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عضویت

جستجوی مقالات مرتبط با کلیدواژه « heavy metal » در نشریات گروه « پزشکی »

  • Nasrin Hassanzadeh *, Faezeh Jafari, Fariba Hedayatzadeh
    Background

    This study aimed to investigate the concentration of potentially toxic elements (PTEs) including iron (Fe), zinc (Zn), copper (Cu), cadmium (Cd) and lead (Pb) and determine their health risks, and evaluate the water quality of Abbas-Abad, Khako, Moradbeig Valley rivers and Ekbatan Dam inlets and bodies located in Hamadan, Iran.

    Methods

    In spring 2019, the concentrations of PTEs in water samples collected from 61 stations were quantified using an inductively coupled plasma optical emission spectrometry device. Water quality was evaluated using heavy metal pollution index (HPI), heavy metal evaluation index (HEI), contamination degree , heavy metal toxicity load (HMTL), and environmental water quality index (EWQI) indices. Carcinogenic and non-carcinogenic risks were calculated usingcancer risk (CR) and hazard index (HI), respectively.

    Results

    It was found that the average concentration of Fe and Zn had a statistically significant difference (P < 0.05). By comparing the metal concentration to the World Health Organization’s standard, the concentrations of all elements were below the permissible limit, except for Fe and Cd, in 4 and 5 sampling stations. The quality of water sources revealed a low level of PTE contamination in the studied surface water. According to the HI results, there was no apparent threat to the residents’ health. Based on the CR assessment results, the dermal absorption of PTEs for both age groups was classified as low-risk. However, ingestion of these elements was categorized as high-risk.

    Conclusion

    Since Hamdan’s surface water sources are contaminated with PTEs, it is necessary to investigate effective management strategies for preserving the integrity and health of water resources.

    Keywords: Potentially Toxic Elements, Pollution, Heavy Metal, Water Quality, Hazard, Cancer Risk}
  • یوسف دادبان شهامت، زهره مقیسه*، غلامرضا جمالی اترگله، مینا قهرچی
    هدف

    آلوده شدن آب های زیرزمینی تاثیرات عمده ای بر سلامت انسان ها، فعالیت صنایع، کشاورزی و محیط زیست دارد. مطالعه حاضر با هدف تعیین غلظت فلزات سرب، کادمیوم، آرسنیک، کروم و نیکل در آب های زیرزمینی اطراف محل دفن شهرستان جویبار و مقایسه آن ها با استانداردهای موجود جهت مصارف شرب انجام شد.

    مواد و روش ها

    در این مطالعه توصیفی- تحلیلی، نمونه برداری از 4 حلقه چاه در طی سه ماه متوالی به تعداد 12 نمونه انجام شد. غلظت عناصر سنگین با استفاده از تکنیک جذب اتمی با کوره گرافیتی (GFAA) بر اساس روش های استاندارد آب و فاضلاب اندازه گیری شد. علاوه بر این، پارامترهای سختی، دما، pH و کل جامدات محلول (TDS) با دستگاه های پرتابل نیز مورد سنجش قرار گرفت.

    یافته ها

    بررسی ها نشان داد که میانگین غلظت نیکل، سرب، کروم و کادمیوم در آب چاه ها به ترتیب 0425/0، 0071/0، 0268/0 و 0117/0 میلی گرم در لیتر بوده است. در هیچ نمونه ای آرسنیک مشاهده نشده است. میانگین دما، سختی، pH و TDS در محدوده به ترتیب  C20-21، mg/L 33/136-66/108، 36/3-7/7 و mg/L  33/712-25/566 سنجش شد. علاوه بر این، ضریب همبستگی نشان داد که رابطه همبستگی مثبتی بین فلزات نیکل، کروم، سرب، کادمیوم و پارامترهای دما، سختی، pH و TDS و همچنین با یک دیگر در سطح اطمینان 01/0=ɑ وجود داشت.

    نتیجه گیری

    بر اساس نتایج آب چاه های موجود از لحاظ مقدار فلزات آرسنیک، سرب، کروم و pH و سختی منابع قابل قبولی جهت مصارف شرب هستند اما مقدار فلزات کادمیوم و نیکل و TDS از حد استاندارد بالاتر است.

    کلید واژگان: فلز سنگین, منابع آبی, شهر جویبار, شیرابه, استاندارد}
    Yosof Dadban Shahamat, Zohreh Moghiseh*, Gholamreza Jamali Atargole, Mina Gharchi
    Introduction

    Groundwater contamination has major effects on human health, industrial activity, agriculture, and the environment. The present study determined the concentration of lead, cadmium, arsenic, chromium, and nickel metals in the groundwater around the landfill in Juybar City and compared them with the drinking water standards.

    Materials and Methods

    In this descriptive-analytical study, 12 samples were sampled from four wells for three consecutive months. The concentration of heavy elements was measured using the graphite furnace atomic absorption technique (GFAA) based on standard water and wastewater methods. Also, the hardness, temperature, pH, and total dissolved solids (TDS) parameters were measured with portable devices.

    Results

    Investigations showed that the average concentration of nickel, lead, chromium, and cadmium in well water was 0.0425, 0.0071, 0.0268, and 0.0117 mg/l, respectively. The average concentration of arsenic was not observed in any sample. The average temperature, hardness, pH, and TDS were measured in the range of 20-21°C, 108.66-136.33 mg/L, 7.3-7.36, and 566.25-712.33 mg/L. Also, the correlation coefficient showed a positive correlation between the metals nickel, chromium, lead, and cadmium and the parameters of temperature, hardness, pH, and TDS, as well as with each other at a confidence level of 0.01.

    Conclusion

    The amount of arsenic, lead, chromium, pH, and hardness are acceptable in the investigated wells for drinking purposes, but the amount of cadmium, nickel, and TDS is higher than the standard.

