احمد الله آبادی

This study investigated the corrosive and scaling potential of drinking water in the rural areas of eastern Kakhk, southern Khorasan Razavi, Iran. Corrosion and scaling are critical issues that lead to the deterioration of water distribution infrastructure and decreased water quality. The analysis was conducted using indices such as the Langelier Saturation Index (LSI), Ryznar Stability Index (RSI), Puckorius Scaling Index (PSI), Larson-Skold Index (LS), and the Aggressiveness Index (AI).

A total of 32 water samples were collected from 16 locations, including one city and 15 rural regions. Samples were drawn from springs, qanats, and distribution systems. Key physicochemical parameters such as pH, electrical conductivity, and concentrations of calcium and magnesium were measured. Each sample was analyzed twice in accordance with APHA standards, and corrosion and scaling indices were calculated.

The LSI revealed that 100% of the samples had a tendency to form scale, while the RSI indicated that 68.75% were corrosive. Over 80% of the samples were confirmed to be corrosive by the Larson-Skold and Aggressiveness indices. However, the Puckorius Index showed that 62.5% of the samples were in a balanced state, without a strong inclination towards either corrosion or scaling.

These results emphasize the need for continuous monitoring of water quality and the adoption of preventive measures to mitigate corrosion and scaling in rural water systems. The findings provide important insights for decision-makers to develop strategies aimed at preserving water infrastructure and ensuring long-term sustainability.

In today's society, preparing healthy food has become challenging due to the variety of food production methods. Oil is produced in several ways in our country. In the cold pressing method, there is insufficient monitoring of the manufactured product. The aim of the present study is to investigate the physicochemical characteristics and the levels of heavy metals of industrial oil compared to cold-pressed oil.

In this research, 54 samples of sunflower, sesame, and canola oil produced by both cold pressing and industrial refiningmethods were prepared. Their physicochemical characteristics, including refractive index, acid value, iodine value, saponification value, peroxide value, anisidine value, as well as the concentrations of lead, iron, arsenic and copper were determined. Additionally, the effect of storage time on these characteristics was investigated.

The Iodine number showed the highest deviation from the standard (61%), with an average of 136.70 gI/100g for the cold-pressed oil and 134.48 gI/100g for industrially refined oiland. The average value of the physicochemical characteristics, except for the saponification value, were higher in the cold-pressed oil samples  compared to the industrially refined oil samples, but the observed difference was not statistically significant. An investigation into the effect of storage time on physicochemical properties revealed a significant increase in peroxide value (p<0.01) and anisidine (p <0.05) in both oil groups over a two-month period. The average concentration of arsenic, lead, iron and copper in the studied oils was 0.03, 0.78, 0.05 and 0.05 mg/kgoil, respectively. A deviation from the standard was observed only in one sample of cold-pressed sunflower oil, with an arsenic concentration of 0.11 mg/kgoil).

Based on the obtained results, the refined industrial oils exhibited more favorable chemical characteristics and stability.  It is suggested that cold-pressed oils should be consumed within a short period of time. For frying purposes, refined industrial oils are preferable.

The emergence of new chemical industries has caused the release of a large amount of organic compounds including industrial by-products, insecticides and other chemicals in nature. Endocrine disrupting compounds are a known group of hazardous and complex pollutants that occurs in wastewater and water sources worldwide, either naturally or as a result of human activities. In this study, an attempt is made to remove diethyl phthalate from water environments by the advanced oxidation process of ozonation in the presence of activated carbon produced from the Skanbil tree.

methods and Materials:

 This experimental study was done in a reactor with a volume of 100 mL. In each experiment, diethyl phthalate solution was poured into the pilot in the desired concentration and ozone with 0.8 mg/min dose was injected into the reaction solution. Process parameters included pH (2-8), reaction times (2 to 30 min), pollutant concentration (5-25 mg/L) and catalyst dose (0.025-0.1 gram). In the end of each experiment, the sample was withdrawn from the pilot and analyzed using HPLC to determine the residual diethyl phthalate.

