جستجوی مقالات مرتبط با کلیدواژه « cmp pulp » در نشریات گروه « صنایع چوب و کاغذ »

In this study, the influences of nano-chitosan and poly-DADMAC on the optical and mechanical properties of chemi-mechanical pulp (CMP) were evaluated. For this purpose, some of the bleached CMP pulps of Mazandaran Wood and Paper Industries (MWPI) were randomly selected as a control sample. In addition, the poly-DADMAC were used as a white powder at 4 levels of ‎0, 0.3, 0.5, and 0.7%. The nano-chitosan was then added to the CMP pulps suspensions at 3 levels of 0, 1, and 2%, as well. Hand-sheets with a basis weight of 60 gr/m2 were prepared from the mentioned pulps. The optical and mechanical properties were measured and compared using TAPPI standard test methods. The results showed that by adding poly-DADMAC to the CMP pulps, brightness, a* factor, breaking length, tensile and burst strengths ‎increased, but yellowness, greenness and Cobb 60 decreased and opacity, tear strength and air resistance‎ not sensible changed. The results indicated that the brightness, a* factor, opacity, tear strength, burst strength and air resistance were increased and greenness and water absorption and were decreased by increasing nano-chitosan amount. In this condition, the suitable properties showed that in handsheets from adding nano-chitosan to CMP pulps. When poly-DADMAC and nano-chitosan were added simultaneously to CMP, the brightness, opacity, a* factor, tear strength, burst strength and air resistance were suitable increased, but yellowness, water absorption and greenness were decreased. Moreover, the findings showed that by simultaneous adding 2% nano-chitosan (separate) and 2% nano-chitosan with 0.5 and 0.7% poly-DADMAC to the CMP pulp, most of the paper properties were improved. Therefore, ‎it can also be introduced as the best treatment.

 Today, with the increase in population, increasing demand for paper, as well as greater restrictions on raw materials, the production of pulp from high-yield pulps and mechanical pulps has found a special place. These pulps have a high yield greater than 85%, but due to the presence of lignin, extracts, and metal ions, their use is limited to short-term usage, as in the long run they suffer from brightness reversion and photo-yellowing. This study aimed to investigate the effect of DTPA, nano-cellulose, and nano-chitosan spray on the optical properties of chemical-mechanical pulp (CMP).

 For this purpose, first, a quantity of bleached chemical-mechanical pulp (CMP) was selected as a control sample from ‎Mazandaran wood and paper industry.‎ Papers with a base weight of 60 gr/m2 were prepared from the mentioned paper pulp. In this study, the nano-fibrillated cellulose (NFC) was purchased from Nano Novin Polymer Co. (Sari, Iran), which was prepared from softwood alpha cellulose pulp with an average fiber diameter of 32 nm. The NFC was loaded at 2% by spraying onto papersheets. Nanochitosan (“Seafresh”, Thailand), obtained from exoskeletons of crustaceans, with a deacetylation degree of 93% and a molecular weight of 270 kDa was used. Nanochitosan was loaded at 1 and 2% of the dry pulp weight. Diethylene triamine penta acetic acid (DTPA) was prepared from DIPER-Samchun (South Korea), with a 50% solid content and 25 cps viscosity. To spray the DTPA onto the paper surface, 0.5% DTPA was prepared. To prepare samples for the surface modification, paper sheets with a basis weight of 60 g/m2 were made. Then, 0.5% DTPA, 2% nanochitosan, and 2% nanocellulose were sprayed separately on the papersheets. In addition, another treatment named mixed-solution (containing 0.5 % DTPA + 2% nanochitosan + 2% nanocellulose) was sprayed onto the handsheets. The spraying time and distance were 20 s and 20 cm, respectively, and the treatment process was named “spray-coated”. Then, the optical properties (brightness, opacity, yellowness, and greenness) of the hand-‎sheets were measured according to ASTM and TAPPI standard methods. ‎

The results showed that by DTPA, nano-cellulose, and nano-chitosan spray in the handsheet paper, brightness, yellowness, greenness, L* factor, and the opacity increased and the a* factor decreased. By spraying nano-cellulose on the test samples, most of the optical properties were significantly improved except for the yellowness of the hand-sheet paper. In addition, the most appropriate properties were observed in the paper obtained from DTPA spray and also in the simultaneous spray treatment of DTPA, nano-cellulose, and nano-chitosan on hand-sheet papers. Therefore, it has caused a very sensible increase and improvement in all the optical properties, which can be selected and suggested as the best treatment. The evaluation results of the brightness reversion of the hand-sheet paper from CMP pulp showed that most of the treatments led to a relative reduction of the return of the paper brightness. On the other hand, the lowest and highest brightness return values in the hand-sheet paper were obtained from 0.5% DTPA spray and nano-chitosan spray, respectively. The evaluation results of the SEM images of the test samples compared to the control sample showed that the hand-sheet paper with nano-chitosan and nano-cellulose spray and also in the simultaneous spray treatment of DTPA, nano-cellulose, and nano-chitosan had more favorable surface and structural properties. The existence of less empty spaces (cavity) and more overlap of fibers in the test samples can be a reason for the higher quality of the properties, as well.