    Keywords: Heavy Metal, Water Resources, Juybar City, Water Pollutants, Standard}
  • Determining the Amount of Lead Heavy Metal in Glycyrrhiza glabra (Licorice) and Foeniculum vulgare (Fennel) Medicinal Plants
    Ghobad Abangah, Mohadeseh Pirhadi, Behnaz Shojaei, Mohamadreza Nazer*, Abas Ghaysouri

    Medicinal plants and herbal medicines are usually safer than chemical medicines, but their arbitrary use may be associated with side effects. Some people think that medicinal plants and medicines that have a plant base cannot cause health problems and are not harmful, while medicinal plants and herbal medicines, like any chemical medicine, have their own side effects. The food chain, including edible and medicinal plants, can be one of the important sources of heavy metals transfer to the human body and endanger human health. The aim of this study is to determine the amount of lead heavy metal in licorice and fennel medicinal plants using furnace atomic absorption spectrometry. The results of this study showed that the average heavy metal concentration of lead in licorice and fennel was 21.63 ppb and 23.45 ppb, respectively. The results obtained in this study are higher than the limit set by WHO. Based on the results, consumption of licorice and fennel medicinal plants has dangerous health consequences for consumers, especially children and pregnant women. Heavy metals enter the body by consuming food such as medicinal plants, contaminated water and other sources and can lead to toxic effects in different organs. Considering the potential risk of heavy metal contamination for public health and their carcinogenic effects, obtaining information regarding the concentration of heavy metals in medicinal plants can be helpful.

    Keywords: Heavy Metal, Toxic, Carcinogenic, Medicinal Plant, Licorice, Fennel}
  • Faezeh Saberinasab, Samar Mortazavi *, Alireza Riyahi Bakhtiari
    Background
    In regions with heightened pollutant concentrations, especially in industrial and urban areas, dust plays a crucial role in carrying complex metal components, posing environmental challenges and health risks. This study utilized pollution indicators and geographic information system (GIS) to delineate the spatial distribution of heavy metals in the Arak plain.
    Methods
    Dust samples from 30 stations across the Arak plain were systematically collected through random sampling. Analysis using inductively coupled plasma spectrometry (ICP-OES) allowed the calculation of pollution indices (PI) and the Nemerow Integrated Pollution Index (NIPI) for lead (Pb), zinc (Zn), copper (Cu), nickel (Ni), and iron (Fe). GIS generated spatial distribution maps depicting metal pollution.
    Results
    The average concentrations were 45.5 mg/kg for Pb, 10.7 mg/kg for Zn, 0.47 mg/kg for Cu, 30.8 mg/kg for Ni, and 0.206 mg/kg for Fe. Analysis of PI, NIPI, and spatial distribution maps revealed heightened pollution in the northeast, center, south, and southwest areas of the Arak plain, attributed to human activities like heavy vehicle traffic, high population density, concentrated agriculture, and specific industrial operations.
    Conclusion
    The study recommends mitigation strategies, including biological methods like phytoremediation, promotion of public transportation, mandatory environmental standards for industries, and encouragement of green practices. These initiatives aim to address and reduce environmental pollution in the Arak plain.
    Keywords: spatial distribution, Heavy metal, Integrated Nemerow Pollution Index (NIPI), industrial capital of Iran}
  • Mohsen Bayatzadeh, Fatemeh Karimi Organi *, Azita Koshafar, Sima Sabzalipour, Maryam Mohammadi Rouzbahani
    Background
    This study aimed to determine the maximum concentration of lead in the water and sediments of Hawizeh Swamp during 2020-2021.
    Methods
    The ECOFATE model was employed to calculate ecological risk parameters (RQ) along with total dissolved solids (TDS), total suspended solids (TSS), and total organic carbon (TOC) at four stations during summer and winter. Using the framework of environmental fate model of ECOFATE, comprehensive data on hydrological sections, input chemical quantities, chemical characteristics, and ecosystem attributes were measured.
    Results
    The findings indicated that lead concentrations were at the highest level in both sediment and water samples of the wetland across three-dimensional space during summer and winter. TSS, TOC and TDS values were estimated, of which the TDS was used to measure ecological risk due to its higher values.
    Conclusion
    The RQ values of lead indicated high and medium risk within the sedimentary and aquatic environments of the wetland ecosystem, respectively. Statistical calculations further revealed that this wetland was at risk of environmental pollution, posing potential hazards to humans through the food chain. The increase in the biological pollution of this wetland is due to the increase in the population and urban sewage. Therefore, it is imperative to raise public awareness regarding the significance of the wetland and advocate for its regular monitoring.
    Keywords: Hawizeh marshes, Heavy metal, Environmental fate model, Sediment, ECOFATE}
  • Amir Shahbazadeh Bengar, Somayeh Namroodi*, Somayeh Galdavi
    Background

    Heavy metals, such as lead harms animals’ health. The objective of this study was to evaluate the level of Pb pollution in the cities of Golestan and Mazandaran Provinces by measuring Pb concentrations in the blood of brown rats, which serve as omnivorous bioindicators living in the same habitat as humans.

    Methods

    Eight highly populated cities were selected, with 10 rats trapped in each city. Blood samples were taken from the rats, and Pb measurements were done by atomic absorption spectrometry.

    Results

    All sampled rats were Pb-contaminated. The mean Pb concentrations in different cities of Golestan Province were statistically similar (p > 0.05). In Mazandaran cities, however, significant differences in mean Pb concentrations were observed. The highest contamination was recorded in Neka (10.28 ± 0.97 μg/dL), while the lowest contamination was observed in Babol (7.3 ± 1.36 μg/dL). The mean Pb concentrations in the studied cities of Golestan (9.43 ± 1.81 μg/dL) and Mazandaran (9.02 ± 1.07 μg /dL) Provinces, as well as in male (10.38 μg/dL) and female (9.25 μg/dL) rats were similar.