The results showed that under optimal conditions of pH = 6.8, ozone dose = 0.8 mg/min and contact time = 30 minutes, ozonation could only remove 60% of diethyl phthalate, and under the same conditions, catalytic ozonation with 0.075 g of carbon obtained from the skanbil tree could remove 94% of diethyl phthalate.

The results of this research showed that catalytic ozonation with carbon obtained from the wood waste of shanbil tree can be used as an advanced treatment method.

Antibiotics, comprising a significant amount of pharmaceutical compounds, are used as human and veterinary treatments . these antibiotics come to appear as contaminantoin soil, surface water, groundwater, and even drinkingwater.Advanced oxidation processes such as catalytic ozonation are effective to remove the antibiotics form water and wastewaterThe aim of this study was to investigate the efficiency of Catalytic Ozonation Process for tetracycline antibiotics removal from contaminated waters

In this design, an ozonation pilot with a volume of 200 cc was used. In each experiment, the tetracycline solution was poured into the desired concentration, the pH of the sample was adjusted with sulfuric acid and NaOH. At different times of 5 to 30 minutes and different pHs of 2 to 10 ozonation was performed at the dose of 0.8 mg/min. Then, under these conditions, ozonation was performed in the presence of activated carbon catalyst and a sample was discharged from the pilot and analyzed (HPLC) to determine the remaining tetracycline.

The results showed that under optimum conditions of pH= 8 and ozone dose of 0.8 mg / min and contact time of 30 minutes ozonation only eliminated 59% of tetracycline and in the same conditions catalytic ozonation with 0.01 g/L carbon. The Calligonum comosum tree was able to remove 100% tetracycline in 30 minutes.

The results of this study showed that carbon catalyzed ozonation from wood Calligonum comosum waste can be used as an advanced treatment method.

Penicillin G (PG) is one of the most widely antibiotics used around the world. The release of PG in an aqueous solution leads to contamination of water resources. This study aimed to determine the efficiency of modified Eskanbil activated carbon for the removal of PG from aqueous solutions. The NH4Cl-induced activated carbon was synthesized by a simple method and used for the degradation of PG in contaminated water.

Activated carbon was characterized by Fourier transform infrared spectroscopy (FTIR), Field emission scanning electron microscopy (FESEM), and Brunauer–Emmett–Teller (BET) surface area analysis. The influence of important parameters including solution pH, contact time, and initial PG concentration, and dosage of adsorbent was examined on the efficiency of EAC in degradation of penicillin G in aqueous solution.

The synthesized carbon was characterized. The BET results indicated that the surface area of the Activated Carbon catalyst was1473 m2/g. The maximum PG adsorption onto EAC was observed at the pH of 6. The PG removal of 33% at an EAC concentration of 0.1 g/L increased to 99.98% at an activated carbon concentration of 0.5 g/L. The isotherm and kinetic studies of PG removal by EAC showed that the Freundlich model (R2>0.995) and the pseudo-second-order (R2>0.983) equation represented the best fit with the adsorption data.

EAC is recommended as a suitable and cost-efficient adsorbent for removing poisons, pharmaceuticals, and other emerging contaminants from water resources.

The presence of drugs in water and wastewater sources poses risks to humans and the environment. These materials are not completely eliminated by conventional water and wastewater treatment methods. This study aimed to investigate the photocatalytic removal of acetaminophen from aqueous solutions by the advanced UV/H2O2/ZnO oxidation method.

In this experimental analytical study, zinc oxide and hydrogen peroxide were used in a 500 ml reactor under UV-C irradiation to remove acetaminophen. The effects of initial parameters of acetaminophen, solution pH, contact time, hydrogen peroxide concentration, and zinc oxide nanoparticle concentration were investigated. Experiments were designed and analyzed using the CCD method by Design Expert 10 software.

Themaximum removal efficiency of acetaminophen was obtained as 94% at pH 7, contact time 8 min, the initial contaminant concentration 62.5 mg/l, catalyst dose 0.0275 g, and H2O2 concentration 2 ml. By changing the time to 1 and 15 minutes, the removal rate decreased by 26 and 76%, respectively, and by increasing the catalyst dose from 0.0275 g to 0.05 g, the removal rate increased by 99%.