The results showed that by spraying nanocellulose, nano- chitosan and DTPA on the test samples, the optical properties, brightness, greenness, opacity, a* factor, l* factor , yellowness and brightness ‎‎durability improved. In ‎addition, among the various treatments, the DTPA treatment in long-term thermal aging and the use of nano-chitosan and nano-cellulose in the short-term aging had noticeable effects on brightness ‎‎durability and decrease in the color reversion. As a result, there was an increase in the durability of the paper ‎against thermal deterioration.

This study was aimed to investigate the effect of polyalumium chloride and ‎nano-chitosan on optical and mechanical properties of chemi-mechanical pulp. For this purpose, some of the bleached CMP pulp of Mazandaran Wood and Paper Industries (MWPI) were randomly selected as a control sample. In addition, the polyalumium chloride were used as a white powder at 4 levels of ‎0, 0.5, 1, and 1.5%. The nano-chitosan was then added to the CMP pulps suspensions at 3 levels of 0, 1, and 2%, as well. Hand-sheets with a basis weight of 60 gr/m2 were prepared from the mentioned pulps. The optical and mechanical properties were then measured and compared using TAPPI standard test methods. The results showed that by adding polyalumium chloride and nano- chitosan(separate) to the CMP pulps, brightness, opacity, greenness,tear, tensile, burst strengths, air resistance‎ ‎increased , but Cobb 60 and a* factor ‎decreased. On the other hand, with the addition of nano-chitosan and polyalumium chloride to CMP pulp, the brightness and greenness increased, but tensile, burst, tear strengths, air resistance, Cobb 60 and opacity low decreased and then suitable increased. Moreover, the findings showed that by simultaneous adding 1% polyalumium chloride and 2% nano-chitosan(separate) and 2% nano-chitosan with 1.5% polyalumium chloride to the CMP pulp, most of the paper properties were improved. Therefore, ‎it can also be introduced as the best treatment.

This study and it aim was accomplished on the effect of using cellulose nano-fibers and cationic starch on optical and mechanical properties of chemi-mechanical pulp. For this purpose, first some of bleached CMP pulps were randomly selected from Mazandaran Wood and Paper Industries (MWPI) as control. Then, cellulose nano fibers bought as white gel and used in 0, 2, 3 and 4 % levels. The cationic starch were added in 0, 0.3 and 0.6 % levels and imported long fibers with 0 and 5 % levels to CMP pulps suspensions, too. The hand sheets were prepared from above-mentioned of pulps with 60 gr/m2 basis weight and then the optical and mechanical properties were measured and compared according to TAPPI standard test methods. The results showed that brightness, a* factor, tear, tensile, burst strengths and air resistance were increased and opacity and greenness were decreased. The results showed that all optical and mechanical properties expect greenness and burst strength, improved with 5% addition imported long fiber and 3 and 4 % cellulose nano-fibers. The results showed that using 0.6 % cationic starch with 4 % cellulose nano fibers improved the most paper properties, expect brightness and tensile strength, too.

This study was aimed to investigate the effect of cellulose nano-fibers and ‎chitosan on optical and mechanical properties of chemi-mechanical pulp. For this purpose, some of the bleached CMP pulp of Mazandaran Wood and Paper Industries (MWPI) were randomly selected as a control sample. In addition, the cellulose nanofibers were used as a white gel at 3 levels of ‎0, 2, and 3%. The chitosan was then added to the CMP pulps suspensions at 5 levels of 0, ‎‎0.5, 1, 1.5, 2%, as well. Hand-sheets with a basis weight of 60 gr/m2 were prepared from the mentioned pulps. The optical and mechanical properties were then measured and compared using TAPPI standard test methods. The results showed that by adding chitosan, tear, tensile, burst and breaking length strengths, air resistance, ‎yellowness, and greenness ‎increased and brightness, Cobb 60 and a* factor ‎decreased. On the other hand, with the addition of chitosan and nano-‎cellulose to CMP pulp, the tensile, burst, breaking length strengths, air resistance, Cobb 60, yellowness and a* factor ‎increased and the tear, brightness, and opacity decreased. Moreover, the findings showed that by simultaneous adding 2% chitosan, 2% chitosan, and 3% cellulose nanofibers to the CMP pulp, most of the paper properties were improved. Therefore, ‎it can also be introduced as the best treatment.