    Conclusion

    The Pb contaminations observed in the sampled rats are indicative of Pb contaminations of the sampled cities and the presence of Pb sources in these areas. It seems necessary to take precautionary procedures to prevent the entry of polluted effluents into the sampled cities and the consumption of Pb-contaminated gasoline in these areas, to prevent Pb contamination of human populations.

    Keywords: Heavy metal, Rodent, North Iran, Golestan, Mazandaran}
  • Zeyana Nassor Mohamed*, Abdulsudi Issa-Zacharia, Frida Nyamete

    The increase of heavy metals concentrations in aquatic and terrestrial environments and their toxicity is of global concern. The bioaccumulation of toxic metals in fish poses a serious risk to human health when consumed. This study assessed the quality of Rabbit fish (Signus Sutor) and their associated health risks from four landing sites (namely Malindi, Mazizini, Kizimkazi and Matemwe) in Zanzibar. The concentrations of toxic metals, including Lead (Pb), Cadmium (Cd), Copper (Cu), Chromium (Cr), Nickel (Ni), and Arsenic (As), in the fish muscle were scrutinized using inductively coupled plasma optical emission spectrometry (ICP-OES). The detected mean concentration (mg/kg) of Pb, As, Cr, Cd, Cu, and Ni at Malindi were 0.25±0.14, 2.22±0.44, 0.02±0.02, 0.01±0.00, 0.02±0.02 and 0.00±0.00 respectively; at Kizimkazi were 0.39±0.39, 2.30±0.44, 0.11±0.01, 0.07±0.04, 0.17±0.13 and 0.15±0.04 respectively: at Matemwe were 0.38±0.12, 0.52±0.14, 0.04±0.02, 0.05±0.01, 0.65±0.21 and 0.09±0.03 respectively; and Mazizini were 0.21±0.12, 5.56±1.37, 0.02±0.02, 0.03±0.01, 0.05±0.02 and 0.15±0.05 respectively. The mean concentration levels detected for all the elements in the fish gathered from all four landing sites were below international and local maximum (FAO/WHO) permissible limits for human consumption, except for Arsenic (As) and lead (Pb). The study also investigated the relationship between fish size and metal concentration which shows a positive correlation for Cu and Ni. However, it was negative for the remaining metals, possibly due to ecological and metabolic differences. The study emphasizes the necessity for regular monitoring of the marine environment and enforcement of hygienic regulations, as well as the treatment of land-based pollutants before they are discharged into the marine environment to protect fish quality.

    Keywords: Heavy metal, Pollution, Bioaccumulation, Fish quality, Food safety, Health risk}
  • Rezgar Feizolahi, Mohammad Reza Mehrasbi, Mazyar Peyda, Zohre Farahmandkia *
    Background

    The contamination of food with heavy metals is a significant concern for humans. Among food products, milk and dairy products have received more attention due to their widespread consumption at all ages, particularly among children. The aim of this study is to determine the concentration of lead and cadmium in milk and dairy products in Zanjan.

    Methods

    132 samples of milk, doogh, yogurt, and cream were collected from Zanjan city during the winter and summer of 2020-2021. The lead and cadmium levels in the samples were quantified using microwave digestion and graffiti furnace atomic absorption spectrophotometry.

    Results

    The average concentrations of lead and cadmium in traditional milk, industrial milk, doogh, full-fat yogurt, low-fat yogurt, and cream samples were 96.23, 89.91, 78.79, 49.79, 53.74, 106.08, and 2.76, 2.07, 2.59, 1.09, 1.34, 5.60 µg/kg, respectively. The mean lead concentrations in milk and dairy products during winter were significantly higher than those during summer, whereas the mean cadmium concentrations during summer were higher than those during winter for all dairy products.

    Conclusion

    The lead and cadmium concentrations in most of the samples exceeded the WHO-FAO standards of 20 and 2.6 µg/kg for lead and cadmium, respectively. Therefore, prompt action is necessary to address this issue.

    Keywords: Milk, dairy products, Lead, Cadmium, Zanjan, Heavy metal}
  • Nwabudike Hillary Nwabuaku, Oluwatoyin Ologe, Lukman Abdullahi, Hamdalat Sheu, Yunusa Abdulganiyu, Tajudeen Olanrewaju Yahaya *
    Background

    This study focused on the evaluation of the quality of borehole water in Oshodi, Lagos, Nigeria, considering that groundwater serves as the primary source of potable water in the country. However, the vulnerability of groundwater to contamination raises concerns regarding its suitability for consumption.

    Methods

    Water samples were obtained from Okota, Ayo, Osi, Oke-Afa, Ajao, Oshi, and Iso-Aye Streets in Oshodi and assayed for the presence of heavy metals and microorganisms. The heavy metals analyzed in the samples included zinc (Zn), lead (Pb), chromium (Cr), manganese (Mn), copper (Cu), iron (Fe), and cadmium (Cd). Additionally, the water samples were examined for the presence of bacteria, coliforms, and fungi as representative microorganisms. To evaluate the potential health risks associated with the heavy metals detected, non-carcinogenic risks were assessed. This involved determining parameters such as average daily dermal exposure (ADDE), average daily ingestion (ADI), and hazard quotient (HQ). Further, the carcinogenic risks (CR) of the heavy metals were determined.

