adsorption and ion exchange) have been proposed to remove dyes as one of the most important water pollutants. In this study, hydrodynamic cavitation (bubble formation in a liquid) was considered as a new method for dye removal. The important advantages of this method are no need to use chemicals, low energy consumption and the ability to combine with other advanced oxidation processes. A literature review on dye removal focusing on combination with other advanced oxidation processes indicated that orifice plates and venturi tubes are often used and less than 2 h (in optimum operating conditions) more than 80% of dye was removed. Also, factors such as device geometry, inlet pressure, operating temperature, pH and liquid properties (like vapor pressure, viscosity and surface tension) are effective parameters in this process. The results of previous works imply excellent efficiency of this method in combination with other processes and methods such as Fenton, photocatalytic, ozonation, aeration and presence of various metal and non-metallic ions in the reaction medium. Also, flexibility in designing and combining with advanced oxidation processes, depend on the purpose, are another major and important advantages for replacing this method with conventional methods in the near future.

    Keywords: treatment, Dye removal, Water, Wastewater, Hydrodynamic Cavitation}
  • Swati Singh, Pradeep Sharma *, Anju Rani, Pratibha Naithani
    A lab based hybrid constructed wetland system (1.645 m2) consisting of sludge drying bed (0.135 m2), vertical sub-surface flow bed (0.58 m2), and horizontal sub-surface flow bed (0.93 m2) was operated for the treatment of septage. All the beds were filled with gravels of varied sizes (5-40 mm), sand (0.25 mm) and planted with Canna indica L. Average concentration in influent and effluent was observed as; BOD5 (2395.6±1196.4 and 41.87±8.9 mg/L), COD (7442± 7342.6 and 29.6±7.6 mg/L), TSS (4965.9±801.69 and 336.1±152.9 mg/L), TN (1774.8±693.5 and 55.7±13.7 mg/L), and Total P (849.3±237.7 and 7.05±3.5mg/L) during study period. Hybrid System was operated with high influent loads of BOD5 (175.2± 87.5 g m-2 d-1), COD (544.5±537 g m-2 d-1), TSS (363.3±58.6 g m-2 d-1), Total N (129.8±50.7 g m-2 d-1), NH4-N (7.8±1.1 g m-2 d-1), and Total P (62.1±17.4 g m-2 d-1), throughout the study period. Hybrid-CW has showed significant removal of BOD5 (99.1±0.3%), COD (99.7±0.3%), TS (98.2±6.8%), TSS (96.9±4.9%), Total N (98.4±0.4 %), NH4-N (94.8±0.1%), and Total P (99.6±0.1%) from the septage. Finally treated septage met effluent discharge standards for all parameters except BOD5.
    Keywords: Septage, Hybrid Constructed wetland, Wastewater, BOD, Sludge drying bed}
  • فرزاد مهرجو *، محمدصابر باغخانی پور، امیر علم

    وجود یون های فلزات سنگین در پساب های آلوده تهدیدی جدی برای سلامت انسان بوده و دفع صحیح آن ها از اهمیت بالایی برخوردار است. استفاده از غشاهای نانوصافش (Nanofiltration) به دلیل عملکرد کارآمد، طراحی سازگار و مقرون به صرفه بودن، به عنوان یکی از موثرترین روش های حذف یون فلزات سنگین از پساب مطرح شده است. غشاهای نانوصافش (NF) ایجادشده از مواد پیشرفته به دلیل توانایی آن ها در آلودگی پساب در شرایط مختلف به طور فزاینده ای محبوب شده اند. ثابت شده است که ویژگی های غشای نانوصافش (NF) برای حذف کارآمد یون های فلزات سنگین از پساب، روش های پلیمرشدن سطحی و پیوند، همراه با افزودن پرکننده های نانو، موثرترین روش های اصلاح هستند. این پژوهش مروری بر فرایندهای اصلاح و عملکرد غشای نانوصافش (NF) برای حذف فلزات سنگین از پساب و همچنین بررسی کاربرد این غشاها برای تصفیه پساب یون فلزات سنگین است. بازده تصفیه بسیار بالا، مانند 90/99 %، با استفاده از غشاهای متشکل از پلی وینیل آمین (Polyvinyl Amine) و گلوتارآلدیید (Glutaraldehyde) برای حذف کروم سه ظرفیتی از پساب به دست آمده است. با این حال، غشاهای نانوصافش (NF) دارای معایب خاصی از جمله رسوب غشا هستند که تمیز کردن مکرر غشا بر طول عمر آن تاثیر می گذارد.