In this study, the effect of pigment composition on the properties of paper prepared from CMP pulp was studied. There for 3 different pigment combinations (100% calcium carbonate (GCC), 70% calcium carbonate and 30% kaolin clay (70GCC30Clay) and 70% calcium carbonate and 25% gritty and 5% titanium dioxide (70GCC25Clay5TiO2)) were made with anionic starch, latex and dispersersant and Used for coating. Physical properties included (surface roughness of the paper, Ash content and Apparent density) And the optical properties included (brightness, absorption and diffusion coefficient) and paper resistance characteristics including tensile strength, bursting resistance, tear strength based on standard TAPPI standardized measurements and Using factorial design, analysis of variance was performed and the mean of paper properties was compared with Duncan's test. The purpose of this research is to achieve the best combination for coating the paper with the improvement of physical and optical properties and maintaining resistance properties. By adding clay and dioxide titanium to calcium carbonate, the roughness of the paper surface decreased The highest roughness of the surface of the paper in the diet was observed for the control paper and the lowest was seen in the treatment of 70GCC30Clay surface. Also, the highest degree of brightness is related to 70GCC25Clay5TiO2 treatment. The highest index of tensile strength and burst strength index was related to gypsum treated paper (GCC) and also the highest tear strength index for treated paper at level 2 (70GCC30Clay).

During the paper manufacturing process, especially when mechanical pulp or recycled pulp used, a large amount of soluble and colloidal substances (DCS) are comprised and dispersed or dissolved in the process water. Accumulation of DCS during the papermaking operation with the increasing closure process water systems, can have a variety of deleterious effects on papermaking process and paper products. In this study, The effect of anionic trash neutraliziation was investigated by using different catcher anionic tarsh and also pulp washing (removal of anionic trash) on the CMP pulp and paper properties. After the initial preparation chemi-mechanical pulp (CMP), bleached long fiber kraft pulp and mixing the pulps with each other, filler of precipitated calcium carbonate (PCC) was added. Then a cationic retention aid That in this research has been cationic polyacrylamide were added to the mix. To neutralization of and reduce the negative effects of anionic trash, different levels of poly DADMAC with molecular weight 100000-200000 (0.025, 0.05, 0.1, 0.15%) and poly aluminium chloride (PAC) (0.1, 0.25, 0.5%) was added before adding of retention aid. Results showed that the use of different neutralizers imprived of zeta potential and drainage time of pulp, and increase of total retention; but reduces burst index of paper that was not significant statistically. CMP pulp washing and drainage treatment caused reducing COD and on the other hand reduced the amount of anionic trash with organic origin. Washing treatment pulp improved drainage time from pulp, total retention; but reduced burst index. Based on these findings, using cationic polyelectrolyte can introduce as a good strategy to reduce the harmful effects anionic trash and more retention suspension components.

This study and it aim was accomplished on the effect of TCF bleaching on optical and mechanical properties of CMP pulp. For this purpose, some unbleached CMP pulps were randomly selected from Mazandaran Wood and Paper Industries (MWPI). Then these pulps were bleached with two and three OP, OPY, PY and O(Eo)P bleaching stages by using oxygen(O), alkali extraction with hydrogen peroxide(Eo), sodium dithionite(Y) . The hand sheets with 70 gr/m2 were prepared from above-mentioned of pulps, and then the optical and mechanical properties were measured and compared according by using TAPPI Standard test methods. The results showed that brightness, greenness, folds breaking length, tensile and tear strength were increased and opacity and a* factor were decreased. In general, role of three O(Eo)P stages and two OP and PY bleaching stages were better than P stage and unbleached CMP pulp mill in improve of brightness and its paper strength, too.

In this study, the possibility of using ash and orange bleached CMP pulp as replace in the full or part of CMP pulp of Mazandaran Wood and Paper Industries (MWPI) for making newsprint was investigated. For this purpose, first, ash and orange CMP pulps were prepared by using cooking conditions of MWPI with 101 gr/lit Na2O at the yield 85% in 75 minutes. Then some of the CMP pulps bleached with hydrogen peroxide, then its mixed samples with 15, 30, 45 and 60 percent to CMP pulp mill (control sample). From the mixed pulps provided hand sheets with 60 gr/m2 and these optical and mechanical properties measured and the data average were analyzed and compared. The results showed that newsprint from ash CMP pulp were more suitable than CMP pulp mill in all measured properties (except brightness) and orange CMP pulp (except opacity). Following bleaching with hydrogen peroxide, the brightness, tear, burst, tensile and breaking length strengths increased and opacity decreased. The results showed that ash and orange unbleached CMP pulps are not good properties for newsprint production and these pulps have to bleach with hydrogen peroxide. In generally, the best mixed pulps were includes 45-60 percent ash and orange bleached CMP pulps with 40-55 percent MWPI CMP pulp for newsprint production.