    Results

    The analysis of the water samples revealed that the levels of Pb and Mn, exceeded the recommended limits. However, ADI values for these heavy metals were found to be within permissible limits. The HQ of dermal exposure to Zn, Mn, and Pb during the dry season, as well as for Cr, Mn, Zn, and Pb during the wet season, were higher than recommended limits. The CR (dermal) of Pb and Cr during the wet season and Pb during the dry season were also above recommended limits. In terms of microorganisms, the presence of bacteria, coliforms, and fungi in the water samples was found to be within permissible limits.

    Conclusion

    Given the identified presence of heavy metals exceeding recommended limits and the potential health risks associated with dermal exposure and ingestion, it is evident that the water from the assessed boreholes in Oshodi poses health hazards to consumers. Therefore, it is imperative to implement decontamination measures to mitigate these risks and ensure the provision of safe and potable water to the community.

    Keywords: Carcinogenic risk, Groundwater, Hazard quotient, Heavy metal, Lead}
  • Masoumeh Abedi, AmirHossein Baghaie, Hamid Toranjzar
    Background

    This study investigated the effect of inorganic and organic sources of iron on Pb availability in soil.

    Methods

    The treatments involved applying organic and inorganic Fe sources at the rate of 0, 30, and 60 kg/ha pure Fe from different sources in the Pb-polluted soil treated with municipal sewage sludge biochar (MSSB). Corn was chosen as the tested plant in this experiment. The plants were collected after 90 days, and the Pb concentration in the soil and plants was determined using atomic absorption spectroscopy (AAS). Further, the plant enzyme activity was determined.

    Results

    Soil application of ethylenediamine Di-2-Hydroxyphenyl Acetate Ferric (Fe-EDDHA) had the greatest efficiency in reducing the soil and plant concentration. Using 30 kg Fe/ha from Fe-EDDHA relative to iron slag and FeSo4 source significantly decreased the plant Pb concentration by 11.6 and 9.8%, respectively. For ascorbate peroxidase (APX) and peroxidases (POX) enzyme activity, it was decreased by 17.2 and 15.4%, respectively.

    Conclusion

    Considering the results of this research, using inorganic and organic Fe sources in soil treated with MSSB had a substantial impact in reducing the soil and plant Pb concentration which is an advantage of environmental studies.

    Keywords: Iron source, Biochar, Heavy metal, Corn, Municipal Sewage Sludge}
  • Elham Khanniri, Saeideh Esmaeili *, MohammadEsmaeil Akbari *, Ebrahim Molaee-aghaee, Sara Sohrabvandi, Nader Akbari
    Background

     Several contaminants such as trace elements can pollute drinking water sources with subsequent toxic effects on humans. These compounds may also accumulate in target organs and result in carcinogenic reactions.

    Objectives

     The concentrations of heavy metals, including arsenic (As), nickel (Ni), zinc (Zn), aluminum (Al), copper (1), cobalt (Co), lead (Pb), cadmium (Cd), iron (Cd), tin (2), antimony (Sb), chromium (3), and mercury (Hg) were aimed to determine in the drinking water of Tehran, Iran and to assess the carcinogenic and non-carcinogenic risk for consumers.

    Methods

     A total of 66 tap water samples were collected from 22 regions of Tehran and their heavy metal contents were measured by inductively coupled plasma mass spectrometry (ICP-MS). The non-carcinogenic and carcinogenic health risks were calculated, using hazard quotient (HQ) and incremental lifetime cancer risk (ILCR), respectively.

    Results

     The findings revealed that the mean concentrations of measured elements were lower than the maximum permissible limits established by Iranian National Standards, United States Environmental Protection Agency (USEPA), and the World Health Organization (WHO). HQ was less than 1 for all metals except Cr and ILCR was higher than 1× 10-4 for Cr and Cd, which may cause human health risk.

    Conclusions

     No carcinogenic effects were posed by heavy metals contamination in the drinking water of Tehran; however, the content of Cr and Cd may cause human health risks because of the high daily intake of tap water throughout the lifetime and the tendency of these metals to accumulate in the human body organs. Therefore, implementing ongoing programs to monitor heavy metals in municipal drinking water and applying appropriate corrective actions to prevent the transfer of these pollutants to drinking water is crucial.

    Keywords: Drinking Water, Heavy Metal, Standard Limit, Carcinogenic Health Risk, Non-carcinogenic Health Risk}
  • Afrooz Saadatzadeh, Enayat Berizi, Aminoddin Ehmali, Mehrnoosh Moosavi Basedi, Seyyed MohammadAli Noori *
    Background

    Rice milk is one of the traditional foods in Khuzestan province. Due to the combination of milk and rice, this product plays a major role as a diet for children under two years old and also as a diet for adults. Heavy metals represent a special group of food contaminants and exposure to heavy metals was shown to be directly related to progression of diseases. This study was conducted to determine the concentrations of some heavy metals in rice milk to evaluate whether the concentrations of these elements correspond to the permissible levels of toxic elements in milk and rice in Ahvaz, Khuzestan Province, Iran.

    Methods

    Totally, 50 rice milk samples (25 samples from East Ahvaz and 25 samples from West Ahvaz) were collected. The heavy metals in all samples were evaluated using quantified diffuse spectroscopy (OES) or mass spectrometry (MS).

    Results

    The mean concentration of the arsenic and lead was above the permissible limit. The average nickel and cadmium concentrations in the samples were below the allowable limit values and no mercury was detected in all samples.

    Conclusion

    The study results showed that consumption of rice milk did not pose a direct and serious threat to the health of consumers. Future studies and continuous monitoring are necessary to assess the content of heavy metals and the risk of their consumption to the consumer of the rice milk.

