جستجوی مقالات مرتبط با کلیدواژه « Converter sludge » در نشریات گروه « آب و خاک »

Lead (Pb) is of great concern in environment because of its toxicity to animals and humans. Lead is a cumulative toxin and known carcinogen. Although, plants do not require Pb for growth, the bioaccumulation index of Pb in plants exceeds that of most other trace elements. It is therefore important to control Pb concentration in plants, especially in the edible parts of crops to ensure food safety. There are many factors that control Pb accumulation and availability to plants in agricultural soils such as Pb source, Pb loading rate, soil pH, soil cation change capacity (CEC), chloride concentration in soil solution and soil organic matter content. These are important factors that should be considered for evaluating Pb phyto-availability. In addition, element interactions can also affect the elements uptake. Thus, this study was performed to investigate the effect of converter sludge-enriched cow manure on the changes in corn Pb uptake in a Pb-polluted soil under greenhouse condition.
This pot experiment was conducted under greenhouse condition around the city of Arak, using a Fine loamy, mixed and thermic, Typic Haplargids soil. A factorial experiment with a randomized complete block design with 24 treatments in three replications was carried out. The treatments consisted of applying enriched cow manure (0, 15 and 30 t ha-1) with 0% and 5% pure Fe from converter. To investigate the effect of converter sludge-enriched cow manure on the changes in corn Pb uptake, a non-saline soil with low carbon percentage was selected. The soil was polluted with Pb from Pb(NO3)2 source at the concentrations of 0, 200, 300 and 400 mg Pb kg-1 soil and incubated for one month. Cow manure was produced in a local farm and aged for two years before the experiment. The cow manure was enriched with converter sludge and incubated for three months in room temperature. Then, the enriched cow manure was added to the Pb polluted soil and corn (Zea mays L. single grass 704) seeds were sown. After 60 days from the experiment, soil physio-chemical properties and soil and plant Pb concentration were measured.
The greatest and least DTPA-extractable-Pb were determined in the polluted soil (400 mg Pb) without applying cow manure and the polluted soil (200 mg Pb) treated with 30 t ha-1 enriched cow manure, respectively. The DTPA-extractable-Pb in uncontaminated soils was not detectable by atomic absorption spectroscopy (AAS). Increasing the amount of cow manure caused a significant reduction in DTPA-extractable-Pb as applying 15 and 30 t ha-1 cow manure in a polluted soil (300 mg Pb) resulted in a significant decrease in DTPA-extractable-Pb by 11.9 and 23.4 units, respectively. This can be accounted for by the role of organic and inorganic fractions of cow manure in decreasing soil Pb availability. Interactions between Fe and Pb appear to influence the soil Pb availability as application of 15 and 30 t ha-1 converter sludge-enriched cow manure in 300 mg Pb-polluted soil caused a significant decline in soil Pb availability by 10.4 and 9.3 units, respectively. The highest and least root Pb concentration were observed in the polluted soil (400 mg Pb) without applying cow manure and the polluted soil (200 mg Pb) treated with 30 t ha-1 enriched cow manure, respectively. The corn root Pb concentration in unpolluted soils was not detectable by AAS. Applying 5% (W/W) pure Fe from converter sludge in the polluted soil (300 and 400 mg Pb) which were not manured significantly decreased the root Pb concentration by 19 and 9 units, respectively which is explainable by the interaction existing between Pb and Fe in soil. Furthermore, root Pb concentration was affected by converter sludge enriched-cow manure as applying 15 and 30 t ha-1 converter sludge cow manure in a polluted soil (400 mg Pb) significantly decreased the root Pb concentration by 20.8 and 10.9 units, respectively. However, the role of cow manure in increasing pH and decreasing root Pb concentration cannot be ignored. The greatest and least shoot Pb concentration was obtained for the polluted soil (400 mg Pb) without applying cow manure and the polluted soil (200 mg Pb) treated with 30 t ha-1 enriched cow manure, respectively. The corn shoot Pb concentration in unpolluted soils was not detectable by atomic absorption spectroscopy (AAS). Interaction effects were also observed for shoot Pb concentration as using 5% (W/W) pure Fe from converter sludge in the polluted soil (300 and 400 mg Pb) which were not treated by cow manure significantly decreased the shoot Pb concentration by 4.1 and 4.7 units, respectively.
The results of this study showed that interactions between Pb and Fe seem to play an important role in reducing root and shoot Pb concentration. On the other hand, applying cow manure can increase the soil sorption properties such as CEC and decrease the soil Pb availability and plant Pb uptake which is explainable by the fact that the organic and inorganic fractions of manure impact the Pb availability. However, the influences of soil physico-chemical properties such as pH upon soil Pb availability should be taken into account.