    کلید واژگان: غشاء, نانوصافش, فلزات سنگین, حذف, پساب}
    Farzad Mehrjo *, MohammadSaber Baghkhanipour, Amir Alam

    The presence of heavy metal ions in polluted wastewater represents a serious threat to human health, making proper disposal extremely important. The utilization of nanofiltration (NF) membranes has emerged as one of the most effective methods of heavy metal ion removal from wastewater due to their efficient operation, adaptable design, and affordability. NF membranes created from advanced materials are becoming increasingly popular due to their ability to depollute wastewater in a variety of circumstances. Tailoring the NF membrane’s properties to efficiently remove heavy metal ions from wastewater, interfacial polymerization, and grafting techniques, along with the addition of nano-fillers, have proven to be the most effective modification methods. This paper presents a review of the modification processes and NF membrane performances for the removal of heavy metals from wastewater, as well as the application of these membranes for heavy metal ion wastewater treatment. Very high treatment efficiencies, such as 99.90%, have been achieved using membranes composed of polyvinyl amine (PVAM) and glutaraldehyde (GA) for Cr3+ removal from wastewater. However, nanofiltration membranes have certain drawbacks, such as fouling of the NF However, nanofiltration membranes have certain drawbacks, such as fouling of the NF membrane. Repeated cleaning of the membrane influences its lifetime. membrane. Repeated cleaning of the membrane influences its lifetime.

    Keywords: Membranes, Nanofiltration, Heavy metal, Removal, Wastewater}
  • Kh. R. Kalash *, M. H. Alfuraiji, A. R. Alazraqi

    Managing sewage has become increasingly important at both the national and international levels, largely due to uncertain future options for recovery and disposal. Due to this, it is necessary to develop innovative technology that can reduce pollutants such as surfactants to mitigate the problem at its source. Surfactants are the kind of pollutants that can pose health and environmental risks. This paper aims to study the efficiency of the removal of methylene blue active substances as an anionic surfactant (MBAS) and chemical oxygen demand (COD) from carpet cleaning wastewater using a thermophilic aerobic membrane reactor (TAMR). A laboratory-scale reactor was monitored daily for a month during this study. The removal efficiencies of MBAS and COD were 92 and 95 %, respectively. This study demonstrated that the TAMR process could resist high-stress situations (sudden load peaks) and withstand high surfactant concentrations, making it the ideal pretreatment option. For MBAS removal, the TAR and UF processes combined led to higher removal yields. MBAS was removed almost completely (>92 %) by the TAMR+UF procedure. Moreover, membrane cleaning operations and fouling problems are discussed.

    Keywords: Anionic surfactants, Wastewater, Thermophilic, Carpet cleaning wastewater, Methylene blue}
  • سمیه سبحانی، مرتضی اسفندیاری*

    فلزات سنگین به دلیل سمیت، زیست تخریب ناپذیری و تجمع زیست محیطی آلاینده های محیطی فوق العاده مضری هستند که می توانند بر افراد و محیط تاثیر بگذارند. پیل های سوختی میکروبی نوعی رویکرد بیوالکتروشیمیایی است که در آن گونه های باکتریایی، آلاینده های آلی و یون های فلزی را از فاضلاب مصنوعی و صنعتی حذف می کنند و به طور همزمان برق تولید می کنند. در حال حاضر کاربردهای واقعی این دستگاه ها در جهان به دلیل سطح پایین دانسیته تولیدی محدود هست . با بررسی های انجام شده در این مقاله در سال های اخیر از پیل سوختی میکروبی به عنوان یکی از راه های حذف فلزات سنگین از پساب صنایع مورد استفاده قرار گرفته است که میزان حذف 10 تا 100 درصدی برای فلزاتی مانند طلا، کروم، مس، سرب، کادمیوم، جیوه، روی، آرسنیک و نیکل دست یافتند. همچنین پارامترهای موثر بر میزان حذف در این بررسی ها مورد ارزیابی قرار گرفت که شرایط بهینه در اکثر موارد در محدوده pH خنثی و در بعضی موارد در 2=pH، در دمای 22 تا 35 درجه سانتی گراد و مقاومت خارجی 200 تا 1000 اهم می باشند.