With considering that in chemical-mechanical pulp (CMP) production process , the wood chips washing pre-treatment is important , so this research was conducted to investigate the effect of pre-treatment washing of populous deltoids wood chips on CMP Optical(brightness and opacity) and Strength(tensile and burst indexes) properties. Pre-treatment was accomplished with pure hot water and alkaline solutions (NaOH) at three levels of 0.5, 2 and 3.5 percent too. Pre-treated populous deltoids wood chips and control (chips without washing) were converted to pulp by CMP process. The results of this research indicated that the pretreatment of populous deltoids wood chips with hot water and also alkaline solutions caused wood chips mass and using of these treated chips for pulping caused pulp yield and brightness increscent, pulp strength reduction and also energy consumption increscent. . Removing of some part of chips hemicellulos have negative effect on the pulp refinability and cause pulp strength reduction.

Importing of wood is a solution to supplying raw material in the Iranian paper industry because of wood shortage. Therefore, the effect of mixing the imported aspen roundwood with the two hardwood native forest species including hornbeam and beech were perused on the optical and mechanical properties of CMP pulp. Cooking constant conditions consist of maximum temperature were 170 °C with a liquor-to-wood ratio (L/W) of 7, and chemical content of 20% based on the oven-dry weight of the wood chips. CMP pulps were prepared at different cooking times of 30 to 120 minutes using 20, 30, 40, 60, and 100% aspen wood in combination with the two species to achieve the yield of nearly 85%. Standard laboratory handsheets were made after pulp refining by 300 ml CSF, and then the strengths and optical properties were measured. Statistical analysis of result showed that there were significant differences among of the properties of CMP pulps by increasing the aspen wood ratio. All the properties have been improved except opacity paper. The required strength of newsprint and printing/writing paper made in Mazandaran wood and paper industries (MWPI) could be achieved by mixing of 20 and 30% imported aspen wood to the native species used in currently, respectively.

In this study, production of bleached chemical- mechanical pulp from wheat straw for newsprint papermaking was investigated. Wheat straw for pulping was obtained from Lorestan province. Wheat straw CMP pulp was prepared at 120, 140, and 160 °C temperature, 45 minute time, 10, 12, and 14% chemicals charge and 10:1 cooking liquor and straw ratio. The yield after defibration treatment varied between 56.5% and 72.5%. Two optimum pulps bleached by TCF method applying 2% and 3% NaOH, 1.5% and 2% H2O2, and 60 and 120 minutes bleaching time. One way analysis variance method showed that bleaching time had the most significant effect on optical properties of handsheet. Applying 3% (based on oven dry weight of the unbleached pulp) NaOH, 2% H2O2, and 120 min. in bleaching improved the brightness and opacity to 52.9%, and 79.5% ISO, respectively. Optimum pulp strengths including tensile, burst and tear indices were measured 43.87 Nm/g, 2.18 kPa.m2/g, and 8.46 mN.m2/g, respectively. All the strengths were higher than newsprint paper strength produced by Mazandaran wood and paper and Korean companies.

This research and aim was using Bamboo and Reed CMP pulp for newsprint production. For this purpose, some chips of bamboo stem in the west of Mazandaran were randomly chosen. Then CMP Pulps were prepared at the yield 85%in 120 minutes(Bamboo) and 31 minutes(Reed), by using cooking conditions of Wood and Paper Industries of Mazandaran 60 gr/m2 newsprint handsheets were prepared from the Bamboo and Reed CMP and Mill(MWPI) CMP pulps, first in a separate and then mixed way with 25,50,75 percents. Then the optical and mechanical properties were measured and compared according by using TAPPI Standard test methods. The results showed that the most strength of the burst, breaking length, tensile, tear strength, yellowness and opacity were in the handsheets obtained from 100% the bamboo CMP pulp and the lowest strength (except brightness) was in Reed CMP pulp. The results also pointed out that the above-mentioned all strengths (except brightness) can be improved by using 25-100% of the bamboo CMP pulp, too. The results also indicated that 25-100% of the bamboo CMP pulp and 25% of the Reed CMP pulp can use for newsprint production.