Nowadays, different materials such as applying Fe chelates, soil acidifying materials and industrial wastes are used to correct soil Fe deficiency. Slag and convertor sludge of steel factories are useful as a reclamation material for Fe nutrition among the industrials wastes for this purpose. These materials contain considerable amount of Fe produced in large quantities every year. Application of slag and convertor sludge to soil may affect bioavailability and chemical forms of Fe in soil. On the other hand, environmental pollution caused by heavy metals such as lead (Pb) is a serious and growing problem and can affect nutrient management such as Fe. Considering interaction of Fe and Pb, this research was performed to investigate the effect of converter sludge enriched cow manure on the changes in Fe bio-availability in a Pb polluted soil.
A factorial experiment with a randomized complete block design with 3 factors in three replications was conducted in greenhouse conditions. Treatments were consisting of applying enriched cow manure (0, 15 and 30 t ha-1) with 0 and 5% pure Fe from converter sludge. In addition, the soil was polluted with Pb from Pb(NO3)2 source at the rates of 0, 200, 300 and 400 mg Pb kg-1 soil and incubated for one month. Then, the enriched cow manure was added to the Pb polluted soil and corn (Zea mays L. single grass 704) seeds were sown. After 60 days from the experiment, soil physio-chemical properties and soil and plant Fe concentration were measured.
Increasing the loading rate of cow manure from 0 to 15 and 30 t ha-1 in a Pb polluted soil (300 mg Pb soil-1) caused an increasing in DTPA extractable-Fe by 21 and 35 times, respectively. Similar to this result, root and shoot Fe concentration was also increased, as, applying 30 t ha-1 cow manure in a polluted soil (200 mg Pb soil-1) caused an increasing in root and shoot Fe concentration by 7 and 12.3 times, respectively. Enriched cow manure with converter sludge had also a positive effect on root and shoot Fe concentration, as, applying 30 t ha-1 enriched cow manure in a Pb polluted soil (200 mg Pb soil-1) caused an increasing in root and shoot Fe concentration by 2 and 7.7 times, respectively.
The greatest DTPA extractable Fe and root and shoot Fe concentration was belong to the non- polluted soil treated with 30 t ha-1 cow manure enriched with 5% Fe pure from converter sludge. Considering the interaction effect of Fe and Pb, increasing the soil Pb pollution caused the significant decreasing in soil Fe availability and root and shoot Fe concentration. The result of this study showed that applying cow manure enriched with 5% Fe pure from converter sludge can probably increase soil and plant Fe bio-availability. However, the role of applying cow manure on decreasing Pb bio-availability and thereby, increasing soil Fe bio-availability (iron and lead competitive effect) cannot be ignored.

Mulching is one of the most common ways to soil stabilization, prevent wind erosion and control dusts. Some types of mulches is not economically practical choices, thus use of inexpensive and safe industrial wastes in the mulch compositions have both economically and environmentally importance(waste recycling). Therefore, a key objective of this research is use two types of industrial waste for preparation of mulch. Since Proctor method has been considered to test and compare the strength of mulches, so another purpose of this research is simplification of Proctor method to estimate the strength of soil stabilizer mulches under the influence of wind erosion.
Based on the results of previous studies and pre-treatments, some mulches were tested. These mulches were non-living composed of different percentages of stone powder, converter sludge, clay soil, and sandy soil. Instron device was used to measure the compressive strength of the mulch. Considering applying of the Proctor method for working with Instron device, simplification of the procedure was also performed. These two methods were called as “Proctor” and “simplified Proctor” methods, whose results were compared as the criterion for utilizing the simplified method. The treatments included five types of mulch in three replications, where their compressive strength was measured by the two methods of “Proctor” and “simplified Proctor” and were compared by the random factorial designs.
Reducing the clay percentage from 80 to 50 and increasing the percentage of sand from 20 to 50 in the treatments containing clay and sand in both methods resulted in compressive strength reduction of mulches. Increasing the percentage of the stone powder from 5 to 25 and simultaneous reduction of clay percentage from 85 to 65 together with constant percentage of converter sludge led to decreased compressive strength through the simplified Proctor method. The differences between the results of the two Proctor and simplified Proctor methods were not significant, but the simplified Proctor method had specific order in the results.
Compressive strength reduction with reduced clay percentage and increased stone powder percentage was showed in the comparison of the treatments containing clay and stone powder through the simplified Proctor method. However, the results of the Proctor method lacked a logical order. The comparison of the treatments containing clay and sand indicated that in both methods, as the clay decreases and the sand increases, compressive strength reduced. Compressive strength test results using Instron device was compared in both simplified Proctor and Proctor methods, therefore it was showed that these two methods do not have a significant statistic difference, although orderly changes of the simplified Proctor method results was found. Considering the simplicity and time reduction in the simplified Proctor method, this method is recommended for mulch comparisons in wind erosion.