    کلید واژگان: پیل سوختی میکروبی, حذف فلزات سنگین, پساب, انرژی}
    Somayeh Sobhani, Morteza Esfandyari *

    Heavy metals are extremely harmful environmental pollutants due to their toxicity, non-biodegradability and environmental accumulation that can affect people and the environment. Microbial fuel cells are a type of bioelectrochemical approach in which bacterial species remove organic pollutants and metal ions from synthetic and industrial wastewater and simultaneously generate electricity. Currently, the real applications of these devices in the world are limited due to the low level of production density. According to the investigations carried out in this article in recent years, microbial fuel cells have been used as one of the ways to remove heavy metals from industrial effluents, and 10 to 100% removal rates were achieved for metals such as gold, chromium, copper, lead, cadmium, mercury, zinc, arsenic and nickel. Also, the parameters affecting the amount of removal were evaluated in these studies, and the optimal conditions are in most cases in the range of neutral pH and in some cases in pH=2, at a temperature of 22 to 35 0C and an external resistance of 200 to 1000 ohms.

    Keywords: Microbial fuel cell, Removal of Heavy Metals, Wastewater, energy}
  • Reyhaneh Mokari, Mashaallah Rahmani *
    The objective of this work was to evaluate the efficiency of a promising ultrasonically assisted adsorption with the Fe3O4@THAM-CH2CH2Cl magnetic nanoparticle (MNPS) as a new adsorbent for the elimination of Congo red from water samples. The FE-SEM images show that Fe3O4@THAM-CH2CH2Cl MNPs adsorbent is spherical. Due to the presence of pores on the Fe3O4@THAM-CH2CH2Cl MNPs adsorbent surface, the proposed adsorbent can remove Congo red from the aqueous environment by trapping the pollutant in its pores. Different parameters influencing the ultrasonically assisted adsorption (UAA) by the Fe3O4@THAM-CH2CH2Cl MNPs adsorbent, including the dye concentration and adsorbent mass, ultrasonic time, and pH, were studied and optimized by multivariate methods. The best adsorption efficiency was obtained at 0.04 g of adsorbent, 17 mg.L-1 of dye, pH = 6.6, and ultrasonic treatment for 7.2 min. The results indicated that the efficiency of dye adsorption ranged from 97.85 to 99.65 %. The kinetic, isotherm, and thermodynamic for the proposed method were assayed. The larger R2 for the pseudo-second kinetic model indicates that this model is more suitable to describe the adsorption process of Congo red on the Fe3O4@THAM-CH2CH2Cl MNPs adsorbent. The Langmuir adsorption isotherm had a larger correlation coefficient (R2 = 0.9987), which indicates it fits best with the experimental data and is more suitable for the Congo red adsorption process. Analysis of actual samples showed that Congo red removal values (R %, mean ± standard deviation, n = 3) in tap water and wastewater were 98.48 ± 1.52 % and 98.05 ± 2.11 %, respectively.
    Keywords: Congo red, Fe3O4@THAM-CH2CH2Cl, Multivariate methods, Wastewater}
  • علی حسینیان نائینی، محمدرضا کلایی، امید مرادی، نیازمحمد محمودی

    در سال های اخیر، صنعت نساجی بیش از 50 درصد از پساب های رنگی در جهان را تولید کرده است. آب پاکیزه نقش مهمی در زندگی انسان ها ، موجودات آبزی و محصولات کشاورزی دارد . وجود مواد رنگزا در آبها به دلیل سمیتی که دارند باعث کیفیت نامطلوب ، به خطر انداختن سلامتی آنها شده و تغییراتی را در محیط زیست ایجاد می کند. روش های مختلفی جهت تصفیه پساب وجود دارد که براساس تحقیقاتی که انجام شده نشان می دهد که امروزه بیشتر از روش جذب سطحی برای تصفیه پساب به دلیل ارزان بودن، سادگی و مقرون به صرفه بودن استفاده می شود. در این مقاله بررسی حذف مواد رنگزا از پساب با استفاده از نانوکامپوزیت های مختلف انجام شده است که تاثیر جذب سطحی با نانوکامپوزیت ها براساس عوامل موثر بر جذب سطحی شامل زمان تماس، غلظت اولیه ، اثر دما وpH  محلول می باشند مورد بررسی قرار گرفتند. نانوکامپوزیتها تاثیر زیادی در حذف مواد رنگزا دارند و می توانند با کیفیت خوبی، تصفیه پساب را انجام دهند. در این پژوهش از نانوکامپوزیت های کربن فعال ، نانولوله های کربنی ، نانوذرات نقره ، فریت روی، ZnO،TiO2</sub> ، Fe3</sub>O4</sub> و نانوذرات آهن صفر ظرفیتی معمولا برای رنگبری پساب استفاده می شوند. در این مقاله نتایج نشان می دهد که نانوکامپوزیت های مختلف نوید بخش آینده ای امیدوار کننده برای تصفیه پساب رنگی می باشند. 

