جستجوی مقالات مرتبط با کلیدواژه "پلی آلومینیوم کلراید" در نشریات گروه "مهندسی آب"

One of the important steps in the process of removing water turbidity is the use of coagulants. Amongst the most applied materials is poly aluminum chloride (PAC) which is used to precipitate colloidal particles. The use of this compound, which contains Aluminum, in the coagulation causes some residual aluminum in the water. Natural and synthetic coagulants aid can be used to reduce the effects of overuse of poly aluminum chloride. In this study, the effect of bentonite and polyelectrolyte coagulant aid in the turbidity removal process of Babasheikhali water treatment plant is investigated. The results showed that optimum pH for turbidity removal was 8 and the optimal concentration of poly aluminum chloride at the optimum pH was 10 mg/L. In the presence of bentonite, the optimal PAC concentration decreased to 4mg/L and the turbidity removal efficiency increased to 92%. The results also showed that the combination of PAC and polyelectrolyte together can be used to reduce the concentration of heavy metals in the incoming water. Therefore, bentonite and polyelectrolyte coagulants aid can be used as a suitable option along with poly aluminum chloride to remove turbidity from the water treatment plant.

Conventional water treatment processes include screening, coagulation, flocculation, sedimentation, filtration and disinfection. Many coagulants are widely used in conventional water treatment processes. These materials can be classified into inorganic and organic coagulants. Many researches on natural coagulants were carried out in recent years. This study evaluates Tragacanth as natural coagulants aids with poly aluminum chloride (PAC) for the removal of turbidity and coliform bacteria from water Karoon River. Tragacanth is a gum that extracted from astragalus. According to results of this study, adding tragacanth as a coagulant aid improved performance of the process and experimental observations showed that by applying tragacanth as coagulant aid in optimal conditions, larger flocks are formed compared to PAC applications and the sedimentation rate was higher. In total, this study showed that dose of 0.06 mg/l of tragacanth as a coagulants aid with 15 mg/l of PAC coagulant in high turbidity (480-500 NTU) has the best performance in reducing turbidity and total coliform.

The effluent from the active sludge treatment plant of Qom Shokoohiyeh industrial flows into surface water and reuse of water in industrial process is necessary. The aim of this study was to investigate the efficiency of aluminum sulfate, chlorofluorocarbons and poly aluminum chloride in removing turbidity and other parameters in industrial wastewater before entering RO in Shokoohiyeh Qom industrial refinery. This study was applied in a laboratory scale using a jar-test and experiments based on varying concentrations of coagulants (200, 400, 700, 800, 1000, 1200 mg/L) and pH=2.4.6.7.8.10 has been done. Steady mixing, slow mixing and stagnation have been performed and factors such as turbidity, pH, COD, BOD5, EC, SVI and TSS have been investigated. Coagulants are effective in removing turbidity. The highest removal rate was for polyvinyl chloride (95%) and the least amount of turbidity removal was in chlorofacry (50%). The highest and lowest levels of pH were detected at pH=2 (72%) and pH=8 (10%), respectively. The lowest BOD5 removal efficiency in poly aluminum chloride was 88% at pH=4 and the highest removal rate of BOD5 was found in chloroformate coagulant with pH=4 (96%). The highest COD reduction was observed in poly aluminum chloride at pH=9 (89%) and the lowest COD reduction was observed at a concentration of 800 mg/L alum with 34%. The highest reduction in electric conductivity in poly aluminum chloride with 87% and the lowest amount of electrical conductivity reduction occurred at a concentration of 500 mg per liter of alum with 12%. The highest total removal of suspended solids in chlorofacrylic coagulant was 88% and the lowest amount was removed in chloroform with up to 18%. The maximum amount of sludge deposited at  pH=9 (240 mg/L) in aluminum chloride and the lowest amount of sludge deposited at pH=2 (5 mg/L). The use of coagulant materials can increase the purification efficiency, eliminate opacity and return water to the cycle. PAC and Alum coagulant have high efficiency in removing turbidity and other wastewater treatment parameters that can be used to treat wastewater for RO systems.

In this paper, the response surface methodology and the central composite design are used to model and optimize bromide removal efficiency in the coagulation process. Bromide ions are naturally found in surface waters. Despite its non-toxicity, when exposed to disinfectants commonly used in water treatment, bromide ions produce disinfection byproducts which are more carcinogenic than their chlorinated counterparts. A key process in water treatment is coagulation. Most studies have recently focused on enhanced coagulation achieved by new coagulants known as inorganic polymer coagulants which exhibit a remarkable ability in both removing colloidal particles and reducing turbidity and the zeta potential from water. In the present experiments, poly-aluminum chloride (PAC) is used as a coagulant. Moreover, an experimental design is constructed using the Design-Expert software to develop an efficient model with a regression coefficient of 0.9925 which fitted the observed data on bromide removal efficiency. It is found that coagulant dosage and initial bromide concentration have direct impacts on bromide removal efficiency while a different behavior is observed in the case of pH.