Many researchers have reported positive effects of converter sludge and slag, two by-products in Isfahan iron melting factory. In this work, the optimum rate of application and the availability of some essential elements (for plant growth) in the converter sludge and slag for corn were investigated. The converter sludge contains about 64% Fe ІІ and ІІІ oxides and some other essential elements for plant growth. The slag also contains 17% iron oxides, 52.8% calcium oxide as well as considerable amounts of some other elements. Treatments included a control, Fe-EDTA foliar spray with 5 in 1000 concentration, application of sludge in 4 levels (L1, L2, L3 and L4 equal to 5.83, 13.33, 20.83 and 26.67 ton/ha, respectively) and application of slag in 4 levels (S1, S2, S3 and S4 equal to 3.20, 7.28, 11.36 and 15.44 ton/ha, respectively) which supply 1, 2, 3 and 4 times as much as soil test recommends, based on AB-DTPA extractable Fe in the soil. Corn (Zea mays) single cross 704 was planted for the experiment. Applications of the two compounds increased the soil extractable Fe and Mn, decreased Mg but the treatment did not change the soil-extractable Zn, Cu and Ca. The corn yield also increased due to the applications of the two compounds and the maximum yield was related to L3, L4, S3 and S4 treatments. The foliar application treated the leaf chlorosis and increased the silage, grain and leaf + stalk yields however, this was not as efficient as sludge and slag application. Also applications of the two compounds increased the Fe, Mn, Zn, Cu, Ca and Mg uptake by corn. The L3 and S3 treatments can be recommended as the proper levels of these compounds as iron fertilizer.

Application of slag and converter sludge, major by-products of Esfahan Zob Ahan factory, to enrich two organic amendments for corn nutrition, was investigated. Farm manure and its vermicompost mixed with different rates of slag and sludge were incubated in 3 Kg pots at field capacity moisture and home temperature for three months. The applied rates of slag and sludge were 0, 5 and 10 percent (w/w) of pure iron from these compounds to the organic amendments. Iron sulfate with the above ratios was also examined for comparison. Sub-samples of the incubated materials were taken after 0, 10, 25, 45, 65 and 90 days of incubation and examined for DTPA extractable Fe, Mn, Zn and Cu. After the incubation, the enriched amendments were applied to a soil sample to grow corn. Three Kg soil samples, taken from Chah Anari experimental farm, Esfahan University of Technology, were mixed with 17 gr of the amendments (50 ton/ha) placed in 3 Kg pots. In each pot two corn seeds (single cross 704) were planted and after 70 days crop yield and concentration of Fe, Mn, Zn, Cu in the plant tissues were determined. Results showed that the use of iron sulfate strongly increased DTPA extractable Fe and Mn of the amendments. In enrichment by converter sludge, the best result was obtained in the mixture of 10 percent pure iron with the vermicompost on 60 days of incubation. Treatment of 5 percent pure iron from slag mixed with the manure increased DTPA extractable Fe and Mn with the time, but the 10 percent treatment was not much effective in this regard. The highest rates of iron uptake by the plants occurred in the iron sulfate and 10 percent converter sludge treatments, respectively however, the highest rate of the plant Mn uptake was observed in 5 percent iron from converter sludge mixed with vermicompost. In general, 10 percent pure iron from converter sludge was the most effective enrichment treatment, increasing the plant uptake of Fe, Mn, Zn and Cu micronutrients.