    کلید واژگان: حذف ماده رنگزا, نانوکامپوزیت ها, جذب سطحی, پساب}
    Ali Hosseinian Naeini, MohammadReza Kalaee, Omid Moradi, Niyaz Mohammad Mahmoodi

    In recent years, the textile industry has produced more than 50 % of the colored wastewater in the world. Clean water is essential in the lives of humans, aquatic organisms, and agricultural products. Due to their toxicity, dyestuff in water causes adverse quality, endangers their health, and causes environmental changes. There are different methods for wastewater treatment, which, based on the research, shows that today's surface absorption method is mainly used for wastewater treatment due to its cheapness, simplicity, and cost-effectiveness. In this article, the removal of dyestuff from wastewater was investigated using different nanocomposites, and the effect of adsorption with nanocomposites was investigated based on factors affecting adsorption, including contact time, initial concentration, the effect of temperature, and pH of the solution. Adsorbents significantly impact removing dyestuff and can perform wastewater treatment with good quality. This research used activated carbon nanocomposites, carbon nanotubes, silver nanoparticles, zinc ferrite, ZnO, TiO2</sub>, Fe3</sub>O4</sub> and zero-valent iron nanoparticles for wastewater decolorization. In this article, the results show that different nanocomposite adsorbents are promising. They are a promising future for the treatment of colored wastewater.  

    Keywords: Dye removal, Nanocomposites, Adsorption, Wastewater}
  • Zeynab Honarvar, MohammadReza Miroliaei *, Amir Sarrafi, Seyed Ahmad Ataei

    Oily sludge is one of the major oil pollutants that bioremediation is considered the most efficient way of treating and removing harmful hydrocarbons from these pollutants. In this study, the biodegradation of oil sludge from the Sirjan Gasoil storage reservoir in the slurry phase was investigated. In this research, the effect of sewage (wastewater) and surfactant and their interactions on biodegradation in the slurry phase has been investigated. The oil sludge was mixed with a 25% (w/v) combined ratio with different liquids and the slurry phase was applied for 21 days by incubator shaker at 130, 150, and 190 rpm. The temperature of the specimens was set in the appropriate range for the activity of degrading bacteria (30°C). Determination of the amount of hydrocarbons by dichloromethane extraction was carried out every week and an incremental removal of hydrocarbon was observed during this period. Among the samples, the highest removal of hydrocarbons was attributed to a rotational speed of 190 rpm with a removal rate of approximately 55%.

    Keywords: Bioremediation, Slurry phase, Oily sludge, Hydrocarbon, Wastewater, Tween 80}
  • MOHAMED EL AMINE EL AISSAOUI EL MELIANI *, MENG SUN, TAREQ W. M. AMEN, HOUCINE CHOUBANE, ABDELKADER IDDOU, BING LIU, MITSUHARU TERASHIMA
    The present work investigates the aeration pressurization effect by monitoring the airflow (Qg) variations during its injection at various diffuser arrangements in an activated sludge (AS) system and its impact on the overall energy-saving strategy. To this extent, a laboratory pilot-scale system (450 mm in length, 400 mm in width, and 470 mm high) was built to conduct the experiments with an effective volume of 84.6 L. To determine the optimum operating conditions, an experimental design combined with the grey method was used to establish the optimal tests to minimize the process’s energy footprint based on the pressurization effect due to various diffuser arrangements. Successful implementation of this operation confirmed that controlling the local diffuser densities (DDL) benefits the power consumption value by experiment ( ) savings and the mixing performances at a DDL = 0.0144. Undoubtedly, increasing the DDL improved the mixing performance of the AS and reduced the inhibition of the oxygen mass transfer coefficient by the mixed liquor suspended solids (MLSS). Furthermore, an empirical model was built to describe the nature of the power consumed accurately. The outcomes showed that the coefficient of determination was R² = 0.9856 with a significant corresponding probability (P-values) < 0.05. As a result, the multiple linear regression model (MLR), which means that the model’s reliability to predict the data revealed an R² > 80 %, confirmed that the model is reliable at a 95% confidence interval (CI).
    Keywords: Optimization, Wastewater, Modeling, Diffuser, Aeration}
  • Saeid Jabbarzare *
    A simple method was applied to construct Ni-doped CaTiO3 nano-powders from commercial CaCO3 and TiO2, characterized by XRD, FE-SEM, and FT-IR. The sample was composed of small grains with an average size of 78 nm. This method could be a useful, inexpensive, and efficient tool for the preparation of Ni-doped CaTiO3 nano-powders. The prepared sample was used for the removal of Cd2+ from water media. Results indicated that Cd2+ removal by Ni-doped CaTiO3 nano-powders was very efficient (100% removal yield) when the pH was adjusted to 4.5, the catalyst dosage amounted to 0.05 g, and the Cd2+ solution concentration was 60 mg.L-1. A pseudo-second-order kinetic model described the kinetics of Cd2+ removal.
    Keywords: CaTiO3 Nano-powders, Ni-Doped CaTiO3, Cd2+ Removal, Wastewater, adsorption experiment}
  • Behnaz Sarani, Mashaallah Rahmani *, AhmadReza Abbasian