    Keywords: Heavy metal, Rice milk, Health, Iran}
  • نسترن عاقلان، سهیل سبحان اردکانی*، مهرداد چراغی، بهاره لرستانی

    زمینه و هدف :

    با توجه به این که گیاه پالایی فناوری نوین پالایش خاک آلوده است، این پژوهش با هدف بررسی برخی اصلاح کننده ها با نرخ تجزیه پذیری زیستی متفاوت در بهبود کارایی گیاه پالایی خاک آلوده به کروم و مس توسط گونه های زینتی تاج خروس و گل جعفری در سال 1397 انجام شد.

    مواد و روش ها

    با آلوده سازی خاک توسط نمک های دی کرومات پتاسیم 50 و 100 و سولفات مس 200 و 400 میلی گرم در کیلوگرم و تیمار با محلول 2.50 میلی مول در کیلوگرم EDTA و اسید سیتریک (CA) و 2.00 میلی مول در کیلوگرم اسید سالیسیلیک (SA)، نسبت به کشت گیاهچه ها و برداشت آن ها بعد از 60 روز اقدام شد. پس از هضم اسیدی گیاهچه ها، محتوی عناصر کروم و مس در آن ها به روش طیف سنج نشری پلاسمای جفت شده القایی خوانده شدند.

    یافته ها

    بیشینه غلظت کروم در خاک کشت شده، ریشه و شاخساره تاج خروس با 2.40، 5.18 و 1.86 و در گل جعفری با 2.74، 6.00 و 1.30 میلی گرم در کیلوگرم به ترتیب مربوط به تیمارهای SA، EDTA و EDTA و در مورد مس در خاک کشت شده، ریشه و شاخساره تاج خروس با 6.74، 3.77 و 3.34 به ترتیب مربوط به SA، SA و EDTA و در گل جعفری نیز با 6.65، 3.45 و 9.50 میلی گرم در کیلوگرم به ترتیب مربوط به تیمارهای SA، EDTA و EDTA بود. از طرفی، تاج خروس با فاکتورهای انتقال و تجمع زیستی بزرگ تر از یک در تیمار 100 میلی گرم در کیلوگرم دی کرومات پتاسیم افزوده واجد CA، فرا انباشتگر کروم بود.

    نتیجه گیری

    با توجه به نقش مهم اسیدهای آلی در الکتروکینتیک پالایش خاک و بهبود کارایی گیاه پالایی، استفاده از این عوامل اصلاح کننده برای پاکسازی خاک های آلوده به فلزات سنگین توصیه می شود.

    کلید واژگان: الکتروکینتیک, اصلاح کننده خاک, گیاهان زینتی, فلز سنگین, گیاه پالایی}
    Nastaran Aghelan, Soheil Sobhan Ardakani *, Mehrdad Cheraghi, Bahareh Lorestani
    Background and Purpose

    Phytoremediation is a new technology for remediation of contaminated soils, this study was conducted to evaluation of efficiency of EDTA, citric acid and salicylic acid chelating agents in phytoremediation enhancing of Amaranthus caudatus and Tagetes patula for elimination of Cr(III) and Cu(II) from contaminated soils in 2018.

    Material and Methods

    After soil pots contaminating by 50 and 100 (mg/kg) K2Cr2O7 and 200 and 400 (mg/kg) CuSO4 salts, and 2.5 (mmol/kg) of EDTA and citric acid (CA) and 2.0 (mmol/kg) of salicylic acid (SA) solution treating, the cultured seedlings were harvested after 60 days. Then, after seedlings digestion, Cr and Cu contents were determined using ICP-OES

    Results

    Based on the results obtained, the maximum contents of Cr (mg/ kg) in cultivated soil, root and stem samples of A. caudatus were 2.40, 5.18 and 1.86 were found in the SA, EDTA and EDTA treatments, respectively and in T. patula with 2.74, 6.00 and 1.30 were found to be in the SA, EDTA and EDTA treatments, respectively. Also, the maximum contents of Cu (mg/kg) in cultivated soil, root and stem samples of A. caudatus with 6.74, 3.77 and 3.34 were found to be in the SA, SA and EDTA treatments, respectively and in T. patula with 6.65, 3.45 and 9.50 were found to be in the SA, EDTA and EDTA treatments, respectively. On the other hand, translocation (TF) and bioconcentration (BCF) factors of A. caudatus both were greater than 1 in soils with 100 mg/kg added K2Cr2O7 containing CA, which indicates that this species can be known as hyperaccumulator of Cr

    Conclusion

    In conclusion, concerning to the considerable role of organic acids in soil refining electrokinetic and phytoremediation efficiency enhancing, using of these soil amendment agents is recommended to cleanup of contaminated soil with heavy metals

    Keywords: Electrokinetic, Soil amendment, Ornamental plants, Heavy metal, Phytoremediation}
  • زهره سلطانی، رسول قربانی، سید علی اکبر هدایتی*، افشین عادلی، محمد مازندرانی
    زمینه و هدف

    روی یکی از فلزات سنگین موجود در اکوسیستم های آبی است. در حال حاضر فناوری نانو دارای پیشرفت چشمگیری در صنایع مختلف شده است، در مطالعه حاضر میزان سمیت نانواکسید روی بر شاخص های خونی سیاه ماهی بررسی شد.

    روش ها

    این تحقیق با غلظت های 0، 5، 20، 400 و 100 میلی گرم بر لیتر نانواکسیدروی به مدت 14 روز بر تعداد 70 قطعه سیاه ماهی با میانگین وزنی 5±20 گرم انجام شد. پس از اتمام آزمایش، شاخص های خونی شامل تعداد کل گلبول های سفید، لنفوسیت، نوتروفیل، ایوزینوفیل، تعداد کل گلبول های قرمز، محتوای هموگلوبین، سطح هماتوکریت، حجم متوسط گلبولی (MCV)، وزن هموگلوبین داخل گلبولی (MCH) و درصد غلظت هموگلوبین داخل گلبولی (MCHC) اندازه گیری شد.