In recent years, poly aluminum chloride has been replaced as an efficient coagulant for other coagulating material. Despite the diversity in the formulations of this family of coagulants, it is necessary to develop a comprehensive national standrad for the qualitative analysis and determination method for these materials. The presents study aims to investigate the standard approach adopted in China as a major supplier of these coagulants. For this purpose, literature review, scientific findings, and test-based comparisons are exploited for the assessment of these materials and for developing relevant recommendations.In the course of these investigations, the effect of pH, heating procedure, elimination of impurities, and identification of proper reagents will be described.

Given the increasing importance of surface water bodies as supply sources of drinking water and regarding the requirement for using different chemicals at various stages of water treatment processes, it is essential to investigate coagulant consumption in water treatment plants. Determination of the required dosage of coagulants used in the coagulation and flocculation unit is one of the most important decisions in water treatment operations. For this purpose, the jar test is generally used to determine the type and concentration of suitable coagulants in a water treatment plant. However, the test is rather time-consuming and unreliable due to the inaccurate results it yields. Instead, intelligent methods can be employed to overcome this shortcoming of the jar test. In this study, experimental data were collected over the period from 2011 to 2012 and further refined for study. Two non-linear models based on adaptive neuro-fuzzy inference system (ANFIS) and GMDH-type neural networks were then developed and experimental results were used to determine the optimum poly-aluminium chloride dosage for use at Guilan water treatment plant. The effects of input parameters including temperature, pH, turbidity, suspended solids, electrical conductivity, and color were investigated on coagulant dosage. The ANFIS model was found to outperform the GMDH model in predicting the required poly-aluminium chloride dosage.

Chitosan، is a biodegradable cationic polymer، which is derived from deacetylation of chitin. The present study was conducted to investigate the effect of chitosan as a coagulant aids in improving the performance of coagulant property of poly-aluminum chloride as a primary coagulant on the removal of turbidity from water. This study، was performed in a laboratory scale and using jar test apparatus in Ahwaz Water Treatment Plant. Experiments were performed with different concentrations of coagulants، pH and different concentrations of chitosan as a coagulant aids. First the samples mixed under rapid mixing condition (120rpm) for 1minute and then the apparatus set to slow mixing (40rpm) for 20 minute. After mixing the samples left for 30 minute in order to settle the sediments. The optimum pH was found 8 in this study. The optimum doses of poly-aluminum chloride in conjunction with chitosan، were 5mg/L and 0. 02 mg/L، respectively. The required dosage of poly-aluminum chloride as a primary coagulant be reduced upto 50% under optimum condition with chitosan. It was also found using chitosan also produced larger floc with higher settling velocity than primary coagulant alone. The results also showed that chitosan as a coagulant aid had a positive effect on turbidity removal.

Coagulation is one of the important processes in water treatment plants. The experts attempt to find out both low cost and high efficient coagulant in water treatment plants. The coagulants which are widely used in coagulation process, are inorganic salts, specially Iron and Aluminum salts.. Aluminum Sulfate and Ferric Chloride are two coagulants which are used in many water treatment plants in Iran. Recently there is a tendency to use a new coagulant which is called Ploy Aluminum Chloride (PAC) which are used in many other countries such as Canada, America, China and England. The purpose of this study was comparison of PAC, Alum and Ferric Chloride removal of TOC and Total coliforms as indicators of chemical and biological pollution of water and to find out optimum concentrations for turbidity removal of raw water of Esfahan water treatment plant.In this study 20 samples of raw water were taken during 4 months from Esfahan water treatment plant. At first, the amounts of total coliforms and TOC was measured. Then the optimum coagulant dosage for turbidity removal was obtained using jar test apparatus Final TOC and total coliform concentrations were measured after jar test study.The results of this study show that Ferric Chloride and PAC in removal of turbidity, total coliforms and TOC are more efficient than Alum. It was also found Ferric Cholide in removal of TOC is better than PAC. Due to Ferric Chloride disadvantages, the PAC coagulant is recommended as a good alternative for Alum in coagulation process.

In this research, reduction of color, turbidity and COD in sulfite pulp mill effluent due to using various dosages of coagulants (alum, ferric chloride and poly aluminum chloride) as single and dual have been investigated. Results of investigation illustrate that combination of above mentioned coagulants sometimes improve the coagulation and flocculation operation in wastewater treatment plant. But respect to cost of coagulants and chemical treatment system in similar conditions, using combined coagulants for taking equal results often increases the costs and complexity of chemical effluent treatment.