    In this study, we present a new combustion method for the preparation of meso-adsorbent NiFe2O4 powders. SEM, XRD, and BET were used for the characterization of adsorbents. BET measurements confirmed a specific surface area (SSA) of 87.7 m2.g-1, a total pore volume (PV) of 0.2377 cm3.g-1, and a mean pore size (PS) of 10.841 nm. The mean crystallite diameter of the adsorbent using the Scherrer equation was 10 nm. Also, the response surface methodology and artificial neural network models were used for modeling, optimization, and prediction of responses for removing methyl violet from water and wastewater in lab-scale batches. To study absorption, a four-factor central composite design was used to select the best experimental condition for ultrasonic-assisted adsorption of methyl violet dye. The adjusted R2 of 0.9931 and the predicted R2 of 0.9813 are very close, indicating the compatibility of the experimental results with the quadratic model. According to the results, optimum conditions were set at an ultrasonic time of 231 s, 13.5 mg of adsorbent, a dye concentration of 2.0 mg.L-1, and a pH = 7.9. Also, the learning rule of Levenberg–Marquardt was used for ANN Modeling. According to the proposed ANN, the value of the root mean square error (RMSE) was 2.562, and the value of the correlation coefficient (R2) was 0.986. Also, removal efficiencies of 96.8% and 95.57% were obtained for the tap water and wastewater, respectively.

    Keywords: NiFe2O4 Meso-adsorbent, Ultrasonic assisted adsorption, Water, wastewater}
  • علی نورانی سنجبد، علی نعمت الله زاده*، ناصر سپهری جوان

    رنگ ها به دلیل تنوع و ساختار پیچیده کاربردهای فراوانی دارند. در سال های اخیر پساب ناشی از تولید یا مصرف رنگ ها در صنایع مختلف، افزایش یافته و تبدیل به خطری جدی برای محیط زیست و سلامتی انسان ها شده است. در این مقاله، تاثیر پلاسمای سرد به عنوان یک فناوری جدید و پیشرفته جهت تصفیه رنگ از پساب آورده شده است. از این روش می توان برای کاربردهای مختلف از جمله تصفیه و پیش تصفیه پساب ها، حذف رنگدانه ها و مواد شیمیایی خطرناک از پساب ها استفاده کرد. در این سامانه ی تصفیه پساب، مواردی مانند ویژگی های پساب و مواد تشکیل دهنده هدف، نوع تخلیه مناسب و راکتور پلاسمای به کار برده شده، آزمایش های سمیت و آزمایش های قابلیت تجزیه زیستی واسطه های تولید شده توسط پلاسما، ارزیابی سازگاری زیست محیطی فناوری های ترکیبی و برآورد اقتصادی مورد توجه قرار گرفته است. با توجه به مطالعات انجام شده، نتایج حاصل از این پژوهش بیانگر اثرات مثبت پلاسمای سرد بر رنگ زدایی از پساب و نیز افزایش کارآیی سامانه های نوین تصفیه پساب می باشد.

    کلید واژگان: پلاسمای سرد, تصفیه, پساب, رنگ, تخلیه سد دی الکتریک}
    Ali Noorani Sanjabad, Ali Nematollahzadeh *, Naser Sepehri Javan

    Dyes have many uses due to their variety and complex structure.In recent years, wastewater from the production or consumption of dyes in various industries have increased and become a serious threat to the environment and human health.The effect of cold plasma as a new and advanced technology for the treatment of dye from wastewater is presented in this review paper. This method can be used for various applications such as treatment and pre-treatment of effluents, removal of pigments, and hazardous chemicals from effluents.In this wastewater treatment system, different cases such as characteristics of effluent, target materials, type of suitable plasma discharge, reactor type, toxicity experiments, biodegradability tests of plasma generated intermediates, environmental compatibility assessment of combined technologies, and economic estimation were considered. According to the studies, the results indicated the positive effects of cold plasma for decolorization of wastewater and also increased efficiency of modern wastewater treatment systems.  