    یافته ها

    تمامی شاخص های اریتروسیتی خون تغییرات معنی داری از خود نشان دادند ولی شاخص های لوکوسیتی هیچ گونه تغییری نداشتند. همچنین با افزایش غلظت نانواکسید روی در تیمارهای مختلف میزان گلبول های قرمز، هموگلوبین و هماتوکریت کاهش و میزان گلبول های سفید افزایش یافت.

    نتیجه گیری

    با افزایش غلظت نانواکسیدروی میزان تاثیر نامطلوب خون شناسی بالاتر بوده و غلظت 100 میلی گرم بر لیتر دارای بیشترین عوارض نامطلوب است. نانواکسیدروی باعث بروز کم خونی و ایجاد اختلال در سیستم ایمنی ماهی می شود که ممکن است به دلیل اثرات مخرب آن بر اندام های خون ساز مانند کبد و کلیه باشد.

    کلید واژگان: نانواکسید روی, سیاه ماهی, فلز سنگین, شاخص های خون شناسی}
    Zohre Soltani, Rasoul Ghorbani, Aliakbar Hedayati*, Afshin Adeli, Mohammad Mazandarani
    Background and Aim

    Zinc is one of the heavy metals in aquatic ecosystems. Currently, nanotechnology has made significant progress in various industries, in the present study, the toxicity of nano-zinc oxide on the blood indices of Capoeta capoeta gracilis (Capoeta) was investigated.

    Methods

    This research was conducted with concentrations of 0, 5, 20, 100 and 400 mg/L of nano-zinc oxide (Nano-ZnO) for 14 days on 70 Capoeta with a mean weight of 20±5 grams. After the experiment, blood samples were taken from the Capoeta and various blood indices were measured including leukocytes, lymphocytes, neutrophils, eosinophils, erythrocytes, hemoglobin, hematocrit, MCV, MCH and MCHC.  

    Results

    All blood erythrocyte indices in Capoeta showed significant changes, but leukocyte indices did not change. Also, with the increase of nano-zinc oxide in different treatments, the number of red blood cells, hemoglobin and hematocrit decreased and the number of white blood cells increased in Capoeta.  

    Conclusion

    With rising the concentration of nano-zinc oxide, the level of hematological adverse effects increased and the concentration of 100 mg/l has the most adverse effects in Capoeta. Nano-zinc oxide causes anemia and disrupts Capoeta's immune system, which may be due to its destructive effects on hematopoietic organs such as the liver and kidney.

    Keywords: Nano-zinc oxide, Capoeta capoeta gracilis (Capoeta), Heavy Metal, Hematological Indices}
  • Alireza Esmaeili, Shabnam Shamaei, Ebrahim Molaee Aghaee, Zabih Nosrati Akhtar, Seyede Fatemeh Hosseini, Samira Shokri *

    Anemia patients are more susceptible to environmental contaminations such as heavy metals. The present study aimed at risk assessment of heavy metals in edible mushrooms and Anemia.The databases searched in those articles were Google Scholar, SID, Scopus, PubMed, Science Direct, and ISI. Related human health risks were calculated using the target hazard quotient (THQ). THQ ratio of Cd, Cu, Fe, Pb, Cr, Ni, and Mn were 3×10−3, 2.31, 8.43×10 −1, 2.35, 2.92×10−1, 6.6×10− 2 and 1.96×10− 1 m m-1 respectively. The highest non-carcinogenic diseases risk for adults were found in Pb (2.35 m m-1) while the lowest value was observed in Cd (3×10− 3 m m-1). The risk of carcinogenicity of lead was at the level of acceptable (10−4 to 10−6 m m-1). There is no concern about the non-carcinogenic risk of consuming heavy metals in edible mushrooms, in Iran except Cu and Pb. In some countries, adults and children can be exposed to non-cancerous foods by eating mushrooms. And can aggravate anemia in the consumer.

    Keywords: Mushroom, Risk Assessment, Anemia, Carcinogenic, Toxic, Heavy metal}
  • Zahra Kaveh, Sima Askari *, Gelareh Ghaffari Asl, Reza Marandi

    Biological adsorption of heavy metals is an effective process for removing heavy metals from aqueous solutions. In this study, the adsorption properties of non-viable Phanerochaete Chrysosporium biomass are studied for biological adsorption of lead ion in both continuous and batch systems. In the batch process, Langmuir, Freundlich and Dobbinin-Radushkevich isotherms are studied. The adsorption kinetics including pseudo-first order, pseudo-second order and intraparticle diffusion models are also investigated. The experimental equilibrium data follow Langmuir, Freundlich and Dobbinin-Radushkevich models. The kinetic data fit well to the pseudo-second order and intraparticle diffusion models. In the continuous system, by studying the Thomas and Yoon-Nelson models it can be concluded that particles of Phanerochaete Chrysosporium are very suitable adsorbents for the adsorption of heavy metal of lead with high efficiency. Increasing input flowrate causes earlier breakthrough point. Thermodynamic calculations also prove that the process is spontaneous and self-healing and positive ∆H indicate process is endothermic.

    Keywords: Heavy metal, Sonochemical, Pb (II), Biosorption, Wastewater treatment}
  • نسرین الوند، محمد علیمرادی، مجید بغدادی*، اعظم مرجانی، طاهره مومنی اصفهانی
    مقدمه

    در پژوهش حاضر، یک روش ریزاستخراج نیکل سازگار با محیط زیست بر پایه فاز جامد به کمک فلز آهن مورد بررسی قرار گرفت. به دلیل عدم استفاده از حلال های آلی، این روش می تواند به عنوان یک روش سبز به منظور استخراج و کاهش حد تشخیص نیکل در نمونه های آب مورد استفاده قرار گیرد.