In this study, the efficiency decreased with increasing contaminant concentration. The removal efficiency was higher in neutral conditions than in acidic and alkaline conditions. The photocatalytic process (UV/H2O2/ZnO) is highly potent for removing acetaminophen from aqueous solutions.

With industrial development and population growth, the emerging contaminants enter into the natural water resources. Therefore, in this study Adsorption potential of NH4Cl-induced activated carbon (NAC) was investigated to remove antibiotic sulfanilamide from contaminated water.

Materials & Methods:

The effect of operational conditions including solution pH, NAC concentration, sulfanilamide initial concentration and contact time were studied.

NAC and SAC had specific surface area of 1029, 1024 and mean pore volume of 2.64, 2.23nm, respectively. With increasing the NAC concentration to 1 g/L, sulfanilamide adsorption efficiency increased to 84.4% within 40 min. Then the adsorption slightly increased with the increase in the contact time to 120 min and reached to its maximum adsorption of 99.2%. The maximum adsorption percentage of sulfanilamide onto SAC under similar conditions reached to 49.2%. The kinetics analysis showed that experimental adsorption data for both NAC and SAC were best fitted to the pseudo-second-order model. The maximum adsorption capacity of sulfanilamide onto NAC and SAC, calculated by the Langmuir model, was 238.1 and 87/7 mg/g, respectively.

Generally, these results showed that NAC was an efficient adsorbent with high removal efficiency for eliminating the antibiotics from the contaminated water streams

Herbicides, including atrazine, are among the most important newly discovered contaminants found in water bodies and are hazardous to human health and the environment. adsorption is one of the best techniques used to remove these contaminants from  contaminated water.

In this study, two carbon from waste Pomegranate and  calligonum Comosum were used to remove atrazine herbicide. After chemical activation these carbons with NH4Cl, and then 800 ° C for 2 hours, parametric tests were performed and the effect of pH, adsorbent concentration, atrazine concentration and contact time were investigated; then absorption equilibrium tests; absorption capacity and its isotherms  investigated for the removal of atrazine by two carbons were calculated.

The results showed that the carbon produced from the calligonum Comosum wood in optimal conditions at pH =7; carbon concentration 0.2 g/L, and the mixing time of 50 minutes could remove 100% atrazine at 25 mg/L . The carbon produced from pomegranate in optimal conditions pH =6; carbon concentration of 0.2 g/L and mixing time of 50 minutes could remove 91.5% atrazine to 25 mg/ L. Absorption equilibrium tests showed that the absorption capacity of carbon Calligonum Comosum and  pomegranate were 672 and 645mg/g respectively. Discussion The results of this study showed that both carbons have high absorption capacity in the removal of atrazine herbicide and can be an effective and economical absorbent for the removal of this contaminant from natural waters.

One of the most important environmental pollutants that there is in sewage of different industrials is cyanide to cause pollution of water sources that are dangerous to humans and the environment. Cyanide can be removed in different ways from the aqueous media, but most of these methods are costly. Therefore, the aim of this study is the removal cyanide using iron nanoparticles.

Removal of cyanide from aqueous media using iron nanoparticles in various conditions including the effect of the adsorbent, initial cyanide concentration, contact time and pH were studied in discontinuous phase. In this study, adsorption equilibrium and also the kinetics of the reaction examined.

In the process of sharing discontinuous, the balance was achieved after 120 minutes of contact time and maximum amount of removal cyanide in the pH =11 for cyanide concentration of 2.5 mg/L and 1 gr of nanoparticle over 97% obtained. Also the results showed that the adsorption process fitted with Langmuir isotherm and chemical kinetic fitted with of secondary grade.

According to the findings, iron nanoparticles can be used as a suitable option for removal cyanide from aqueous solution in hazardous waste. Keywords: iron nanoparticles, cyanide, hazardous waste