    Keywords: Cold plasma, treatment, Wastewater, Dye, Dielectric barrier discharge}
  • S. M. Etezad *, M. Sadeghi-Kiakhani

    Malachite green dye is widely used in food and textile industries for various purposes and also used as biocide in the aquaculture industry to control fungal attacks and protozoan infections. Surface and ground water is contaminated by dyes due to discharge of untreated wastewater from industries. The presence of malachite green in water causes serious health effects such as mutagenesis, respiratory toxicity and carcinogenesis. Therefore, removal of malachite green from water by using various techniques is an essential concern for living beings as well as environment. In this study, the ability of isolated bacteria (from oil contaminated soil) for biodegradation of MG dye was investigated. The bacterium was able to grow in temperature range of 25 to 45°C and pH range of 5 to 9. Optimum temperature and pH for bacterial growth were determined as 37 °C and 7, respectively. Effect of temperature, initial concentration of dye and shaking condition on decolorization of dye solution was also tested. 20 ppm MG dye was efficiently degraded by bacteria in less than 2 h, and biodegradation of MB dye followed first-order kinetics model. These properties make the bacteria suitable for industrial wastewater treatment.

    Keywords: Malachite Green, Decolorization, Wastewater, Biodegradation, Bacteria}
  • محمد خواجه مهریزی*، زهرا شاهی

    پساب های صنعتی حاوی یون های فلزی و ترکیبات رنگی می باشند که می توانند برای سلامتی انسان ها و حیوانات، مضر و موجب بیماری های جدی مانند سرطان، آسیب سیستم های عصبی، اندام ها و حتی مرگ شوند. بنابراین حذف این مواد  </strong>از آب وفاضلاب بسیارمهم می باشد. روش های مختلفی شامل ته نشینی، تبادل یون، الکترودیالیز و اسمز معکوس جهت حذف فلزات سنگین از فاضلاب ها استفاده می شود که این روش ها ناکارآمد و گران می باشند. از میان این روش ها، جذب، روشی موثر در تصفیه آب و رنگ بری پساب، به علت هزینه پایین، اجرای آسان تر، دوست دار محیط زیست، بازده بالا و مصرف کم انرژی می باشد.جاذب های مورد استفاده اغلب، مواد طبیعی اصلاح شده، ضایعات کشاورزی و برخی از میکروارگانیسم ها می باشند. در این مطالعه به معرفی برخی از جاذب های طبیعی و زیستی شامل باگاس نیشکر، پوست پیاز، جلبک و غیره پرداخته شده است.

    کلید واژگان: جذب, پساب, جاذب های طبیعی, ضایعات کشاورزی, جاذب های زیستی}
    Mohammad Khajeh Mehrizi*, Zahra Shahi

    Industrial wastewater have metal ions and colour compounds which can be harmful for human and animals and causing serious diseases such as cancer, damaging of nervous system, organ damage and even death. So, the removal of these materiales from waters and wastewaters is very important. Different methods have been used to remove heavy metals from wastewater such as precipitation, ion exchange, electrodialysis and reverse osmosis, that these methods are inefficient and expensive. Among these methods, adsorption is an efficient method for water treatment and wastewater decolorization, because of its low cost, easy operation, environmental friendly, high efficiency and low energy. The adsorbents used are mostly natural modified materials, agricultural waste and many micro-organism species. In this article, some of the natural adsorbents and biosorbents including bagasse, onion skin, algae, etc. have been introduced

    Keywords: Adsorption, Wastewater, Natural adsorbents, Agricultural waste, Biosorbents}
  • Hadis Shooshtary, Leila Hajiaghababaei *, Alireza Badiei, MohammadReza Ganjali, Ghodsi Mohammadi Ziarani