    روش ها

    با افزودن 06/0 گرم سدیم بروهیدرید به 100 میلی لیتر محلول حاوی یون های آهن (II) به غلظت 12 میلی گرم بر لیتر و نیکل، این یون ها به ذرات با ظرفیت صفر تبدیل شد و ذرات نیکل احیا شده در میکروذرات آهن حبس و به همراه آن ته نشین شوند. سپس فاز جامد تشکیل شده در 200 میکرولیتر اسید هیدروکلریک 6 نرمال حل و غلظت نیکل در آن از طریق جذب اتمی اندازه گیری گردید. برای بهینه سازی فرایند، اثر pH (1 تا 8)، مقدار پتاسیم هیدروژن فتالات (3/0-02/0 گرم)، غلظت آهن (II) (5-20/2 میلی گرم بر لیتر)، سدیم بروهیدرید (2/0 تا 01/0گرم)، زمان (15-5/0 دقیقه) و دما (80-20 درجه سانتی گراد) مورد بررسی قرار گرفت. همچنین، اثر یون های مزاحم در تحقیق بررسی شد. در نهایت، ارقام شایستگی روش به دست آمد و عملکرد روش روی نمونه های آب واقعی مورد ارزیابی قرار گرفت.

    یافته ها

    با بهینه سازی صورت گرفته، سدیم بروهیدرید 06/0 گرم، 5/4 = pH، غلظت آهن (II) 5/2 میلی گرم بر لیتر، مقدار پتاسیم هیدروژن فتالات 08/0 گرم، زمان 4 دقیقه، دمای 50 درجه سانتی گراد و حجم نمونه 100 میلی لیتر به عنوان شرایط بهینه برای فرایند انتخاب گردید. فاکتور تغلیظ 410، حد تشخیص 3/0 نانوگرم بر میلی لیتر و میزان انحراف استاندارد نسبی (Relative standard deviation یا RSD)، 7/2 درصد به دست آمد.

    نتیجه گیری

    با توجه به حد تشخیص پایین و حذف حلال های آلی در ریزاستخراج فلز نیکل، این روش به عنوان یک روش مورد اعتماد برای اندازه گیری مقادیر بسیار پایین نیکل با راندمان بسیار قابل قبول می باشد. این حد تشخیص پایین به دلیل فاکتور تغلیظ خیلی بالا است که در بین روش های ریزاستخراج دیگر میزان قابل توجهی می باشد.

    کلید واژگان: آب, ریزاستخراج فاز فلزی, نیکل, تغلیظ, فلز سنگین}
    Nasrin Alvand, Mohammad Alimoradi, Majid Baghdadi*, Azam Marjani, Tahereh Momeni-Isfahani
    Background

    In the present study, an environmentally friendly microextraction of nickel based on solid-phase method coupled to flame atomic absorption spectrophotometry was investigated. Due to elimination of organic solvents in this method, it can be used as a green technique to extract and reduce the detection limit of nickel in water samples.

    Methods

    By adding 0.06 g sodium borohydride (NaBH4) to 100 ml of the solution containing Fe (II) ions with concentration of 12 mg/l and nickel, these ions were converted to zero-valent particles. The nickel revived particles were trapped in the iron microparticles and deposited with them. After that, the solid phase produced was dissolved in 200 µl  of hydrochloric acid (HCl) 6N and the nickel concentration was measured using atomic absorption method. To optimize the process, effect (1 to 8), the amount of potassium hydrogen phthalate (KHP) (0.02-0.30), Fe (II) concentration (2.20-5.00 mg/l), NaBH4 (0.20-0.01 g), time (0.5-15.00 minutes), and temperature (20° -80°  C) were investigated. In addition, the effect of interfering ions was evaluated. Finally, the figures of merit were calculated, and the function of the method was investigated in the real water samples.

    Findings

    According to the performed optimization, pH = 4.5, NaBH4 = 0.06 g, Fe (II) = 2.5 mg/l, KHP = 0.08 g, time= 4 minutes, temperature = 50° C , and sample size = 100 ml were the optimum conditions. Besides, the concentration factor of 410, the detection limit of 0.3 ng/ml, and relative standard deviation (RSD) of 2.7% were obtained.

    Conclusion

    Due to the low detection limit and the elimination of organic solvents in nickel microextraction, this method can be a suitable method for determining trace amount of nickel with high efficiency. The low detection limit is due to the high concentration factor, which is significantly higher than the other microextraction methods.

    Keywords: Water, Metal-phase microextraction, Nickel, Concentration, Heavy metal}
  • عباس خدابخشی، فاضل محمدی مقدم، سارا همتی، کبری شاکری*
    زمینه و هدف

     آبیاری با پساب فاضلاب و استفاده از لجن به عنوان کود یکی از نگرانی های مهم مسایل بهداشتی و زیست محیطی می باشد. هدف این پژوهش تعیین مقدار فلزات سنگین ارسنیک، کادمیوم و سرب در سیب زمینی و خاک زمین های کشاورزی منطقه سفید دشت استان چهارمحال و بختیاری می باشد.

    روش کار

    این تحقیق یک مطالعه تجربی- آزمایشگاهی است. نمونه برداری از سه قطعه زمین کشاورزی به طور میانگین به مساحت یک هکتار انجام شد. به منظور هضم نمونه های خاک و سیب زمینی بترتیب از  هاضم Hach و اجاق شنی استفاده شد. در نهایت با استفاده از دستگاه جذب اتمی Varian مدل AA240 غلظت فلزات سنگین قرایت شد.

    یافته ها

    نتایج این تحقیق نشان داد که فلز سرب بیش ترین تجمع پذیری را در خاک  و سیب زمینی  دارد. همچنین میانگین غلظت فلزهای کادمیوم، آرسنیک و سرب در سیب زمینی پایین تر از حدود استاندارد بود. فاکتور انتقال از الگوی آرسنیک > کادمیوم> سرب پیروی کرد.