    The present work focuses on the synthesis and application of imine-modified silica-coated magnetic (IM-SCM) nanoparticles. The X-ray diffraction (XRD) tests indicated the presence of highly crystalline cubic spinel magnetite both before and after coating with the silica. The FTIR spectra also proved the successful surface coating and imine-modification of the Fe3O4 nanoparticles. Further investigations were performed to examine the capability of the modified IM-SCM nanoparticles for simultaneous removal of Ag+ and Cu2+ from the water samples. Atomic absorption spectrometry was used for ion determination. The best operating conditions for removing the target ions were a pH=5-9 and a stirring time=30 min. Only 20 mL of 3M nitric acid was used for stripping the ions using the IM-SCM nanoparticles. The resulting data were found to fit well with the Langmuir model, and the maximum capacity of the adsorbent was determined to be 270.3 (± 1.4) mg and 256.4 (± 0.9) mg of Ag+ and Cu2+ /g of IM-SCM, respectively. The adsorbent was successfully used for simultaneously removing the target ions from the wastewater samples.

    Keywords: Ag+, Cu2+, Imine-modified silica-coated magnetic nanoparticles, Removal, Wastewater}
  • فاطمه اوشنی، علی الله وردی *
    مواد رنگزا در تعدادی صنایع نظیر چاپ، نساجی، کاغذ، چرم و پلاستیک استفاده می گردند. مقدار زیادی از مواد رنگزا از صنایع به صورت پساب خارج می گردد. سمی بودن پساب مواد رنگزا زندگی انسان ها و موجودات زنده را تهدید می نماید. به طور کلی، پساب مواد رنگزا توسط روش های فیزیکی، شیمیایی و بیولوژیکی تصفیه می گردد. تصفیه فیزیکی به جداسازی غشایی، لخته کردن/انعقاد و جذب سطحی تقسیم می گردد. در طی فرایند رنگرزی از مقادیر متنابهی آب و مواد شیمیایی نظیر نمک های معدنی (NaCl, Na2SO4) استفاده می شود، که منجر به تولید مقدار زیادی پساب رنگی حاوی مقدار بالایی مواد آلی سمی و ترکیبات معدنی می شود. بنابراین، بازیابی مواد رنگزا و نمک از اهمیت زیادی برخوردار است. فرایندهای غشایی می تواند مواد رنگزا و ترکیبات معدنی را با راندمان بالا جداسازی نموده و آن ها را به فرایند رنگرزی بازگرداند، در حالی که در روش های دیگر، در پساب صنعتی ترکیبات شیمیایی به قدر کفایت مورد بازیابی قرار نمی گیرند. اگرچه، هر دو نوع غشا سرامیکی و پلیمری برای این منظور قابل استفاده می باشند، اما کاربرد غشاهای سرامیکی به دلایلی همچون مقاومت حرارتی و شیمیایی، استحکام مکانیکی، زمان عمر طولانی از جذابیت های بیشتری برخوردار است. برای حذف مواد رنگزا از غشا مرکب نانوفیلتراسیون (NF) که از چندین لایه هم جنس و یا غیر هم جنس تشکیل شده است، استفاده می گردد. غشای سرامیکی معمولا دارای پایه ماکروحفره، یک یا دو لایه حد واسط مزوحفره و لایه سطحی میکروحفره می باشد. پایه غشا با عملیات شکل دهی پودر و سپس استحکام یابی توسط پخت شکل می گیرد. روش هایی نظیر اکستروژن، ریخته گری نواری، ریخته گری دوغابی و پرس برای ساخت پایه غشا سرامیکی وجود دارد. فرایند سل-ژل روش مناسب برای تهیه لایه سطحی و حد واسط می باشد. برای جداسازی نمک از محلول مواد رنگزا به کمک NF نیاز به دفع بالای مواد رنگزا و دفع کم نمک از غشا می باشد. هدف از این مقاله، مروری بر روش های ساخت غشاهای سرامیکی و کاربرد آن ها در تصفیه پساب حاوی مواد رنگزا است.
    کلید واژگان: مواد رنگزای آلی, پساب, فرآیندهای غشایی, غشا سرامیکی}
    Fateme Oshani, Ali Allahverdi *
    Dyes are used in a number of industries such as printing, textile, paper, leather, and plastic manufacturing. Large amounts of dyes are discharged from industries as wastewater. The toxicity of dye effluents threatens human beings and other living organisms. In general, dye containing wastewaters are treated by a number of different physical, chemical, and biological methods. Physical treatments are classified into membrane separation, conventional coagulation/flocculation and adsorption. In various industries, water and chemicals including inorganic salts (NaCl, Na2SO4) are used in dying process that generate large volumes of strongly colored wastewaters with high load of toxic organic and inorganic compounds. Therefore, the recovery of dye and salt from industrial wastewater has a great significance. Membrane processes can separate and recycle both dyes and inorganic salts with considerably high efficiencies, while in other techniques; primary resources are not sufficiently recycled from industrial wastewater. Ceramic membranes are comparable to polymer membranes based on their characteristics such as easy control of the pore size, higher durability, thermal and chemical resistance, mechanical strength, extended lifetime. Nanofilteration (NF) is applied to remove dyes that are usually in the form of composites and composed of one or more several layers with different ceramic materials. Ceramic membranes generally have a macroporous support, one or two mesoporous intermediate layers and a microporous top layer. Ceramic supports are formed by shaping a powder and then consolidating by sintering. There exist a number of methods for fabrication of ceramic supports such as extrusion, tape casting, slip casting and press. The sol-gel process is the most appropriate methods for the preparation of intermediate and top layer. The process of separating salt from dye solution by NF needs a high dye rejection and a low salt rejection. The purpose of this paper is to review the fabrication techniques of ceramic membranes and their applications in treatment of dye-containing wastewaters.
    Keywords: Dye, Wastewater, Membrane process, Ceramic membrane}
  • فضه آریانسب *، شهلا مظفری، سیده فرناز هادی
    پلی ساکاریدهای طبیعی مواد دوست دار محیط زیست هستند که برای جداسازی آلاینده ها از محلول های آبی استفاده می شوند و بسیار مورد توجه قرار گرفته اند. در این میان، نشاسته ماده اولیه طبیعی فراوان، ارزان، تجدیدپذیر و کاملا زیست تخریب پذیر است که به دلیل ظرفیت جذب پایین و پایداری کم، کاربرد آن در جداسازی مواد رنگزا محدود است. برای حل این مشکلات، نشاسته های اصلاح شده سنتز گردیده و به عنوان جاذب برای جذب مواد رنگزای آنیونی استفاده شده اند. در این تحقیق نشان داده شد که نانوذرات مغناطیسی اکسید آهن پوشیده با نشاسته عامل دار شده با دی تیوکاربامات (DTCS-MNPs) می تواند به عنوان جاذبی موثر، برای جداسازی مواد رنگزای آنیونی از محلول های آبی استفاده شود. همچنین نشان داده شده است که ظرفیت جذب DTCS-MNPs برای مواد رنگزای مورد بررسی به pH محلول وابسته بوده و جذب به صورت الکترواستاتیکی است. نتایج مطالعات واجذب نشان داده است که درصد واجذب مواد رنگزا از جاذب در محلول mol/l 0.25 Na2SO3 و در دمای oC 25 به میزان 80% است.
    کلید واژگان: نانوذرات مغناطیسی, نشاسته عامل دار شده با دی تیوکاربامات, جذب سطحی ماده رنگزا, پساب}
    F. Aryanasab *, Sh. Mozaffari, F. Hadi
    Natural polysaccharides are environmentally friendly materials for removing toxic pollutants from aqueous solutions, and attracted much attention. Among numerous polysaccharides, starch is an abundant, inexpensive, renewable and fully biodegradable natural raw material. However, its application in dyes removal is limited due to its low capacity and stability. To circumvent these problems, modified starches has been synthesized and applied as adsorbent for anionic dyes. We showed that the Fe3O4 magnetic nanoparticles coated with dithiocarbamate-modified starch (DTCS-MNPs) is an efficient adsorbent for the removal of water-soluble anionic dyes from wastewaters. It is found that the capacity of DTCS-MNPs for each dye is pH dependent, and the adsorption is governed by electrostatic attractions. The desorption data shows that the removal percent of dye from the dye loaded DTCS-MNP is over 80% in 0,25 mol/l Na2SO4 solutions at 25 ºC.
    Keywords: Magnetic nanopaticles, Dithiocarbamate-modified starch, Dye adsorption, Wastewater}
نکته
  • نتایج بر اساس تاریخ انتشار مرتب شده‌اند.
  • کلیدواژه مورد نظر شما تنها در فیلد کلیدواژگان مقالات جستجو شده‌است. به منظور حذف نتایج غیر مرتبط، جستجو تنها در مقالات مجلاتی انجام شده که با مجله ماخذ هم موضوع هستند.
  • در صورتی که می‌خواهید جستجو را در همه موضوعات و با شرایط دیگر تکرار کنید به صفحه جستجوی پیشرفته مجلات مراجعه کنید.
درخواست پشتیبانی - گزارش اشکال