    نتیجه گیری

    با توجه به نتایج این مطالعه باید اقداماتی در جهت پیشگیری از ورود بیش از حد عناصر سنگین به خاک صورت گیرد، بنابراین باید با کاهش مقدار مصرف کودهای دامی و شیمیایی وضعیت عناصر سنگین در منطقه سفید دشت کنترل نمود.

    کلید واژگان: فلزات سنگین, سیب زمینی, خاک}
    Abbas Khodabakhshi, Fazel Mohammadi-Moghadam, Sara Hemati, Kobra Shakeri*
    Background and Aim

    Irrigation with wastewater and the use of sludge as fertilizer is one of the important issues related to health and environmental concerns. The purpose of this study was to determine the amount of heavy metals of arsenic, cadmium and lead in potato and soil of agricultural lands in Sefid Dasht in Chaharmahal and Bakhtiari Province.

    Materials and Methods

    This study was an experimental-laboratory study. Samples were obtained from three agricultural lands with an average area of ​​one hectare. Hach digestion and Sandstone were used for digestion of soil and potato samples, respectively. Finally, the concentrations of heavy metals were measured using Varian atomic absorption spectrophotometer (AA240 model).

    Results

    The results of this study showed that lead metal had the highest rate of accumulation in soil and potato. The calculated transfer factor was according to the Arsenic > Cadmium > Lead pattern.

    Conclusions

    According to the results of this study, measures should be taken to prevent contamination of the soil by heavy elements. Therefore, the amount of heavy elements in the soil of Sefid Dasht should be controlled by reducing use of livestock manure and chemical fertilizers.

    Keywords: Heavy metal, Potato, soil}
  • Leila Rezaei, Vali Alipour, AmirHesam Hassani, Mohsen Dehghani *
    Background

    the Persian Gulf ecosystem is facing degradation, so further degradation must be prevented. The present study was conducted to assess the environmental pollution risk potential of the coastal ecosystem due to heavy metal content in desalination plant’s effluent.

    Methods

    In this cross-sectional study, the researchers selected five stations in the west of Bandar Abbas beach, located at the outlet of desalination effluent canals to the shore, and two stations in the east shore (without effluent discharge) as case and control stations, respectively. The researchers collected 51 Sediment samples and measured heavy metal concentration, using an AA spectrophotometer, and assessed the potential ecological risk. They used SPSS software and the T-test to statistically analyze data.

    Results

    The concentration means for sediments in case and control stations samples were: 40.63±16.79, 96.64±30.60, 159.74±50.65, 109.22±17.09, 205.35±86.96 mg.kg-1 and 40.15±17.21, 79.16±28.26, 152.43±90.07, 101.82±43.55, and 193.82±112.90 mg.kg-1, respectively for (Pb, Cu, Ni, Cd, and Zn). The ecological risk and Pollution Load Index were (31.72, 35.95, 3.30, 36.96, and 45.61) and (0.62, 0.63, 0.71, 0.68, and 0.9), respectively for metals mentioned order. Individual potential risk for all stations showed a low-risk degree.

    Conclusion

    Although the heavy metals accumulated in coastal sediments due to the discharge of desalination plant effluents, severe ecological and environmental damage has not occurred. Therefore, there is still time to prevent an environmental catastrophe on the shores receiving desalination effluents. Therefore, it is recommended to all responsible persons to take the necessary measures to monitor and control the plan and reduce the discharge of effluents to the shores.

    Keywords: Desalination, Ecological, Environmental, Heavy metal, Persian Gulf, Pollution}
  • Majid Ramezani, Mohammad Hashemi, Mehdi Varidi, Mitra Rezaie *

    The present study aimed to evaluate Fatty acid profile and level of heavy metals in the sesame oils consumed in Iran. In total, 30 sesame oil samples were collected from factories (n=20; industrial) and from traditional mills (n=10; non-industrial). Heavy metal content and the FA profile of examined samples oil were determined by ICP-OES and gas Chromatography respectively. Significant differences were observed between the industrial and non-industrial sesame oil samples in terms of the Fatty acid profile and toxic heavy metals contamination. In addition, the fatty acid profile of the industrial and non-industrial sesame oil indicated high levels of unsaturated fatty acids (84.5% and 83.49%, respectively), with the main fatty acids determined to be oleic acid and linoleic acid. The fatty acid profile of the sesame oil samples indicated no adulteration with other vegetable oils. The concentration of lead, cadmium, iron in industrial sesame oil were observed in the range of 0.008–1.33, 0.001–0.04, 0.11–6.74 mg/kg, and in non-industrial sesame oil were found to be 0.00–0.199, 0.01–0.04, 0.8–4.3 mg/kg respectively. In general, lead content was higher than that of the legislation limit of Iran and European Union (0.1 mg/kg). Mercury and arsenic metals no detected in any of sesame oil samples. Mean values obtained in this work for Fe was lower than the maximum values recommended for FAO/WHO (1-1.5 μg/g) and for Cd was agree whit international requirements, the approved content of Cd in oils are: 0.05 μg/g (1). The health risks carcinogenic (ILCRs) and no carcinogenic (HI or THQ) were highly exceeded than threshold value of 1 in the both consumer groups of adult and children. This calls for concern for both adults and children exposed to consume of sesame oil through ingestion. It is necessary to monitor the presence of heavy metal contaminants and the quality of imported sesame seeds prior to oil preparation.

    Keywords: Sesame oil, Heavy metal, Risk Assessment, Hazard Quotient, Food analysis}
نکته
  • نتایج بر اساس تاریخ انتشار مرتب شده‌اند.
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